Author
W.R. Walker
Bio: W.R. Walker is an academic researcher from Duquesne University. The author has contributed to research in topics: Hexafluoroacetylacetone & Stability constants of complexes. The author has an hindex of 4, co-authored 5 publications receiving 180 citations.
Papers
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TL;DR: Spectrophotometric studies in the visible region have been made on benzene solutions of Cu(chelate)2 with increasing amounts of 4-methyl-pyridine (4-me-py) as discussed by the authors.
60 citations
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TL;DR: In this article, the authors used the phosphorus nuclear magnetic resonance method to determine the equilibrium constant of the reaction Zn(TTA)2 (org.) + TOPO (org.), which was found to be approximately 10 1/mole in anhydrous carbon tetrachloride medium.
51 citations
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TL;DR: Some ternary complexes of the type M(chelate) 2 S x [M = TBP (tri-n-butyl phosphate), TBEP (trin-nbutoxyethyl phosphate), TOPO (tri n-octyl phosphine oxide), 4-me-py (4-methyl pyridine), TPPO(tri-phenyl-phosphine oxide)] have been prepared and investigated as discussed by the authors.
46 citations
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TL;DR: In this article, it is suggested that the term "antisynergism" is a misnomer, in that the phenomenon is merely the destruction of synergism, and that synergism involves both the stability and solubility of binary and ternary complexes.
22 citations
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1 citations
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192 citations
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TL;DR: In this article, der Ubersichtsartikel befast sich mit der Darstellung, der Rontgenstrukturanalyse und den spektroskopischen Eigenschaften von uber 80 Metallchelaten von fluorierten 1,3-Diketonen.
147 citations
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85 citations
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TL;DR: In this paper, the formation of an adduct with the undissociated chelating acid was observed at high ligand concentrations M 3 + (aq) + 4 Ha (org) ⇌ MA 3 HA(org) + 3 HA + 3 H+ (aq), where HA denotes the neutral, adduct-forming ligand.
73 citations