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Author

Wladimir Marine

Other affiliations: Aix-Marseille University
Bio: Wladimir Marine is an academic researcher from Centre national de la recherche scientifique. The author has contributed to research in topics: Laser ablation & Laser. The author has an hindex of 31, co-authored 127 publications receiving 3261 citations. Previous affiliations of Wladimir Marine include Aix-Marseille University.


Papers
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Journal ArticleDOI
TL;DR: In this article, a photoluminescence study of silicon nanoclusters produced by laser ablation was conducted and it was found that by varying the preparation parameters it was possible to change the mean cluster size in the range 1-5 nm.
Abstract: We report a photoluminescence study of silicon nanoclusters produced by laser ablation. It was found that by varying the preparation parameters it was possible to change the mean cluster size in the range 1–5 nm. Within this size variation, the photoluminescence band shifts in a wide spectral region from near ultraviolet to near infrared. This size-dependent photoluminescence of Si nanoclusters is consistent with a quantum confinement effect. The observed influence of cluster oxidation on the luminescence properties also supports the quantum confinement interpretation. We proposed a discrete size model which supposes that the spectral position of the luminescence band is essentially determined by the volume of clusters with a complete outer atomic layer. In the framework of this model, we were able to deconvolute the observed luminescence bands into a set of fixed Gaussian bands. The model is supported by the observation of a size selective doping of Si nanoclusters whose effect was well explained by Auger recombination. Finally, our model allowed us to obtain a dependence of the optical gap on the cluster size which is in good agreement with existing calculations of Si nanocrystal electronic structure.

211 citations

Journal ArticleDOI
TL;DR: In this article, the basic principles of nanoparticle synthesis by conventional pulsed laser ablation are described and the theoretical development and analysis of the experimental results are given for condensation, expansion and properties of silicon nanoclusters.

188 citations

Journal ArticleDOI
TL;DR: In this article, the results on cemented tungsten carbide and on titanium carbonitride are reported for the first time and compared with outcomes of investigations on diamond and titanium nitride.
Abstract: Several ultrahard materials and coatings of definite interest for tribological applications were tested with respect to their response when irradiated with fs laser pulses. Results on cemented tungsten carbide and on titanium carbonitride are reported for the first time and compared with outcomes of investigations on diamond and titanium nitride. The experiments were carried out in air, in a regime of 5–8 J/cm2 fluences, using the beam of a commercial Ti:sapphire laser. The changes induced in the surface morphology were analysed with a Nomarski optical microscope, and with SEM and AFM techniques. From the experimental data and from the calculated incident energy density distributions, the damage and ablation threshold values were determined. As expected, the diamond showed the highest threshold, while the cemented tungsten carbide exhibited typical values for metallic surfaces. The ablation rates determined (under the above-mentioned experimental conditions) were in the range 0.1–0.2 μm per pulse for all the materials investigated.

173 citations

Journal ArticleDOI
TL;DR: In this paper, a drift-diffusion-based model is proposed to describe the dynamics of electronic excitation, heating, and charge-carrier transport in different materials (metals, semiconductors, and dielectrics) under femtosecond and nanosecond pulsed laser irradiation.
Abstract: We present a continuum model, based on a drift-diffusion approach, aimed at describing the dynamics of electronic excitation, heating, and charge-carrier transport in different materials (metals, semiconductors, and dielectrics) under femtosecond and nanosecond pulsed laser irradiation. The laser-induced charging of the targets is investigated at laser intensities above the material removal threshold. It is demonstrated that, for near-infrared femtosecond irradiation, charging of dielectric surfaces causes a sub-picosecond electrostatic rupture of the superficial layers, alternatively called Coulomb explosion (CE), while this effect is strongly inhibited for metals and semiconductors as a consequence of superior carrier transport properties. On the other hand, application of the model to UV nanosecond pulsed laser interaction with bulk silicon has pointed out the possibility of Coulomb explosion in semiconductors. For such regimes a simple analytical theory for the threshold laser fluence of CE has been developed, showing results in agreement with the experimental observations. Various related aspects concerning the possibility of CE depending on different irradiation parameters (fluence, wavelength and pulse duration) and material properties are discussed. This includes the temporal and spatial dynamics of charge-carrier generation in non-metallic targets and evolution of the reflection and absorption characteristics.

153 citations

Journal ArticleDOI
TL;DR: In this paper, an unamplified femtosecond Cr4+:forsterite laser in a submicron-thick film of a nanocrystalline ZnO pulsed-laser-deposited on a fused silica substrate was studied.
Abstract: Nonlinear optical conversion is studied in thin films of wide-bandgap materials. Very high conversion efficiency to the third-harmonic radiation is achieved for an unamplified femtosecond Cr4+:forsterite laser in a submicron-thick film of a nanocrystalline ZnO pulsed-laser-deposited on a fused silica substrate.

