Vincent Vivier

Bio: Vincent Vivier is an academic researcher from University of Paris. The author has contributed to research in topics: Dielectric spectroscopy & Corrosion. The author has an hindex of 40, co-authored 194 publications receiving 8172 citations. Previous affiliations of Vincent Vivier include University of Florida & Pierre-and-Marie-Curie University.

Electrochemical Impedance Spectroscopy

Abstract: Electrochemical impedance spectroscopy (EIS) is a powerful tool to investigate properties of materials and electrode reactions. This Primer provides a guide to the use of EIS with a comparison to other electrochemical techniques. The analysis of impedance data for reduction of ferricyanide in a KCl supporting electrolyte is used to demonstrate the error structure for impedance measurements, the use of measurement and process models, as well as the sensitivity of impedance to the evolution of electrode properties. This Primer provides guidelines for experimental design, discusses the relevance of accuracy contour plots to wiring and instrumentation selection, and emphasizes the importance of the Kramers-Kronig relations to data validation and analysis. Applications of EIS to battery performance, metal and alloy corrosion, and electrochemical biosensors are highlighted. Electrochemical impedance measurements depend on both the mechanism under investigation and extrinsic parameters, such as the electrode geometry. Experimental complications are discussed, including the influence of nonstationary behaviour at low frequencies and the need for reference electrodes. Finally, emerging trends in experimental and interpretation approaches are also described.

Constant-Phase-Element Behavior Caused by Resistivity Distributions in Films I. Theory

Abstract: I. Theory Bryan Hirschorn,* Mark E. Orazem,** Bernard Tribollet,** Vincent Vivier,*** Isabelle Frateur, and Marco Musiani*** Department of Chemical Engineering, University of Florida, Gainesville, Florida 32611, USA Laboratoire Interfaces et Systemes Electrochimiques, UPR 15 du CNRS, Université Pierre et Marie Curie, 75252 Paris cedex 05, France Laboratoire de Physico-Chimie des Surfaces, UMR CNRS-ENSCP 7045, Ecole Nationale Supérieure de Chimie de Paris, Chimie ParisTech, 75005 Paris, France Istituto per l’Energetica e le Interfasi, Consiglio Nazionale delle Ricerche, 35127 Padova, Italy

Dielectric Properties of Materials Showing Constant-Phase-Element (CPE) Impedance Response

Abstract: Constant-Phase Elements (CPE) are often used to fit impedance data arising from a broad range of experimental systems. Four approaches were used to interpret CPE parameters associated with the impedance response of human skin and two metal oxides in terms of characteristic frequencies and film thickness. The values obtained with each approach were compared against independent measurements. The power-law model developed recently by Hirschorn et al.1,2 provided the most reliable interpretation for systems with a normal distribution of properties. Readers are cautioned that the CPE parameter Q does not provide an accurate value for capacitance, even when the CPE exponent α is greater than 0.9.

An Impedance Investigation of the Mechanism of Pure Magnesium Corrosion in Sodium Sulfate Solutions

Abstract: The corrosion behavior of pure magnesium in sodium sulfate solutions was investigated using voltammetry and electrochemical impedance spectroscopy with a rotating disk electrode The analysis of impedance data obtained at the corrosion potential was consistent with the hypothesis that Mg corrosion is controlled by the presence of a very thin oxide film, probably MgO, and that the dissolution occurs at film-free spots only This hypothesis was substantiated both by the superposition of the EIS diagrams, obtained for different immersion times and for two Na2SO4 concentrations once normalized, and by use of scanning electrochemical microscopy in the ac mode to sense the local conductivity of the material On the basis of the electrochemical results, a model was proposed to describe magnesium corrosion at the open-circuit potential Simulation of the impedance diagrams was in good agreement with the experimental results

Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction

Abstract: Objective evaluation of the activity of electrocatalysts for water oxidation is of fundamental importance for the development of promising energy conversion technologies including integrated solar water-splitting devices, water electrolyzers, and Li-air batteries. However, current methods employed to evaluate oxygen-evolving catalysts are not standardized, making it difficult to compare the activity and stability of these materials. We report a protocol for evaluating the activity, stability, and Faradaic efficiency of electrodeposited oxygen-evolving electrocatalysts. In particular, we focus on methods for determining electrochemically active surface area and measuring electrocatalytic activity and stability under conditions relevant to an integrated solar water-splitting device. Our primary figure of merit is the overpotential required to achieve a current density of 10 mA cm–2 per geometric area, approximately the current density expected for a 10% efficient solar-to-fuels conversion device. Utilizing ...

Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process

Abstract: Atomic layer deposition(ALD), a chemical vapor deposition technique based on sequential self-terminating gas–solid reactions, has for about four decades been applied for manufacturing conformal inorganic material layers with thickness down to the nanometer range. Despite the numerous successful applications of material growth by ALD, many physicochemical processes that control ALD growth are not yet sufficiently understood. To increase understanding of ALD processes, overviews are needed not only of the existing ALD processes and their applications, but also of the knowledge of the surface chemistry of specific ALD processes. This work aims to start the overviews on specific ALD processes by reviewing the experimental information available on the surface chemistry of the trimethylaluminum/water process. This process is generally known as a rather ideal ALD process, and plenty of information is available on its surface chemistry. This in-depth summary of the surface chemistry of one representative ALD process aims also to provide a view on the current status of understanding the surface chemistry of ALD, in general. The review starts by describing the basic characteristics of ALD, discussing the history of ALD—including the question who made the first ALD experiments—and giving an overview of the two-reactant ALD processes investigated to date. Second, the basic concepts related to the surface chemistry of ALD are described from a generic viewpoint applicable to all ALD processes based on compound reactants. This description includes physicochemical requirements for self-terminating reactions,reaction kinetics, typical chemisorption mechanisms, factors causing saturation, reasons for growth of less than a monolayer per cycle, effect of the temperature and number of cycles on the growth per cycle (GPC), and the growth mode. A comparison is made of three models available for estimating the sterically allowed value of GPC in ALD. Third, the experimental information on the surface chemistry in the trimethylaluminum/water ALD process are reviewed using the concepts developed in the second part of this review. The results are reviewed critically, with an aim to combine the information obtained in different types of investigations, such as growth experiments on flat substrates and reaction chemistry investigation on high-surface-area materials. Although the surface chemistry of the trimethylaluminum/water ALD process is rather well understood, systematic investigations of the reaction kinetics and the growth mode on different substrates are still missing. The last part of the review is devoted to discussing issues which may hamper surface chemistry investigations of ALD, such as problematic historical assumptions, nonstandard terminology, and the effect of experimental conditions on the surface chemistry of ALD. I hope that this review can help the newcomer get acquainted with the exciting and challenging field of surface chemistry of ALD and can serve as a useful guide for the specialist towards the fifth decade of ALD research.

Electrochemical Impedance Spectroscopy

Abstract: This review describes recent advances in electrochemical impedance spectroscopy (EIS) with an emphasis on its novel applications to various electrochemistry-related problems. Section 1 discusses the development of new EIS techniques to reduce measurement time. For this purpose, various forms of multisine EIS techniques were first developed via a noise signal synthesized by mixing ac waves of various frequencies, followed by fast Fourier transform of the signal and the resulting current. Subsequently, an entirely new concept was introduced in which true white noise was used as an excitation source, followed by Fourier transform of both excitation and response signals. Section 2 describes novel applications of the newly developed techniques to time-resolved impedance measurements as well as to impedance imaging. Section 3 is devoted to recent applications of EIS techniques, specifically traditional measurements in various fields with a special emphasis on biosensor detections.