Showing papers by "Vadim G. Kessler published in 1993"
TL;DR: The hexanuclear complex of calcium oxo ethoxide ethanol solvate, [Ca6O2(OEt)8]·14EtOH 1 has been isolated after the prolonged refluxing of an ethanol solution of calcium ethoxide in the presence of the oxygen in air and studied by X-ray diffraction as mentioned in this paper.
Abstract: The hexanuclear complex of calcium oxo ethoxide ethanol solvate, [Ca6O2(OEt)8]·14EtOH 1 has been isolated after the prolonged refluxing of an ethanol solution of calcium ethoxide in the presence of the oxygen in air and studied by X-ray diffraction; the metal-oxygen framework is built of two [Ca4O4] cubes sharing a common [Ca2O2] face, which involves both oxo groups.
44 citations
TL;DR: In this article, the general effect of the M(μ-OR) 2 M ring upon the arrangement of bonds with increased multiplicity is discussed in this and related molecules, and the X-ray single crystal study showed the complex to consist of pseudo-centrosymmetric dimeric molecules.
39 citations
Journal Article•
1 citations