Author
Vimal K. Jain
Other affiliations: University of Rajasthan, University of Guelph, Panjab University, Chandigarh ...read more
Bio: Vimal K. Jain is an academic researcher from University of Mumbai. The author has contributed to research in topics: Palladium & Platinum. The author has an hindex of 38, co-authored 324 publications receiving 5734 citations. Previous affiliations of Vimal K. Jain include University of Rajasthan & University of Guelph.
Papers published on a yearly basis
Papers
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TL;DR: The chemistry of binuclear palladium(II) and platinum (II) complexes has been reviewed in this paper, which deals with complexes derived from various classes of ligands and covers various aspects, viz. synthesis, spectroscopic and structural features and chemical reactivity of these complexes.
179 citations
TL;DR: The chemistry of both tri-and penta-valent compounds of arsenic, antimony and bismuth derived from xanthate, dithiocarbamate and phosphorus based ligands have been reviewed in this paper.
117 citations
Journal Article•
TL;DR: Some salient features of platinum group metal compounds with sulfur, selenium or tellurium, known as chalcogenides, primarily focusing on binary compounds, are described in this article.
Abstract: Some salient features of platinum group metal compounds with sulfur, selenium or tellurium, known as chalcogenides, primarily focusing on binary compounds, are described here. Their structural patterns are rationalised interms of common structural systems. Some applications of these compounds in catalysis and materials science are described, and emerging trends in designing molecular precursors, for the syntheses of these materials are highlighted.
115 citations
TL;DR: In this paper, the crystal structure determination of the compound {nBu2Sn(2-pic)]2O}2 has revealed the presence of two distinct tin atom geometrics in the dicarboxylato tetraorganostannoxane structure.
110 citations
TL;DR: In this paper, the synthesis of both mono-and di-chalcogenides of 2-, 3- and 4-pyridyl and 2-pyrimidyl groups, their spectroscopic and structural studies are discussed.
103 citations
Cited by
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01 Feb 1995
TL;DR: In this paper, the unpolarized absorption and circular dichroism spectra of the fundamental vibrational transitions of the chiral molecule, 4-methyl-2-oxetanone, are calculated ab initio using DFT, MP2, and SCF methodologies and a 5S4P2D/3S2P (TZ2P) basis set.
Abstract: : The unpolarized absorption and circular dichroism spectra of the fundamental vibrational transitions of the chiral molecule, 4-methyl-2-oxetanone, are calculated ab initio. Harmonic force fields are obtained using Density Functional Theory (DFT), MP2, and SCF methodologies and a 5S4P2D/3S2P (TZ2P) basis set. DFT calculations use the Local Spin Density Approximation (LSDA), BLYP, and Becke3LYP (B3LYP) density functionals. Mid-IR spectra predicted using LSDA, BLYP, and B3LYP force fields are of significantly different quality, the B3LYP force field yielding spectra in clearly superior, and overall excellent, agreement with experiment. The MP2 force field yields spectra in slightly worse agreement with experiment than the B3LYP force field. The SCF force field yields spectra in poor agreement with experiment.The basis set dependence of B3LYP force fields is also explored: the 6-31G* and TZ2P basis sets give very similar results while the 3-21G basis set yields spectra in substantially worse agreements with experiment. jg
1,652 citations
1,366 citations
01 Sep 2010
TL;DR: In this paper, the selection of the best choice of reaction conditions and ligand of this class for the most commonly encountered and practically important substrate combinations for Pd-catalyzed amination reactions is discussed.
Abstract: Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions and have been applied in a range of contexts. This perspective attempts to aid the reader in the selection of the best choice of reaction conditions and ligand of this class for the most commonly encountered and practically important substrate combinations.
966 citations
764 citations