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Xihua Wang

Bio: Xihua Wang is an academic researcher from University of Alberta. The author has contributed to research in topics: Quantum dot & Solar cell. The author has an hindex of 25, co-authored 90 publications receiving 5220 citations. Previous affiliations of Xihua Wang include Boston University & University of Texas at Austin.


Papers
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Journal ArticleDOI
TL;DR: An atomic ligand strategy is established that makes use of monovalent halide anions to enhance electronic transport and successfully passivate surface defects in PbS CQD films that shows up to 6% solar AM1.5G power-conversion efficiency.
Abstract: Colloidal-quantum-dot (CQD) optoelectronics offer a compelling combination of solution processing and spectral tunability through quantum size effects. So far, CQD solar cells have relied on the use of organic ligands to passivate the surface of the semiconductor nanoparticles. Although inorganic metal chalcogenide ligands have led to record electronic transport parameters in CQD films, no photovoltaic device has been reported based on such compounds. Here we establish an atomic ligand strategy that makes use of monovalent halide anions to enhance electronic transport and successfully passivate surface defects in PbS CQD films. Both time-resolved infrared spectroscopy and transient device characterization indicate that the scheme leads to a shallower trap state distribution than the best organic ligands. Solar cells fabricated following this strategy show up to 6% solar AM1.5G power-conversion efficiency. The CQD films are deposited at room temperature and under ambient atmosphere, rendering the process amenable to low-cost, roll-by-roll fabrication.

1,435 citations

Journal ArticleDOI
24 May 2010-ACS Nano
TL;DR: In this article, the Schottky device was optimized and explained in terms of a depletion region driving electron−hole pair separation on the semiconductor side of a junction between an opaque low-work-function metal and a p-type CQD film.
Abstract: Colloidal quantum dot (CQD) photovoltaics combine low-cost solution processability with quantum size-effect tunability to match absorption with the solar spectrum. Rapid recent advances in CQD photovoltaics have led to impressive 3.6% AM1.5 solar power conversion efficiencies. Two distinct device architectures and operating mechanisms have been advanced. The first—the Schottky device—was optimized and explained in terms of a depletion region driving electron−hole pair separation on the semiconductor side of a junction between an opaque low-work-function metal and a p-type CQD film. The second—the excitonic device—employed a CQD layer atop a transparent conductive oxide (TCO) and was explained in terms of diffusive exciton transport via energy transfer followed by exciton separation at the type-II heterointerface between the CQD film and the TCO. Here we fabricate CQD photovoltaic devices on TCOs and show that our devices rely on the establishment of a depletion region for field-driven charge transport and...

837 citations

Journal ArticleDOI
TL;DR: In this paper, a colloidal quantum-dot solar cell with two junctions, each designed to absorb and convert different spectral bands of light within the solar spectrum, is presented.
Abstract: Researchers report a colloidal quantum-dot solar cell that features two junctions, each designed to absorb and convert different spectral bands of light within the solar spectrum. The device offers a power conversion efficiency of 4.2% and an open circuit voltage of 1.06 V.

396 citations

Journal ArticleDOI
27 Jan 2010-ACS Nano
TL;DR: The origins of this orders-of-magnitude improvement in air stability compared to larger PbS dots are explored, and evidence is offered in support of an explanation based on the high rate of oxidation of sulfur-rich surfaces preponderant in highly faceted large-diameter P bS colloidal quantum dots.
Abstract: We report colloidal quantum dot (CQDs) photovoltaics having a approximately 930 nm bandgap. The devices exhibit AM1.5G power conversion efficiencies in excess of 2%. Remarkably, the devices are stable in air under many tens of hours of solar illumination without the need for encapsulation. We explore herein the origins of this orders-of-magnitude improvement in air stability compared to larger PbS dots. We find that small and large dots form dramatically different oxidation products, with small dots forming lead sulfite primarily and large dots, lead sulfate. The lead sulfite produced on small dots results in shallow electron traps that are compatible with excellent device performance; whereas the sulfates formed on large dots lead to deep traps, midgap recombination, and consequent catastrophic loss of performance. We propose and offer evidence in support of an explanation based on the high rate of oxidation of sulfur-rich surfaces preponderant in highly faceted large-diameter PbS colloidal quantum dots.

