V
Vincent Robert
Researcher at École normale supérieure de Lyon
Publications - 72
Citations - 1436
Vincent Robert is an academic researcher from École normale supérieure de Lyon. The author has contributed to research in topics: Ab initio & Molecular orbital. The author has an hindex of 22, co-authored 64 publications receiving 1349 citations. Previous affiliations of Vincent Robert include University of Lyon & University of Strasbourg.
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Journal ArticleDOI
Cubane Variations: Syntheses, Structures, and Magnetic Property Analyses of Lanthanide(III)−Copper(II) Architectures with Controlled Nuclearities ‖
Christophe Aronica,Guillaume Chastanet,Guillaume Pilet,Boris Le Guennic,Vincent Robert,Wolfgang Wernsdorfer,Dominique Luneau +6 more
TL;DR: It is suggested that the electronic distribution on the yttrium(III) ion may influence the magnetic interaction between the copper(II) pairs and contribute to improve the SMM synthesis strategy on the basis of the association of 3d and 4f ions.
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Primary role of the electrostatic contributions in a rational growth of hysteresis loop in spin-crossover Fe(II) complexes.
TL;DR: This work reports a comprehensive analysis of the hysteresis behavior in a series of well-characterized spin-crossover Fe(II) materials and suggests that the electrostatic contributions significantly enhance the cooperativity factor while weak bonds are determinant in the structuration of the 3D networks.
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What zeroth-order Hamiltonian for CASPT2 adiabatic energetics of Fe(II)N6 architectures?
TL;DR: It is concluded that the commonly applied IPEA shift value is not satisfactory to properly discriminate the open-shell HS and closed-shell LS states and suggests that a 0.50-0.70 a.u. value would be preferable for these specific adiabatic gap calculations.
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Energetics of [Fe(NCH)6]2+ via CASPT2 calculations: a spin-crossover perspective.
TL;DR: It is concluded that a balanced description of the Fe 7s6p5d3f2g1h and N 4s3p1d partners is needed to reach convergence upon the potential energy surface descriptions and it is shown that the so‐called d′ orbitals allow for a significant charge redistribution along the transition.
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Inspection of the duality of a verdazyl-based radical in transition metal complexes: a pi* donor ligand and a magnetic partner.
TL;DR: It is concluded that the noninnocent nature of the imvd(o) radical is held by the verdazyl ring part, and dynamical correlation effects are introduced to quantitatively recover the exchange interaction in this compound.