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Thomas H. Fletcher

Bio: Thomas H. Fletcher is an academic researcher from Leeds Beckett University. The author has contributed to research in topics: Coal & Char. The author has an hindex of 44, co-authored 236 publications receiving 6177 citations. Previous affiliations of Thomas H. Fletcher include Sandia National Laboratories & Brigham Young University.
Topics: Coal, Char, Combustion, Tar, Pyrolysis


Papers
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Journal ArticleDOI
TL;DR: In this paper, the authors proposed a chemical percolation devolatilization (CPD) model for rapidly heated coal based on the chemical structure of the parent coal, which can predict the effects of pressure on tar and total volatiles yields observed in heated grid experiments.
Abstract: ~~ ~~ ~ ~ ~~ The chemical percolation devolatilization (CPD) model describes the devolatilization behavior of rapidly heated coal based on the chemical structure of the parent coal. Percolation lattice statistics are employed to describe the generation of tar precursors of finite size based on the number of cleaved labile bonds in the infinite coal lattice. The chemical percolation devolatization model described here includes treatment of vapopliquid equilibrium and a cross-linking mechanism. The cross-linking mechanism permits reattachment of metaplast to the infinite char matrix. A generalized vapor preasure correlation for high molecular weight hydrocarbons, such as coal tar, is proposed based on data from coal liquids. Coal-independent kinetic parameters are employed. Coal-dependent chemical structure coefficients for the CPD model are taken directly from 13C NMR measurements, with the exception of one empirical parameter representing the population of char bridges in the parent coal. This is in contrast to the previous and common practice of adjusting input coefficients to precisely match measured tar and total volatiles yields. The CPD model successfully predicts the effects of pressure on tar and total volatiles yields observed in heated grid experiments for both bituminous coal and for lignite. Predictions of the amount and characteristics of gas and tar from many different coals compare well with available data, which is unique because the majority of model input coefficients are taken directly from NMR data and are not used as empirical fitting coefficients. Predicted tar molecular weights are consistent with size-exclusion chromatography (SEC) data and field ionization mass spectrometry (FIMS) data. Predictions of average molecular weights of aromatic clusters as a function of coal type agree with corresponding data from NMR analyses of parent coals. The direct use of chemical structure data as a function of coal type helps justify the model on a mechanistic rather than an empirical basis.

351 citations

Journal ArticleDOI
01 May 1993-Fuel
TL;DR: In coal pyrolysis, a number of new experimental and theoretical approaches have been proposed to shed new light on the subject as mentioned in this paper, such as kinetics, the formation of volatile products, network models, cross-linking, rank effects, and the two-component model of coal structure.

305 citations

Journal ArticleDOI
TL;DR: In this article, a chemical percolation devolatilization (CPD) model is used to describe the effects of heating rate and temperature on tar and gas release from coal.
Abstract: The chemical percolation devolatilization (CPD) model previously developed to describe the devolatilization behavior of rapidly heated coal was based on the chemical structure of the parent coal. Percolation lattice statistics are employed to describe generation of finite tar clusters as labile bonds are cleaved in the infinite coal lattice. The model is used here to describe effects of heating rate and temperature on tar and gas release from coal. Results indicate that the CPD models predictions yied good agreement with published data for a wide range of coals and particle heating rates

249 citations

Journal ArticleDOI
TL;DR: In this paper, the formation, agglomeration and properties of coal-derived soot, including pyrolysis experiments and combustion experiments, are reviewed, as well as the types of experiments performed, the soot yields obtained, the size of the coal particles, the optical properties, the relationship between coal derived soot and soot from simple hydrocarbons, and attempts to model soot in coal flames.

185 citations


Cited by
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Journal ArticleDOI
TL;DR: In this paper, Imagined communities: Reflections on the origin and spread of nationalism are discussed. And the history of European ideas: Vol. 21, No. 5, pp. 721-722.

