Analytical data for Sr, Rb, Cs, Ba, Pb, rare earth elements, Y, Th, U, Zr, Hf, Sn, Nb, Mo, Ni, Co, V, Cr, Sc, Cu and major elements are reported for eocene volcanic rocks cropping out in the Kastamonu area, Pontic chain of Northern Turkey. SiO2% versus K2O% relationship shows that the analyzed samples belong to two major groups: the basaltic andesitic and the andesitic ones. High-K basaltic andesites and low-K andesites occur too. Although emplaced on continental type basement (the North Anatolian Crystalline Swell), the Pontic eocene volcanics show elemental abundances closely comparable with typical island arc calc-alkaline suites, e.g. low SiO2% range, low to moderate K2O% and large cations (Cs, Rb, Sr, Ba, Pb) contents and REE patterns with fractionated light and almost flat heavy REE patterns. ΣREE and highly charged cations (Th, U, Hf, Sn, Zr) are slightly higher than typical calc-alkaline values. Ferromagnesian elements show variable values. Within the basaltic andesite group the increase of K%, large cations, ΣREE, La/Yb ratio and high valency cations and the decrease of ferromagnesian element abundances with increasing SiO2% content indicate that the rock types making up this group developed by crystalliquid fractionation of olivine and clinopyroxene from a basic parent magma. Trace element concentration suggest that the andesite group was not derived by crystal-liquid fractionation processes from the basaltic andesites, but could represent a distinct group of rocks derived from a different parent magma.

Geochemistry of eocene calc-alkaline volcanic rocks from the Kastamonu area, Northern Turkey

Tectonic setting of basic volcanic rocks determined using trace element analyses

This geochemical classification of granitic rocks is based upon three INTRODUCTION variables. These are FeO/(FeO + MgO) = Fe-number [or Although granitoids are the most abundant rock types FeO/(FeO + MgO) = Fe∗], the modified alkali–lime index in the continental crust, no single classification scheme (MALI) (Na2O + K2O – CaO) and the aluminum saturation has achieved widespread use. Part of the problem in index (ASI) [Al/(Ca – 1·67P + Na + K)]. The Fe-number granite classification is that the same mineral assemblage, (or Fe∗) distinguishes ferroan granitoids, which manifest strong iron quartz and feldspars with a variety of ferromagnesian enrichment, from magnesian granitoids, which do not. The ferroan minerals, can be achieved by a number of processes. and magnesian granitoids can further be classified into alkalic, Granitoids can form from differentiation of any hyalkali–calcic, calc-alkalic, and calcic on the basis of the MALI persthene-normative melt and from partial melting of and subdivided on the basis of the ASI into peraluminous, metamany rock types. Furthermore, granitic melts may be luminous or peralkaline. Because alkalic rocks are not likely to be derived solely from crustal components, may form from peraluminous and calcic and calc-alkalic rocks are not likely to be evolved mantle-derived melts, or may be a mixture peralkaline, this classification leads to 16 possible groups of granitic of crustal and mantle-derived melts. Because of this rocks. In this classification most Cordilleran granitoids are magnesian complexity, petrologists have relied upon geochemical and calc-alkalic or calcic; both metaluminous and peraluminous classifications to distinguish between various types of types are present. A-type granitoids are ferroan alkali–calcic, although granitoids. Approximately 20 different schemes have evolved over the past 30 years [see Barbarin (1990, 1999) some are ferroan alkalic. Most are metaluminous although some are for a summary thereof]. Most of these schemes are either peraluminous. Caledonian post-orogenic granites are predominantly genetic or tectonic in nature. This paper is an attempt magnesian alkali–calcic. Those with <70 wt % SiO2 are domto present a non-genetic, non-tectonic geochemical clasinantly metaluminous, whereas more silica-rich varieties are comsification scheme that incorporates the best qualities of monly peraluminous. Peraluminous leucogranites may be either the previous schemes, and to explain the petrologic magnesian or ferroan and have a MALI that ranges from calcic to processes that makes this scheme work. alkalic.

