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Timothy Michaelson

Bio: Timothy Michaelson is an academic researcher from Applied Materials. The author has contributed to research in topics: Layer (electronics) & Atomic layer deposition. The author has an hindex of 13, co-authored 26 publications receiving 1319 citations. Previous affiliations of Timothy Michaelson include University of Texas System & University of Texas at Austin.

Papers
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Proceedings ArticleDOI
25 Jun 1999
TL;DR: In this article, a template is created on a standard mask blank by using the patterned chromium as an etch mask to produce high-resolution relief images in the quartz.
Abstract: An alternative approach to lithography is being developed based on a dual-layer imprint scheme. This process has the potential to become a high-throughput means of producing high aspect ratio, high-resolution patterns without projection optics. In this process, a template is created on a standard mask blank by using the patterned chromium as an etch mask to produce high-resolution relief images in the quartz. The etched template and a substrate that has been coated with an organic planarization layer are brought into close proximity. A low-viscosity, photopolymerizable formulation containing organosilicon precursors is introduced into the gap between the two surfaces. The template is then brought into contact with the substrate. The solution that is trapped in the relief structures of the template is photopolymerized by exposure through the backside of the quartz template. The template is separated from the substrate, leaving a UV-curved replica of the relief structure on the planarization layer. Features smaller than 60 nm in size have been reliably produced using this imprinting process. The resolution silicon polymer images are transferred through the planarization layer by anisotropic oxygen reactive ion etching. This paper provides a progress report on our efforts to evaluate the potential of this process.

643 citations

Patent
04 Dec 2014
TL;DR: In this paper, the authors describe a method for selective deposition of a first substrate surface and a second substrate surface, where the first layer of film over the first substrate is thicker than the second substrate substrate surface.
Abstract: Provided are methods for selective deposition Certain methods describe providing a first substrate surface; providing a second substrate surface; depositing a first layer of film over the first and second substrate surfaces, wherein the deposition has an incubation delay over the second substrate surface such that the first layer of film over the first substrate surface is thicker than the first layer of film deposited over the second substrate surface; and etching the first layer of film over the first and second substrate surfaces, wherein the first layer of film over the second substrate surface is at least substantially removed, but the first layer of film over the first substrate is only partially removed

150 citations

Patent
11 Mar 2014
TL;DR: In this paper, a method of forming an etch mask on a substrate is provided that includes (1) forming a resist layer on the substrate, (2) exposing one or more regions of the resist layer to an energy source so as to alter at least one of a physical property and a chemical property of the exposed regions; (3) performing a hardening process on the resist surface to increase the etch resistance of the first regions of resist layer relative to second regions.
Abstract: In some embodiments, a method of forming an etch mask on a substrate is provided that includes (1) forming a resist layer on a substrate; (2) exposing one or more regions of the resist layer to an energy source so as to alter at least one of a physical property and a chemical property of the exposed regions; (3) performing a hardening process on the resist layer to increase the etch resistance of first regions of the resist layer relative to second regions of the resist layer, the hardening process including exposing the resist layer to one or more reactive species within an atomic layer deposition (ALD) chamber; and (4) dry etching the resist layer to remove the one or more second regions and to form a pattern in the resist layer. Other embodiments are provided.

84 citations

Patent
06 Oct 2011
TL;DR: In this paper, chemical vapor deposition methods of forming films (e.g., silicon-containing films) as photoresists using a plasma which may be exposed to radiation to form a pattern.
Abstract: Methods for forming photoresists sensitive to radiation on a substrate are provided. Described are chemical vapor deposition methods of forming films (e.g., silicon-containing films) as photoresists using a plasma which may be exposed to radiation to form a pattern. The deposition methods utilize precursors with cross-linkable moieties that will cross-link upon exposure to radiation. Radiation may be carried out in the with or without the presence of oxygen. Exposed or unexposed areas may then be developed in an aqueous base developer.

72 citations

Patent
06 Oct 2011
TL;DR: In this paper, the process can be repeated multiple times to deposit a plurality of silicon photoresist layers, and the process of depositing photoresists and forming patterns in photorefers is described.
Abstract: Methods for forming photoresists sensitive to radiation on substrate are provided. Atomic layer deposition methods of forming films (e.g., silicon-containing films) photoresists are described. The process can be repeated multiple times to deposit a plurality of silicon photoresist layers. Process of depositing photoresist and forming patterns in photoresist are also disclosed which utilize carbon containing underlayers such as amorphous carbon layers.

