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Xavier Bugaut
Researcher at Aix-Marseille University
Publications - 58
Citations - 2371
Xavier Bugaut is an academic researcher from Aix-Marseille University. The author has contributed to research in topics: Enantioselective synthesis & Organocatalysis. The author has an hindex of 18, co-authored 54 publications receiving 2034 citations. Previous affiliations of Xavier Bugaut include Centre national de la recherche scientifique & Université Paul Cézanne Aix-Marseille III.
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Journal ArticleDOI
Organocatalytic umpolung: N-heterocyclic carbenes and beyond
TL;DR: This tutorial review aims at offering a didactic overview of organocatalytic umpolung and should serve as an inspiration for further progress in this field.
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Enantioselective Syntheses of Furan Atropisomers by an Oxidative Central-to-Axial Chirality Conversion Strategy
Vivek S. Raut,Marion Jean,Nicolas Vanthuyne,Christian Roussel,Thierry Constantieux,Cyril Bressy,Xavier Bugaut,Damien Bonne,Jean Rodriguez +8 more
TL;DR: For the first time, enantiomerically enriched atropoisomeric furans have been accessed using a central-to-axial chirality conversion strategy and gave rise to axially chiral furans with high enantiopurities accounting from excellent conversion percentages (cp) in most cases.
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Palladium‐Catalyzed Selective Dehydrogenative Cross‐Couplings of Heteroarenes
Xavier Bugaut,Frank Glorius +1 more
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Combining Organocatalysis with Central-to-Axial Chirality Conversion: Atroposelective Hantzsch-Type Synthesis of 4-Arylpyridines.
Ophelie Quinonero,Marion Jean,Nicolas Vanthuyne,Christian Roussel,Damien Bonne,Thierry Constantieux,Cyril Bressy,Xavier Bugaut,Jean Rodriguez +8 more
TL;DR: Suitably substituted enantioenriched 4-aryl-1,4-dihydro-pyridines prepared by an organocatalytic enantioselective Michael addition were oxidized with MnO2 into axially chiral 4-arylpyridine with central-to-axial chirality conversion.
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N-Heterocyclic Carbene (NHC)-Catalyzed Intermolecular Hydroacylation of Cyclopropenes
TL;DR: This work reports the first intermolecular NHC-catalyzed hydroacylation of electron-neutral olefins of aromatic aldehydes with cyclopropenes under mild conditions and preliminary mechanistic studies suggest that product formation occurs via a concerted syn hydroacylated pathway.