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A geochemical classification for granitic rocks

Tethyan evolution of Turkey: A plate tectonic approach

The graywackes of Paleozoic turbidite sequences of eastern Australia show a large variation in their trace element characteristics, which reflect distinct provenance types and tectonic settings for various suites. The tectonic settings recognised are oceanic island arc, continental island arc, active continental margin, and passive margins. Immobile trace elements, e.g. La, Ce, Nd, Th, Zr, Nb, Y, Sc and Co are very useful in tectonic setting discrimination. In general, there is a systematic increase in light rare earth elements (La, Ce, Nd), Th, Nb and the Ba/Sr, Rb/Sr, La/Y and Ni/Co ratios and a decrease in V, Sc and the Ba/Rb, K/Th and K/U ratios in graywackes from oceanic island arc to continental island arc to active continental margin to passive margin settings. On the basis of graywacke geochemistry, the optimum discrimination of the tectonic settings of sedimentary basins is achieved by La-Th, La-Th-Sc, Ti/Zr-La/Sc, La/Y-Sc/Cr, Th-Sc-Zr/10 and Th-Co-Zr/10 plots. The analysed oceanic island arc graywackes are characterised by extremely low abundances of La, Th, U, Zr, Nb; low Th/U and high La/Sc, La/Th, Ti/Zr, Zr/Th ratios. The studied graywackes of the continental island arc type setting are characterised by increased abundances of La, Th, U, Zr and Nb, and can be identified by the La-Th-Sc and La/Sc versus Ti/Zr plots. Active continental margin and passive margin graywackes are discriminated by the Th-Sc-Zr/10 and Th-Co-Zr/10 plots and associated parameters (e.g. Th/Zr, Th/Sc). The most important characteristic of the analysed passive margin type graywackes is the increased abundance of Zr, high Zr/Th and lower Ba, Rb, Sr and Ti/Zr ratio compared to the active continental margin graywackes.

Trace element characteristics of graywackes and tectonic setting discrimination of sedimentary basins

Detrital framework modes of sandstone suites from different kinds of basins are a function of provenance types governed by plate tectonics. Quartzose sands from continental cratons are widespread within interior basins, platform successions, miogeoclinal wedges, and opening ocean basins. Arkosic sands from uplifted basement blocks are present locally in rift troughs and in wrench basins related to transform ruptures. Volcaniclastic lithic sands and more complex volcano-plutonic sands derived from magmatic arcs are present in trenches, forearc basins, and marginal seas. Recycled orogenic sands, rich in quartz or chert plus other lithic fragments and derived from subduction complexes, collision orogens, and foreland uplifts, are present in closing ocean basins, diverse succ ssor basins, and foreland basins. Triangular diagrams showing framework proportions of quartz, the two feldspars, polycrystalline quartzose lithics, and unstable lithics of volcanic and sedimentary parentage successfully distinguish the key provenance types. Relations between provenance and basin are important for hydrocarbon exploration because sand frameworks of contrasting detrital compositions respond differently to diagenesis, and thus display different trends of porosity reduction with depth of burial.

Plate tectonics and sandstone compositions

Detrital modes of sandstone suites primarily reflect the different tectonic settings of provenance terranes, although various other sedimentological factors also influence sandstone compositions. Comparisons of sandstone compositions are aided by grouping diverse grain types into a few operational categories having broad genetic significance. Compositional fields associated with different provenances can then be displayed on standard triangular diagrams.

