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Xue-Lin Wang

Bio: Xue-Lin Wang is an academic researcher from Shandong University. The author has contributed to research in topics: Ion implantation & Waveguide (optics). The author has an hindex of 20, co-authored 146 publications receiving 1667 citations.


Papers
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Journal ArticleDOI
TL;DR: In this article, the results of recent research on the fabrication, investigation and applications of the ion-implanted optical waveguides in various optical materials, including crystals and non-crystalline glasses, are reviewed.

293 citations

Journal ArticleDOI
TL;DR: An operando mass spectrometry technique is presented, along with molecular dynamics simulations, that unveils the evolution of the solid–electrolyte interphase chemistry and structure in lithium-ion batteries during the first cycle.
Abstract: The solid–electrolyte interphase (SEI) dictates the performance of most batteries, but the understanding of its chemistry and structure is limited by the lack of in situ experimental tools. In this work, we present a dynamic picture of the SEI formation in lithium-ion batteries using in operando liquid secondary ion mass spectrometry in combination with molecular dynamics simulations. We find that before any interphasial chemistry occurs (during the initial charging), an electric double layer forms at the electrode/electrolyte interface due to the self-assembly of solvent molecules. The formation of the double layer is directed by Li+ and the electrode surface potential. The structure of this double layer predicts the eventual interphasial chemistry; in particular, the negatively charged electrode surface repels salt anions from the inner layer and results in an inner SEI that is thin, dense and inorganic in nature. It is this dense layer that is responsible for conducting Li+ and insulating electrons, the main functions of the SEI. An electrolyte-permeable and organic-rich outer layer appears after the formation of the inner layer. In the presence of a highly concentrated, fluoride-rich electrolyte, the inner SEI layer has an elevated concentration of LiF due to the presence of anions in the double layer. These real-time nanoscale observations will be helpful in engineering better interphases for future batteries. An operando mass spectrometry technique, along with molecular dynamics simulations, unveils the evolution of the solid–electrolyte interphase chemistry and structure in lithium-ion batteries during the first cycle.

234 citations

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TL;DR: In this article, the defect evolution in silicon carbide (SiC) closely depends on the electronic-to-nuclear energy loss ratio (Se/Sn), nuclear stopping powers (dE/dxnucl), and the temporal and spatial coupling of electronic and atomic subsystems for energy dissipation.
Abstract: Understanding energy dissipation processes in electronic/atomic subsystems and subsequent non-equilibrium defect evolution is a long-standing challenge in materials science. In the intermediate energy regime, energetic particles simultaneously deposit a significant amount of energy to both electronic and atomic subsystems of silicon carbide (SiC). Here we show that defect evolution in SiC closely depends on the electronic-to-nuclear energy loss ratio (Se/Sn), nuclear stopping powers (dE/dxnucl), electronic stopping powers (dE/dxele), and the temporal and spatial coupling of electronic and atomic subsystem for energy dissipation. The integrated experiments and simulations reveal that: (1) increasing Se/Sn slows damage accumulation; (2) the transient temperatures during the ionization-induced thermal spike increase with dE/dxele, which causes efficient damage annealing along the ion trajectory; and (3) for more condensed displacement damage within the thermal spike, damage production is suppressed due to the coupled electronic and atomic dynamics. Ionization effects are expected to be more significant in materials with covalent/ionic bonding involving predominantly well-localized electrons. Insights into the complex electronic and atomic correlations may pave the way to better control and predict SiC response to extreme energy deposition.

52 citations

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TL;DR: In this paper, a planar waveguide has been fabricated in a Nd:YVO4 crystal by 3.0 MeV Si+ ion implantation at a dose of 1×1015 ions/cm2 at room temperature.
Abstract: The planar waveguide has been fabricated in a Nd:YVO4 crystal by 3.0 MeV Si+ ion implantation at a dose of 1×1015 ions/cm2 at room temperature. The waveguide was characterized by the prism-coupling method. The dark modes are measured before and after the annealing at 240 °C for 60 min in air. The refractive index profile is reconstructed using reflectivity calculation method. It is found that relatively large positive change of ordinary refractive index happens in the guiding region, which is quite different from most of the observed ion-implanted waveguides. The TRIM’98 code is carried out to simulate the energy loss during the implantation in order to obtain a better understanding for the waveguide formation.

50 citations

Journal ArticleDOI
Chuan-Lei Jia1, Ke-Ming Wang1, Xue-Lin Wang1, Xi-Jian Zhang1, Fei Lu1 
TL;DR: The experimental results show that high optical quality ZnO films can be obtained with MgZnO buffer layers with high transparencies by radio-frequency magnetron sputtering.
Abstract: ZnO/Mg0.16Zn0.84O (ZnO/MgZnO) films are fabricated on x-cut and z-cut LiNbO3 (LN) substrates by radio-frequency magnetron sputtering. High transparencies are confirmed by a spectrophotometer. X-ray diffraction (XRD) spectra show that all the films are c-axis oriented. The waveguiding properties, as well as the refractive indices and thickness of the films are demonstrated and determined by prism coupling. Both transverse electric (TE) and transverse magnetic (TM) modes are measured at λ=0.633 µm and 1.539 µm, respectively. The waveguide loss is measured at λ=0.633 µm with a fiber probe technique. The experimental results show that high optical quality ZnO films can be obtained with MgZnO buffer layers.

