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William J. Bland
Publications - 5
Citations - 109
William J. Bland is an academic researcher. The author has contributed to research in topics: Addition reaction & Reaction intermediate. The author has an hindex of 5, co-authored 5 publications receiving 108 citations.
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The mechanism of the addition of haloalkanes to alkenes in the presence of dichlorotris(triphenylphosphine)ruthenium(II), [RuCl2(PPh3)3]
TL;DR: In this paper, the addition of haloalkanes to alkenes in the presence of [RuCl 2 (PPh 3 ) 3 ] has been subjected to a detailed kinetic study.
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The mechanism of the addition of tetrahaloalkanes to alkenes in the presence of RuCl2(PPh3)3
TL;DR: In this article, the addition of tetrahaloalkanes to alkenes in the presence of [RuCl2(PPh3)3] has been examined in detail and it is suggested that it proceeds by a non-chain catalysed mechanism involving free radical intermediates.
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The mechanism of the addition of haloalkanes to alkenes in the presence of tricarbonyl-η6-naphthalenechromium(0), [Cr(CO)3(η6-C10H8)]
TL;DR: In this article, a detailed kinetic study of the oct-1-ene was conducted and the results when taken with an examination of reaction intermediates suggest a mechanism involving a non-chain sequence in which [Cr(CO) 3 (η-C 10 H 8 )] acts as a catalyst, but which involves free radical intermediates.
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The mechanism of the addition of tetrachloromethane to alkenes in the presence of [Cr(CO)3(η6-C10H8)]
TL;DR: In this paper, the title reaction has been examined in detail and is shown to proceed via a non-chain catalysed mechanism involving free radical intermediates, which is based on the same approach as in this paper.
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Complex formation between benzene and [Cr(CO)3(η6-arene)]
TL;DR: The 1.1/1 complex formation between benzene d 6 and [Cr(CO) 3 (η 6 -arene)] (arene = C 6 H 5 R (R = H, Me, OMe, Cl), C 10 H 8 ) has been observed by PMR spectroscopy.