369 citations

Journal ArticleDOI
TL;DR: Direct measurement of hot-electron temperatures and relaxation dynamics for peak electron temperatures between 3400 and 11000 K utilizing two-pulse-correlation femtosecond thermionic emission is reported.
Abstract: We report direct measurement of hot-electron temperatures and relaxation dynamics for peak electron temperatures between 3400 and 11 000 K utilizing two-pulse-correlation femtosecond (fs) thermionic emission The fast relaxation times (15 ps) are described by extending RT characterizations of the thermal conductivity, electron-phonon coupling, and electronic specific heat to these high electron temperatures

318 citations


Cited by
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28 Jul 2005
TL;DR: PfPMP1)与感染红细胞、树突状组胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作�ly.
Abstract: 抗原变异可使得多种致病微生物易于逃避宿主免疫应答。表达在感染红细胞表面的恶性疟原虫红细胞表面蛋白1(PfPMP1)与感染红细胞、内皮细胞、树突状细胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作用。每个单倍体基因组var基因家族编码约60种成员,通过启动转录不同的var基因变异体为抗原变异提供了分子基础。

18,940 citations

Journal ArticleDOI
TL;DR: Theoretical models and qualitative explanations of experimental results are presented in this paper for femtosecond laser ablation of solid targets by 0.2-5000 ps Ti: Sapphire laser pulses.
Abstract: Laser ablation of solid targets by 0.2–5000 ps Ti: Sapphire laser pulses is studied. Theoretical models and qualitative explanations of experimental results are presented. Advantages of femtosecond lasers for precise material processing are discussed and demonstrated.

2,513 citations

Journal ArticleDOI
TL;DR: In this paper, the authors summarized the key advantages of using quantum dots as luminophores in light-emitting devices (LEDs) and outlined the operating mechanisms of four types of QD-LEDs.
Abstract: This Review article summarizes the key advantages of using quantum dots (QDs) as luminophores in light-emitting devices (LEDs) and outlines the operating mechanisms of four types of QD-LED. The key scientific and technological challenges facing QD-LED commercialization are identified, together with on-going strategies to overcome these challenges.

2,086 citations

Journal ArticleDOI
TL;DR: The simple mesoscopic CH(3)NH( 3)PbI(3)/TiO(2) heterojunction solar cell shows impressive photovoltaic performance, with short-circuit photocurrent J(sc)= 16.1 mA/cm(2), open-circuits photovvoltage V(oc) = 0.631 V, and a fill factor FF =0.57.
Abstract: We report for the first time on a hole conductor-free mesoscopic methylammonium lead iodide (CH3NH3PbI3) perovskite/TiO2 heterojunction solar cell, produced by deposition of perovskite nanoparticles from a solution of CH3NH3I and PbI2 in γ-butyrolactone on a 400 nm thick film of TiO2 (anatase) nanosheets exposing (001) facets. A gold film was evaporated on top of the CH3NH3PbI3 as a back contact. Importantly, the CH3NH3PbI3 nanoparticles assume here simultaneously the roles of both light harvester and hole conductor, rendering superfluous the use of an additional hole transporting material. The simple mesoscopic CH3NH3PbI3/TiO2 heterojunction solar cell shows impressive photovoltaic performance, with short-circuit photocurrent Jsc= 16.1 mA/cm2, open-circuit photovoltage Voc = 0.631 V, and a fill factor FF = 0.57, corresponding to a light to electric power conversion efficiency (PCE) of 5.5% under standard AM 1.5 solar light of 1000 W/m2 intensity. At a lower light intensity of 100W/m2, a PCE of 7.3% was m...

1,799 citations

Proceedings Article
Ferenc Krausz1
01 Aug 2007
TL;DR: In this paper, an attosecond "oscilloscope" was used to visualize the oscillating electric field of visible light with an oscillator and probe multi-electron dynamics in atoms, molecules and solids.
Abstract: Summary form only given. Fundamental processes in atoms, molecules, as well as condensed matter are triggered or mediated by the motion of electrons inside or between atoms. Electronic dynamics on atomic length scales tends to unfold within tens to thousands of attoseconds (1 attosecond [as] = 10-18 s). Recent breakthroughs in laser science are now opening the door to watching and controlling these hitherto inaccessible microscopic dynamics. The key to accessing the attosecond time domain is the control of the electric field of (visible) light, which varies its strength and direction within less than a femtosecond (1 femtosecond = 1000 attoseconds). Atoms exposed to a few oscillations cycles of intense laser light are able to emit a single extreme ultraviolet (XUV) burst lasting less than one femtosecond. Full control of the evolution of the electromagnetic field in laser pulses comprising a few wave cycles have recently allowed the reproducible generation and measurement of isolated sub-femtosecond XUV pulses, demonstrating the control of microscopic processes (electron motion and photon emission) on an attosecond time scale. These tools have enabled us to visualize the oscillating electric field of visible light with an attosecond "oscilloscope", to control single-electron and probe multi-electron dynamics in atoms, molecules and solids. Recent experiments hold promise for the development of an attosecond X-ray source, which may pave the way towards 4D electron imaging with sub-atomic resolution in space and time.

1,618 citations