T
Toshiyasu Sakakura
Researcher at National Institute of Advanced Industrial Science and Technology
Publications - 48
Citations - 4988
Toshiyasu Sakakura is an academic researcher from National Institute of Advanced Industrial Science and Technology. The author has contributed to research in topics: Catalysis & Palladium. The author has an hindex of 19, co-authored 48 publications receiving 4576 citations.
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Journal ArticleDOI
Transformation of carbon dioxide.
TL;DR: Reaction Mechanism, Synthesis of Urea and Urethane Derivatives, and Alcohol Homologation 2382 10.1.
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Cyclic Carbonate Synthesis from Supercritical Carbon Dioxide and Epoxide over Lanthanide Oxychloride
TL;DR: In this paper, a solid catalyst for propylene carbonate synthesis from supercritical CO 2 and propylene oxide is presented, which requires no additional organic solvents and the product is automatically separated out from the CO 2 phase.
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Efficient synthesis of cyclic carbonate from carbon dioxide catalyzed by polyoxometalate: the remarkable effects of metal substitution
TL;DR: Tetraalkylammonium salts of transition-metal-substituted polyoxometalates, such as [(n-C7H15)4N]6[α-SiW11O39Co] and [(n -C7 H15) 4N] 6[α -SiW 11O39Mn], efficiently catalyze cyclic carbonate synthesis from carbon dioxide and epoxide.
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Selective and high yield synthesis of dimethyl carbonate directly from carbon dioxide and methanol
TL;DR: In this article, supercritical carbon dioxide is efficiently converted to dimethyl carbonate (DMC) via the reaction with methanol in the presence of a catalytic amount of dialkyltin oxide or its derivatives.
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New procedure for recycling homogeneous catalyst: propylene carbonate synthesis under supercritical CO2 conditions
TL;DR: In this paper, the Rf3RPI catalyst was used for catalyzed propylene carbonate synthesis from propylene oxide and carbon dioxide under supercritical CO2 conditions, where the carbonate was spontaneously separated out of the super-critical CO 2 phase.