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Showing papers by "Vadim G. Kessler published in 1991"

Journal Article•DOI•
Molybdenum and tungsten (VI) bimetallic alkoxides. Decomposition accompanied by dialkylether elimination

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N. Ya. Turova1, Vadim G. Kessler1, S.I. Kucheiko1•
Moscow State University1
01 Jan 1991-Polyhedron
TL;DR: In this paper, the existence of (1:1) bimetallic complexes in alcohol solutions has been proved by conductometric titration curves of MO(OR)4, and MO2 (OR)2 (M = Mo, W; R = Et, iPr, C2H4OMe) by sodium (or lithium) alkoxides.

78 citations

Journal Article•DOI•
Synthesis and crystal structure of the double barium–titanium isopropoxide [Ba4Ti4(µ4-O)4(µ3-OR)2(µ-OR)8(OR)6(ROH)4][Ba4Ti4(µ4-O)4(µ3-OR)2(µ-OR)9(OR)5(ROH)3]

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Alexander I. Yanovsky, M. I. Yanovskaya, Victoriya K. Limar, Vadim G. Kessler, Nataliya Ya. Turova, Yuri T. Struchkov 
01 Jan 1991-Journal of The Chemical Society, Chemical Communications
TL;DR: An X-ray structural study of the crystals isolated from the solutions obtained by the reaction of Ba metal with Ti(OPri)4 in isopropyl alcohol has been carried out; the crystals of the compound, which is a precursor for the synthesis of BaTiO3, contain molecules of two different kinds [Ba4Ti4O4(OR)16(ROH)4], where R = Pri as mentioned in this paper.
Abstract: An X-ray structural study of the crystals isolated from the solutions obtained by the reaction of Ba metal with Ti(OPri)4 in isopropyl alcohol has been carried out; the crystals of the compound, which is a precursor for the synthesis of BaTiO3, contain molecules of two different kinds [Ba4Ti4O4(OR)16(ROH)4] and [Ba4Ti4O4(OR)16(ROH)3], where R = Pri.

28 citations

Journal Article•
The structure of Nb8O10(OET)20 and the nature of crystalline metal oxide alkoxides

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Vadim G. Kessler, N. Y. Turova, A. I. Yanovskii, A. I. Belokon, Yu. T. Struchkov 
01 Jan 1991-Russian Journal of Inorganic Chemistry

14 citations

Journal Article•
Methyl cellosolvates of metals

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N. Ya. Turova, E. P. Turevskaya, Vadim G. Kessler, N. I. Kozlova, A. I. Belokon 
01 Jan 1991-Russian Journal of Inorganic Chemistry

8 citations

Journal Article•DOI•
Molybdenum(Vi) Methoxyethoxides. Synthesis and Structure of MoO2(OC2H4OMe)2 and Polymeric NaMoO2(OC2H4OMe)3

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Vadim G. Kessler1, Nataliya Ya. Turova1, Andrei V. Korolev2, A. I. Yanovskii2, Yurii T. Struchkov2 •
Moscow State University1, A. N. Nesmeyanov Institute of Organoelement Compounds2
01 Jan 1991-Mendeleev Communications
TL;DR: In this article, an X-ray structural study of MoO(OC2H4OMe) showed that its crystals are constructed of monomeric molecules with both methoxyethoxide groups forming chelate rings around the molybdenum atoms.

8 citations

Journal Article•
The crystalline aluminium isopropoxy-monochloride probem; determination of the structure of Al4(μ4-O)(μ-OPri)5. .[H(OPri)2]Cl4

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N. Y. Turova, A. I. Yanovskii, Vadim G. Kessler, N. I. Kozlova, Yu. T. Struchkov 
01 Jan 1991-Russian Journal of Inorganic Chemistry

4 citations

Journal Article•DOI•
Metal Alkoxides - Precursors for Preparation of Complex Molybdates and Tungstates

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M. I. Yanovskaya, I. E. Obvintseva, Vadim G. Kessler, N.Ya. Turova
01 Jan 1991-Materials Science Forum

1 citations