69 citations


Cited by
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Journal ArticleDOI
TL;DR: Nanoimprint lithography (NIL) is a high throughput, high-resolution parallel patterning method in which a surface pattern of a stamp is replicated into a material by mechanical contact and three dimensional material displacement.
Abstract: Nanoimprint lithography (NIL) is a high throughput, high-resolution parallel patterning method in which a surface pattern of a stamp is replicated into a material by mechanical contact and three dimensional material displacement. This can be done by shaping a liquid followed by a curing process for hardening, by variation of the thermomechanical properties of a film by heating and cooling, or by any other kind of shaping process using the difference in hardness of a mold and a moldable material. The local thickness contrast of the resulting thin molded film can be used as a means to pattern an underlying substrate on wafer level by standard pattern transfer methods, but also directly in applications where a bulk modified functional layer is needed. Therefore it is mainly aimed toward fields in which electron beam and high-end photolithography are costly and do not provide sufficient resolution at reasonable throughput. The aim of this review is to play between two poles: the need to establish standard processes and tools for research and industry, and the issues that make NIL a scientific endeavor. It is not the author’s intention to duplicate the content of the reviews already published, but to look on the NIL process as a whole. The author will also address some issues, which are not covered by the other reviews, e.g., the origin of NIL and the misconceptions, which sometimes dominate the debate about problems of NIL, and guide the reader to issues, which are often forgotten or overlooked.

715 citations

Journal ArticleDOI
TL;DR: Nanoimprint is an emerging lithographic technology that promises high-throughput patterning of nanostructures as mentioned in this paper, which can achieve pattern resolutions beyond the limitations set by the light diffractions or beam scatterings in other conventional techniques.
Abstract: Nanoimprint is an emerging lithographic technology that promises high-throughput patterning of nanostructures. Based on the mechanical embossing principle, nanoimprint technique can achieve pattern resolutions beyond the limitations set by the light diffractions or beam scatterings in other conventional techniques. This article reviews the basic principles of nanoimprint technology and some of the recent progress in this field. It also explores a few alternative approaches that are related to nanoimprint as well as additive approaches for patterning polymer structures. Nanoimprint technology can not only create resist patterns as in lithography but can also imprint functional device structures in polymers. This property is exploited in several non-traditional microelectronic applications in the areas of photonics and biotechnology.

702 citations

Journal ArticleDOI
02 Jul 2009-ACS Nano
TL;DR: The film thickness after the imprinting process, which is critical in optical applications, as a function of several imprinting parameters such as roller pressure and speed, is thoroughly investigated, and an analytical model has been developed to predict the residual layer thickness in dynamic R2RNIL process.
Abstract: A continuous roll-to-roll nanoimprint lithography (R2RNIL) technique can provide a solution for high-speed large-area nanoscale patterning with greatly improved throughput; furthermore, it can overcome the challenges faced by conventional NIL in maintaining pressure uniformity and successful demolding in large-area imprinting. In this work, we demonstrate large-area (4 in. wide) continuous imprinting of nanogratings by using a newly developed apparatus capable of roll-to-roll imprinting (R2RNIL) on flexible web and roll-to-plate imprinting (R2PNIL) on rigid substrate. The 300 nm line width grating patterns are continuously transferred on either glass substrate (roll-to-plate mode) or flexible plastic substrate (roll-to-roll mode) with greatly enhanced throughput. In addition, the film thickness after the imprinting process, which is critical in optical applications, as a function of several imprinting parameters such as roller pressure and speed, is thoroughly investigated, and an analytical model has been developed to predict the residual layer thickness in dynamic R2RNIL process.

593 citations

Journal ArticleDOI
TL;DR: Different approaches to fabricate polymeric nanostructures of various shapes are reviewed, a comprehensive summary on the current understandings of the influence of nanostructure with different shapes on important biological processes in drug delivery is provided, and future perspectives for the development of nanstructures with well-defined shapes for drug delivery are discussed.

460 citations

Patent
13 Sep 2000
TL;DR: Elastomeric stamps facilitate direct patterning of electrical, biological, chemical, and mechanical materials as discussed by the authors, where a thin film of material is deposited on a substrate, either originally present as a liquid or subsequently liquefied, is patterned by embossing at low pressure using a raised pattern.
Abstract: Elastomeric stamps facilitate direct patterning of electrical, biological, chemical, and mechanical materials A thin film of material is deposited on a substrate The deposited material, either originally present as a liquid or subsequently liquefied, is patterned by embossing at low pressure using an elastomeric stamp having a raised pattern The patterned liquid is then cured to form a functional layer The deposition, embossing, and curing steps may be repeated numerous times with the same or different liquids, and in two or three dimensions The various deposited layers may, for example, have varying electrical characteristics, interacting so as to produce an integrated electronic component

427 citations