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Wenchao Wu
Researcher at Jiangsu Normal University
Publications - 3
Citations - 23
Wenchao Wu is an academic researcher from Jiangsu Normal University. The author has contributed to research in topics: Catalysis & Lewis acids and bases. The author has an hindex of 1, co-authored 3 publications receiving 6 citations.
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A combined experimental and computational study of NHC-promoted desulfonylation of tosylated aldimines
Fang Sun,Tingrui Yin,Yang Wang,Anni Feng,Liuqing Yang,Wenchao Wu,Chenxia Yu,Tuanjie Li,Donghui Wei,Changsheng Yao +9 more
TL;DR: DFT calculations demonstrate that the reaction undergoes multiple stepwise processes including nucleophilic addition of NHC to tosylated imine, formation of an aza-Breslow intermediate, deprotonation, and dissociation of the tosyl group.
Journal ArticleDOI
NHC-catalyzed β-specific addition of N-based nucleophiles to allenoates
Wenchao Wu,Shuangli Xu,Yan Zhang,Xiu Wang,Ruotong Li,Fang Sun,Chenxia Yu,Tuanjie Li,Donghui Wei,Changsheng Yao +9 more
TL;DR: DFT calculations on the possible reaction mechanisms show that the β-add addition pathway is more energetically favourable than the γ-addition pathway, which is in agreement with the experimental observations.
Journal ArticleDOI
A combined experimental and computational study of NHC-catalyzed allylation of allenoate with MBH esters: new regiospecific and stereoselective access to 1,5-enyne
Jens Schlieter,Fang Sun,Xochitl Sandoval López,Fangfang Lu,Xue Song,Wenchao Wu,Kai Zhang,Chenxia Yu,Tuanjie Li,Donghui Wei,Changsheng Yao +10 more
TL;DR: An NHC-catalyzed regiospecific allylation of α-substituted allenoates with MBH carbonates derived from aryl aldehyde furnished highly functionalized 1,5-enynes bearing a quaternary carbon successfully as discussed by the authors.