49 citations


Cited by
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Journal ArticleDOI
TL;DR: In this paper, the authors report the first observation of the behaviour of a PT optical coupled system that judiciously involves a complex index potential, and observe both spontaneous PT symmetry breaking and power oscillations violating left-right symmetry.
Abstract: One of the fundamental axioms of quantum mechanics is associated with the Hermiticity of physical observables 1 . In the case of the Hamiltonian operator, this requirement not only implies real eigenenergies but also guarantees probability conservation. Interestingly, a wide class of non-Hermitian Hamiltonians can still show entirely real spectra. Among these are Hamiltonians respecting parity‐time (PT) symmetry 2‐7 . Even though the Hermiticity of quantum observables was never in doubt, such concepts have motivated discussions on several fronts in physics, including quantum field theories 8 , nonHermitian Anderson models 9 and open quantum systems 10,11 , to mention a few. Although the impact of PT symmetry in these fields is still debated, it has been recently realized that optics can provide a fertile ground where PT-related notions can be implemented and experimentally investigated 12‐15 . In this letter we report the first observation of the behaviour of a PT optical coupled system that judiciously involves a complex index potential. We observe both spontaneous PT symmetry breaking and power oscillations violating left‐right symmetry. Our results may pave the way towards a new class of PT-synthetic materials with intriguing and unexpected properties that rely on non-reciprocal light propagation and tailored transverse energy flow. Before we introduce the concept of spacetime reflection in optics, we first briefly outline some of the basic aspects of this symmetry within the context of quantum mechanics. In general, a Hamiltonian HD p 2 =2mCV(x

3,097 citations

Journal ArticleDOI
TL;DR: This Review covers a sequence of key discoveries and technical achievements that eventually led to the birth of the lithium-ion battery and sheds light on the history with the advantage of contemporary hindsight to aid in the ongoing quest for better batteries of the future.
Abstract: This Review covers a sequence of key discoveries and technical achievements that eventually led to the birth of the lithium-ion battery. In doing so, it not only sheds light on the history with the advantage of contemporary hindsight but also provides insight and inspiration to aid in the ongoing quest for better batteries of the future. A detailed retrospective on ingenious designs, accidental discoveries, intentional breakthroughs, and deceiving misconceptions is given: from the discovery of the element lithium to its electrochemical synthesis; from intercalation host material development to the concept of dual-intercalation electrodes; and from the misunderstanding of intercalation behavior into graphite to the comprehension of interphases. The onerous demands of bringing all critical components (anode, cathode, electrolyte, solid-electrolyte interphases), each of which possess unique chemistries, into a sophisticated electrochemical device reveal that the challenge of interfacing these originally inco...

1,295 citations

Journal ArticleDOI
TL;DR: A review of the state-of-the-art in the fabrication, characterization and applications of femtosecond-laser micromachined waveguiding structures in optical crystals and ceramics is presented in this article.
Abstract: Femtosecond-laser micromachining (also known as inscription or writing) has been developed as one of the most efficient techniques for direct three-dimensional microfabrication of transparent optical materials. In integrated photonics, by using direct writing of femtosecond/ultrafast laser pulses, optical waveguides can be produced in a wide variety of optical materials. With diverse parameters, the formed waveguides may possess different configurations. This paper focuses on crystalline dielectric materials, and is a review of the state-of-the-art in the fabrication, characterization and applications of femtosecond-laser micromachined waveguiding structures in optical crystals and ceramics. A brief outlook is presented by focusing on a few potential spotlights.

535 citations

10 Jun 2016
TL;DR: In this article, a superconcentrated LiN(SO2F)2/dimethyl carbonate electrolyte was proposed to solve the problem of metal-ion dissolution at high voltages.
Abstract: Finding a viable electrolyte for next-generation 5 V-class lithium-ion batteries is of primary importance. A long-standing obstacle has been metal-ion dissolution at high voltages. The LiPF6 salt in conventional electrolytes is chemically unstable, which accelerates transition metal dissolution of the electrode material, yet beneficially suppresses oxidative dissolution of the aluminium current collector; replacing LiPF6 with more stable lithium salts may diminish transition metal dissolution but unfortunately encounters severe aluminium oxidation. Here we report an electrolyte design that can solve this dilemma. By mixing a stable lithium salt LiN(SO2F)2 with dimethyl carbonate solvent at extremely high concentrations, we obtain an unusual liquid showing a three-dimensional network of anions and solvent molecules that coordinate strongly to Li(+) ions. This simple formulation of superconcentrated LiN(SO2F)2/dimethyl carbonate electrolyte inhibits the dissolution of both aluminium and transition metal at around 5 V, and realizes a high-voltage LiNi0.5Mn1.5O4/graphite battery that exhibits excellent cycling durability, high rate capability and enhanced safety.

532 citations

Journal ArticleDOI
TL;DR: This review summarizes the existing issues with regard to Li anodes and their underlying reasons and then highlights the recent progress made in the development of high-performance LiAnodes, and proposes the persisting challenges and opportunities toward the exploration of practical Li-metal anodes.
Abstract: Lithium-ion batteries have had a tremendous impact on several sectors of our society; however, the intrinsic limitations of Li-ion chemistry limits their ability to meet the increasing demands of developing more advanced portable electronics, electric vehicles, and grid-scale energy storage systems. Therefore, battery chemistries beyond Li ions are being intensively investigated and need urgent breakthroughs toward commercial applications, wherein the use of metallic Li is one of the most intuitive choices. Despite several decades of oblivion due to safety concerns regarding the growth of Li dendrites, Li-metal anodes are now poised to be revived because of the advances in investigative tools and globally invested efforts. In this review, we first summarize the existing issues with regard to Li anodes and their underlying reasons and then highlight the recent progress made in the development of high-performance Li anodes. Finally, we propose the persisting challenges and opportunities toward the exploration of practical Li-metal anodes.

384 citations