13,842 citations

Journal Article
TL;DR: The continuing convergence of the digital marketing and sales funnels has created a strategic continuum from digital lead generation to digital sales, which identifies the current composition of this digital continuum while providing opportunities to evaluate sales and marketing digital strategies.
Abstract: MKT 6009 Marketing Internship (0 semester credit hours) Student gains experience and improves skills through appropriate developmental work assignments in a real business environment. Student must identify and submit specific business learning objectives at the beginning of the semester. The student must demonstrate exposure to the managerial perspective via involvement or observation. At semester end, student prepares an oral or poster presentation, or a written paper reflecting on the work experience. Student performance is evaluated by the work supervisor. Pass/Fail only. Prerequisites: (MAS 6102 or MBA major) and department consent required. (0-0) S MKT 6244 Digital Marketing Strategy (2 semester credit hours) Executive Education Course. The course explores three distinct areas within marketing and sales namely, digital marketing, traditional sales prospecting, and executive sales organization and strategy. The continuing convergence of the digital marketing and sales funnels has created a strategic continuum from digital lead generation to digital sales. The course identifies the current composition of this digital continuum while providing opportunities to evaluate sales and marketing digital strategies. Prerequisites: MKT 6301 and instructor consent required. (2-0) Y MKT 6301 (SYSM 6318) Marketing Management (3 semester credit hours) Overview of marketing management methods, principles and concepts including product, pricing, promotion and distribution decisions as well as segmentation, targeting and positioning. (3-0) S MKT 6309 Marketing Data Analysis and Research (3 semester credit hours) Methods employed in market research and data analysis to understand consumer behavior, customer journeys, and markets so as to enable better decision-making. Topics include understanding different sources of data, survey design, experiments, and sampling plans. The course will cover the techniques used for market sizing estimation and forecasting. In addition, the course will cover the foundational concepts and techniques used in data visualization and \"story-telling\" for clients and management. Corequisites: MKT 6301 and OPRE 6301. (3-0) Y MKT 6310 Consumer Behavior (3 semester credit hours) An exposition of the theoretical perspectives of consumer behavior along with practical marketing implication. Study of psychological, sociological and behavioral findings and frameworks with reference to consumer decision-making. Topics will include the consumer decision-making model, individual determinants of consumer behavior and environmental influences on consumer behavior and their impact on marketing. Prerequisite: MKT 6301. (3-0) Y MKT 6321 Interactive and Digital Marketing (3 semester credit hours) Introduction to the theory and practice of interactive and digital marketing. Topics covered include: online-market research, consumer behavior, conversion metrics, and segmentation considerations; ecommerce, search and display advertising, audiences, search engine marketing, email, mobile, video, social networks, and the Internet of Things. (3-0) T MKT 6322 Internet Business Models (3 semester credit hours) Topics to be covered are: consumer behavior on the Internet, advertising on the Internet, competitive strategies, market research using the Internet, brand management, managing distribution and supply chains, pricing strategies, electronic payment systems, and developing virtual organizations. Further, students learn auction theory, web content design, and clickstream analysis. Prerequisite: MKT 6301. (3-0) Y MKT 6323 Database Marketing (3 semester credit hours) Techniques to analyze, interpret, and utilize marketing databases of customers to identify a firm's best customers, understanding their needs, and targeting communications and promotions to retain such customers. Topics

5,537 citations

Journal ArticleDOI
08 Sep 1978-Science

5,182 citations

Journal ArticleDOI
TL;DR: The optical properties of light-absorbing, carbonaceous substance often called "soot", "black carbon", or "carbon black" have been the subject of some debate as discussed by the authors.
Abstract: The optical properties of the light-absorbing, carbonaceous substance often called “soot,” “black carbon,” or “carbon black" have been the subject of some debate. These properties are necessary to model how aerosols affect climate, and our review is targeted specifically for that application. We recommend the term light-absorbing carbon to avoid conflict with operationally based definitions. Absorptive properties depend on molecular form, particularly the size of sp 2-bonded clusters. Freshly-generated particles should be represented as aggregates, and their absorption is like that of particles small relative to the wavelength. Previous compendia have yielded a wide range of values for both refractive indices and absorption cross section. The absorptive properties of light-absorbing carbon are not as variable as is commonly believed. Our tabulation suggests a mass-normalized absorption cross section of 7.5 ± 1.2 m2/g at 550 nm for uncoated particles. We recommend a narrow range of refractive indices for s...

2,312 citations

Journal ArticleDOI
TL;DR: Bourdieu as mentioned in this paper presents a combination of social theory, statistical data, illustrations, and interviews, Distinction: A Social Critique of the Judg..., which is a collection of interviews with Bourdieu.
Abstract: By Pierre Bourdieu (London: Routledge, 2010), xxx + 607 pp. £15.99 paper. A combination of social theory, statistical data, illustrations, and interviews, Distinction: A Social Critique of the Judg...

2,238 citations