T
Teruaki Mukaiyama
Researcher at Kitasato University
Publications - 1072
Citations - 15343
Teruaki Mukaiyama is an academic researcher from Kitasato University. The author has contributed to research in topics: Catalysis & Silylation. The author has an hindex of 52, co-authored 1072 publications receiving 14878 citations. Previous affiliations of Teruaki Mukaiyama include University of Tokyo & Tokyo University of Science.
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Journal ArticleDOI
Regio- and stereoselective cross-aldol reactions via dialkylboryl triflates.
Tan Inoue,Teruaki Mukaiyama +1 more
TL;DR: Vinyloxyboranes showed remarkable reactivity toward aldehydes to give only one regioisomer of the corresponding cross-aldols in good yields and high stereoselectivity was also observed in these reactions.
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4-O-Benzyl-23-O-isopropylidene-L-threose: A useful building block for stereoselective synthesis of monosaccharides
TL;DR: The 4-O-Benzyl-23-Oisopropylidene-L-threose building block is a useful four-carbon building block for monosaccharide synthesis as discussed by the authors.
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A Facile Synthesis of Cyanohydrin Trimethylsilyl Ethers by the Addition Reaction of Trimethylsilyl Cyanide with Aldehydes under Basic Condition
TL;DR: In the presence of a catalytic amount of Lewis base such as amine, phosphine, arsine or antimony, TMS-CN smoothly reacts with aldehydes to afford the corresponding cyanohydrin trimethylsilyl ethers in excellent yields as mentioned in this paper.
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Asymmetric synthesis based on chiral diamines having pyrrolidine ring
TL;DR: In this paper, various highly stereoselective asymmetric reactions based on chiral diamines having pyrrolidine ring are described, and some of these reactions have been successfully applied to the syntheses of natural products.
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Asymmetric Reduction of Prochiral Ketones with Chiral Hydride Reagents Prepared from Lithium Aluminium Hydride and (S)-2-(N-Substituted aminomethyl)pyrrolidines
TL;DR: Asymmetric reduction of prochiral ketones with various hydride reagents prepared from lithium aluminium hyddride and pyrrolidines, derived easily by four steps from commercially available (S)-proline, yields optically active alcohols with 13-92% optical purity having the S-configuration as discussed by the authors.