Author
Xinru Zhu
Bio: Xinru Zhu is an academic researcher from Nanjing Tech University. The author has contributed to research in topics: Electrospinning & Catalysis. The author has an hindex of 1, co-authored 3 publications receiving 3 citations.
Topics: Electrospinning, Catalysis, Carbon nanofiber, Nitrophenol, Cyclohexanone
Papers
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TL;DR: In this paper, a series of hierarchical Pd/UiO-66-NH2-SiO2 nanofibrous catalytic membranes were fabricated, where SiO2 nanoparticles with micropores and mesopores were fabricated on the membrane, which provided more surface areas for loading Pd, thereby enhancing active sites.
11 citations
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TL;DR: Flexible and hierarchical nanostructured Pd/SiO2-TiO2 nanofibrous catalytic membranes were fabricated via combining electrospinning technique and a two-step hydrothermal method as mentioned in this paper.
Abstract: Flexible and hierarchical nanostructured Pd/SiO2-TiO2 nanofibrous catalytic membranes were fabricated via combining electrospinning technique and a two-step hydrothermal method The size and distri
11 citations
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TL;DR: In this article, a hierarchical porous carbon nanofibers (ZCNFs) were fabricated by electrospinning and calcination with ZIF-67 as the nanoparticles precursor and PAN as the CNFs precursor.
Abstract: One-step hydrogenation of phenol is a preferable and economic route for preparing cyclohexanone. The development of catalysts with high catalytic performance and easy recovery still keeps a significant challenge. Herein, the novel ZIF-derived hierarchically porous carbon nanofibers (ZCNFs) were fabricated by electrospinning and calcination with ZIF-67 as the nanoparticles precursor and PAN as the CNFs precursor, and they were used as the supports of Pd nanoparticles for preparing the Pd@ZCNFs-x catalysts [x is the mass ratio of ZIF-67 to PAN (%)]. Pd@ZCNFs-20 exhibits superior catalytic performance in the phenol hydrogenation to cyclohexanone, and its catalytic activity is 2.2 times higher than that of Pd@ZCNFs-0. The ZIF-67 doping is in favor of the formation of ZCNFs with more defects, larger surface area, hierarchical pore structure, higher N content and better Pd dispersion, thereby improving the catalytic activity. Furthermore, the as-prepared Pd@ZCNFs-20 catalyst is easy to be recovered from the reaction mixture due to its one-dimensional structure, and shows good reusability during six reaction cycles. In view of the high catalytic performance and reusability of the Pd@ZCNFs catalysts, the developed hybrid ZCNFs are potential candidates for the phenol hydrogenation. The ZIF-67 doping is in favor of the formation of ZIF-derived hierarchical porous carbon nanofibers (ZCNFs) with more defects, larger surface area, hierarchical pore structure, higher N content and better Pd dispersion, thereby improving the catalytic activity of Pd@ZCNFs in the phenol hydrogenation to cyclohexanone.
6 citations
Cited by
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TL;DR: In this paper , the degradation performance of p-nitrophenol (PNP) with graphene-ZnO nanoparticles based on theoretical and experimental perspectives is investigated. And the degradation pathways were proposed based on discrete Fourier transform (DFT) calculation and relevant literatures.
19 citations
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TL;DR: In this paper, a series of hierarchical Pd/UiO-66-NH2-SiO2 nanofibrous catalytic membranes were fabricated, where SiO2 nanoparticles with micropores and mesopores were fabricated on the membrane, which provided more surface areas for loading Pd, thereby enhancing active sites.
11 citations
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TL;DR: In this article , the authors used a high-temperature steam-induced hydrolysis method to obtain a fluorinated polyethersulfone composite hollow fiber membrane for CO2 capture.
9 citations
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TL;DR: In this paper , a unique CuInS 2 /SiO 2 hollow nanotube with a coral structure was prepared to enhance photocatalytic hydrogen evolution, which exhibited the highest hydrogen production rate of 367.00 μmol g −1 h −1 under visible light irradiation (λ ≥ 420 nm).
8 citations