Interpreting Provenance Relations from Detrital Modes of Sandstones

The determination of detrital modes in graywackes and arkoses, here grouped as subquartzose sandstones, requires special attention to the identification of detrital grain types, as defined operationally, and to the recognition of detrital textures, as opposed to textural elements of diagenetic origin. Accurate detrital modes can yield specific information on provenance that can be gained in no other way. Reserving the terms graywacke and arkose for imprecise field descriptions and abandoning the proportion of matrix as a prime means of classification, subquartzose sandstones can be described adequately using six numerical grain parameters. Three primary parameters summing to 100 permit quantitative serial designation of rock types in the form QxFyLz, w ere Q is total quartzose grains, F is total feldspar grains, and L is total unstable lithic fragments in the framework. Three secondary parameters in the form of ratios permit desirable refinement within each primary parameter: C/Q where C is total polycrystalline quartzose grains, P/F where P is total plagioclase grains, and V/L where V is total volcanic lithic grains. Stable grains, whose sum is the parameter Q, are essentially pure silica in mineralogy, and include both monacrystalline quartz and polycrystalline lithic fragments. The latter are gradational to less quartzose types and difficult to distinguish from felsite grains, which display relict textures of volcanic origin and internal relief owing to their polyminerallic nature. Lithic fragments are subdivided at two levels into our main categories within which are various subcategories: (a) volcanic fragments include felsitic, microlitic, lathwork, and vitric types; (b) clastic fragments include silty-sandy and argillaceous types; (c) tectonite fragments include metasedimentary quartzose types and metavolcanic feldspathic or ferromagnesian types; and (d) microgranular fragments include hypabyssal, hornfelsic, and indurated sedimentary types. Interstitial materials include (a) exotic cements like calcite or zeolite; (b) homogeneous, monominerallic phyllosilicate cement displaying textures indicative of porefilling; (c) clayey detrital lutum called protomatrix; (d) recrystallized lutum or protomatrix called orthomatrix with relict detrital texture| (e) murky, polyminerallic, diagenetic pore-filling called epimatr x, whose growth is accompanied by alteration of framework grains; and (f) deformed and recrystallized lithic fragments called pseudomatrix. Extensive albitization and other alterations complicate the interpretation of detrital modes in many rocks, but potential errors commonly can be avoided by close attention to mineralogy and relict texture except where tectonite fabrics disrupt or transpose the original detrital framework. Most subquartzose sandstones were derived from one. or a mixture, of three salient provenance types: (a) volcanic terranes, yielding feldspatholithic rocks nearly free of quartz, (b) plutonic terranes, yielding feldspathic rocks with few lithic fragments, and (c) uplifted sedimentary and metasedimentary "tectonic" terranes, yielding "chert-grain" lithic rocks with f w quartz and feldspar grains except where recycled volcanic or plutonic detritus is abundant. Many voluminous accumulations of subquartzose sandstones near continental margins had as their provenance complex volcano-plutonic orogens representing ancient magmatic arcs analogous to modern arcs associated with trenches.

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Interpreting detrital modes of graywacke and arkose

Plate tectonics of the Laramide orogeny

▪ Abstract The Cordilleran orogen of western North America is a segment of the Circum-Pacific orogenic belt where subduction of oceanic lithosphere has been underway along a great circle of the globe since breakup of the supercontinent Pangea began in Triassic time. Early stages of Cordilleran evolution involved Neoproterozoic rifting of the supercontinent Rodinia to trigger miogeoclinal sedimentation along a passive continental margin until Late Devonian time, and overthrusting of oceanic allochthons across the miogeoclinal belt from Late Devonian to Early Triassic time. Subsequent evolution of the Cordilleran arc-trench system was punctuated by tectonic accretion of intraoceanic island arcs that further expanded the Cordilleran continental margin during mid-Mesozoic time, and later produced a Cretaceous batholith belt along the Cordilleran trend. Cenozoic interaction with intra-Pacific seafloor spreading systems fostered transform faulting along the Cordilleran continental margin and promoted incipient ...

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William R. Dickinson

Papers

Plate tectonics and sandstone compositions

Interpreting Provenance Relations from Detrital Modes of Sandstones

Interpreting detrital modes of graywacke and arkose

Plate tectonics of the Laramide orogeny

Evolution of the north american cordillera