William Cunha Brandt

Bio: William Cunha Brandt is an academic researcher from University of South Africa. The author has contributed to research in topics: Bond strength & Knoop hardness test. The author has an hindex of 16, co-authored 65 publications receiving 663 citations. Previous affiliations of William Cunha Brandt include State University of Campinas.

Effect of different photo-initiators and light curing units on degree of conversion of composites

Abstract: The aim of this study was to evaluate: (i) the absorption of photo-initiators and emission spectra of light curing units (LCUs); and (ii) the degree of conversion (DC) of experimental composites formulated with different photo-initiators when activated by different LCUs. Blends of BisGMA, UDMA, BisEMA and TEGDMA with camphorquinone (CQ) and/ or 1-phenyl-1,2-propanedione (PPD) were prepared. Dimethylaminoethyl methacrylate (DMAEMA) was used as co-initiator. Each mixture was loaded with 65 wt% of silanated filler particles. One quartz-tungsten-halogen - QTH (XL 2500, 3M/ESPE) and two lightemitting diode (LED) LCUs (UltraBlue IS, DMC and UltraLume LED 5, Ultradent) were used for activation procedures. Irradiance (mW/cm²) was calculated by the ratio of the output power by the area of the tip, and spectral distribution with a spectrometer (USB 2000). The absorption curve of each photo-initiator was determined using a spectrophotometer (Varian Cary 5G). DC was assessed by Fourier transformed infrared spectroscopy. Data were submitted to two-way ANOVA and Tukey's test (5%). No significant difference was found for DC values when using LED LCUs regardless of the photo-initiator type. However, PPD showed significantly lower DC values than composites with CQ when irradiated with QTH. PPD produced DC values similar to those of CQ, but it was dependent on the LCU type.

In vitro toothbrushing abrasion of dental resin composites: packable, microhybrid, nanohybrid and microfilled materials

Abstract: This study evaluated weight loss and surface roughening after toothbrushing of different resin composites: one packable (Solitaire 2, Heraeus Kulzer), one microhybrid (Charisma, Heraeus Kulzer), one nanohybrid (Simile, Pentron) and one microfilled (Durafill VS, Heraeus Kulzer). Cylindrical specimens (n = 20) were prepared. Half of the samples were submitted to 60,000 strokes, at 4 Hz, with a dentifrice-water slurry. Control samples (n = 10) remained stored at 37 degrees C. Pre- and post-abrasion parameters for weight (mg) and surface roughness (Ra, microm) were determined on an analytical balance and a surface profilometer. Data were separately submitted to Repeated Measures ANOVA and Tukey's test (a = 0.05). Percentages of weight loss were analyzed by ANOVA and Tukey's test (a = 0.05). The relationship between both evaluations was assessed by Pearson's test (a = 0.05). The means (%) for weight loss (standard deviation) were 0.65(0.2), 0.93(0.2), 1.25(0.6) and 1.25(0.4) for Simile, Durafill, Charisma and Solitaire, respectively. Baseline roughness means ranged from 0.065(0.01), 0.071(0.01), 0.066(0.02) and 0.074(0.01) for Simile, Durafill, Charisma and Solitaire, respectively, to 0.105(0.04), 0.117(0.03), 0.161(0.03) and 0.214(0.07) after testing. The composites with larger fillers presented higher weight loss and roughening than the finer materials (p < 0.05). For both evaluations, control specimens showed no significant alteration. No significant relationship between loss of weight and roughness alteration was detected (r = 0.322, p = 0.429).

Light- and time-dependent polymerization of dual-cured resin luting agent beneath ceramic.

Abstract: Objective. In this study we investigated the degree of conversion (DC) of a dual-cured resin luting agent beneath a ceramic of different thickness. Material and Methods. The luting material (RelyX) was photo-activated for 40 s through ceramic disks (Empress Esthetic, 0.7, 1.4, or 2 mm thick). Dual (DUC) and chemically cured (CC) control groups were obtained. A delayed exposure (DE) procedure was tested in which the material was light-activated after 5 min without using ceramic. DC (%) was measured using infrared spectroscopy at 40 s, 1, 2, 4, 6, 8, and 10 min. Light irradiance and spectrum transmitted through ceramic were measured using a power meter and a spectrometer. Results. A decrease in irradiance was detected with increasing ceramic thickness, but no alteration in the emission profile was observed. At 10 min, all groups showed DC higher than at 40 s. No significant differences were detected for DUC compared with the groups indirectly activated through the ceramic disks. Generally, CC showed the lowest DC values. No significant effect in DC was detected for DE after 10 min. A significant increase in DC was generally detected only up to 4 min. Conclusions. The luting agent was dependent on light exposure and time to obtain improved DC. Neither the indirect activation nor the DE procedure significantly influenced the final DC.

Stability of external and internal implant connections after a fatigue test.

Abstract: Objective: The objective of this study was to compare the torque and detorque values of screw intermediates of external hexagon, internal hexagon, and Morse taper implants in single restorations before and after mechanical cycling. Materials and Methods: The study sample was divided into three groups ( n = 10) as follows: group EH - external hexagon implant, group IH - internal hexagon implant, and group MT - Morse taper implant. Universal abutments were screwed on the implants, and metal crowns were cemented onto the abutment. The samples were submitted to a mechanical testing of 1 million cycles, with a frequency of 8 cycles per second under a 400 N load. The application and registration of the screw torque (T0) and detorque (T1) values of the intermediate were performed before and after the test. The results were statistically evaluated by analysis of variance (ANOVA) and Tukey's test (α = 0.05). Results: There was no difference between the values of T0 and T1 in the intra-group samples. However, the inter-group difference in T0 between the EH (12.8 N cm) and MT (18.6 N cm) groups and in T1 between the EH (10.4 N cm) and IH (13.8 N cm), EH and MT (19.4 N cm), and MT and IH ( P = 0.001) groups were significant. The MT group showed a lower variation of T0 and T1. Conclusion: The internal implants, particularly MT, showed better stability in these cases when used for single restorations.

Nanohybrid Resin Composites: Nanofiller Loaded Materials or Traditional Microhybrid Resins?

Abstract: Clinical Relevance Under clinical conditions, nanohybrid resin composites may not perform comparable to nanofilled materials.