109 citations


Cited by
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Journal ArticleDOI
01 Aug 2006-Small
TL;DR: A review of current research on the optical properties of ZnO nanostructures and results of nonlinear optical studies, such as second-harmonic generation, are presented.
Abstract: We present a review of current research on the optical properties of ZnO nanostructures. We provide a brief introduction to different fabrication methods for various ZnO nanostructures and some general guidelines on how fabrication parameters (temperature, vapor-phase versus solution-phase deposition, etc.) affect their properties. A detailed discussion of photoluminescence, both in the UV region and in the visible spectral range, is provided. In addition, different gain (excitonic versus electron hole plasma) and feedback (random lasing versus individual nanostructures functioning as Fabry-Perot resonators) mechanisms for achieving stimulated emission are described. The factors affecting the achievement of stimulated emission are discussed, and the results of time-resolved studies of stimulated emission are summarized. Then, results of nonlinear optical studies, such as second-harmonic generation, are presented. Optical properties of doped ZnO nanostructures are also discussed, along with a concluding outlook for research into the optical properties of ZnO.

1,746 citations

Patent
01 Aug 2008
TL;DR: In this article, the oxide semiconductor film has at least a crystallized region in a channel region, which is defined as a region of interest (ROI) for a semiconductor device.
Abstract: An object is to provide a semiconductor device of which a manufacturing process is not complicated and by which cost can be suppressed, by forming a thin film transistor using an oxide semiconductor film typified by zinc oxide, and a manufacturing method thereof. For the semiconductor device, a gate electrode is formed over a substrate; a gate insulating film is formed covering the gate electrode; an oxide semiconductor film is formed over the gate insulating film; and a first conductive film and a second conductive film are formed over the oxide semiconductor film. The oxide semiconductor film has at least a crystallized region in a channel region.

1,501 citations

Journal ArticleDOI
TL;DR: In this article, a comparison of the band gap energy estimated from UV-vis reflectance spectra of TiO2 powders prepared by sol-gel route versus commercial TiO 2 powders, nanopowder, bulk powder and P25 is reported.
Abstract: A comparison of the band gap energy estimated from UV–vis reflectance spectra of TiO2 powders prepared by sol–gel route versus commercial TiO2 powders, nanopowder, bulkpowder and P25 is reported. The experimental results obtained from the optical absorption spectra were reported for all the TiO2 samples. Graphic representations were used to calculate Eg: absorbance versus λ; F(R) versus E; (F(R) hν)n versus E, with n = ½ for an indirect allowed transition and n = 2 for a direct allowed transition. From the results, it could be seen that Eg strongly varied according to the equation used for the graphic representation. Differences in Eg up to 0.5 eV for the same semiconductor depending on the transition chosen were observed. Accurate Eg estimation in the four semiconductors studied was obtained by using the general equation α (hν) ≈ B (hν − Eg)n (where α ~ F(R)) and indirect allowed transition.

1,290 citations

Journal ArticleDOI
TL;DR: In this paper, the authors present the state of the art in LST and the potential of this technology in various lubricated applications like mechanical seals, piston rings and thrust bearings.
Abstract: Surface texturing has emerged in the last decade as a viable option of surface engineering resulting in significant improvement in load capacity, wear resistance, friction coefficient etc. of tribological mechanical components. Various techniques can be employed for surface texturing but Laser Surface Texturing (LST) is probably the most advanced so far. LST produces a very large number of micro-dimples on the surface and each of these micro-dimples can serve either as a micro-hydrodynamic bearing in cases of full or mixed lubrication, a micro-reservoir for lubricant in cases of starved lubrication conditions, or a micro-trap for wear debris in either lubricated or dry sliding. The present paper reviews the current effort being made world wide on surface texturing in general and on laser surface texturing in particular. It presents the state of the art in LST and the potential of this technology in various lubricated applications like mechanical seals, piston rings and thrust bearings. The paper also describes some fundamental on going research around the world with LST.

1,123 citations

Proceedings ArticleDOI
01 Jan 2004-Volume!
TL;DR: Laser Surface Texturing (LST) is probably the most advanced surface texturing technique as mentioned in this paper and it produces a very large number of micro-dimples on the surface and each of these microdimples can serve either as a micro-hydrodynamic bearing in cases of full or mixed lubrication.
Abstract: Surface texturing has emerged in the last decade as a viable option of surface engineering resulting in significant improvement in load capacity, wear resistance, friction coefficient etc. of tribological mechanical components. Various techniques can be employed for surface texturing but Laser Surface Texturing (LST) is probably the most advanced so far. LST produces a very large number of micro-dimples on the surface and each of these micro- dimples can serve either as a micro-hydrodynamic bearing in cases of full or mixed lubrication, a micro-reservoir for lubricant in cases of starved lubrication conditions, or a micro-trap for wear debris in either lubricated or dry sliding. The paper reviews the current effort being made world wide on laser surface texturing in particular. It presents the state of the art in LST and the potential of this technology in various lubricated applications like mechanical seals, piston rings, thrust bearings, magnetic recording etc. The paper also describes some fundamental on-going research around the world with LST.

914 citations