Xuhui Xu

Bio: Xuhui Xu is an academic researcher from Kunming University of Science and Technology. The author has contributed to research in topics: Materials science & Phosphor. The author has an hindex of 24, co-authored 142 publications receiving 1899 citations. Previous affiliations of Xuhui Xu include Hong Kong Polytechnic University & Kunming University.

Sunlight activated long-lasting luminescence from Ba5Si8O21: Eu(2+),Dy(3+) phosphor.

Abstract: Visible-light persistent phosphors are commonly used as self-sustained night vision and fluorescence labeling materials. From the inspiration of the structure of six-membered rings plane in Ba4(Si3O8)2, a similar structure of Ba5Si8O21 is expected that could exhibit more excellent phosphorescence property. In this Article, we report a novel visible long-lasting luminescence phosphor of Eu(2+)/Dy(3+) codoped Ba5Si8O21 for the first time. Ba5Si8O21:Eu(2+),Dy(3+) phosphor could be activated effectively by sunlight or even in severe weather conditions, which is mainly attributed to the broad excitation spectrum (200-455 nm) and highly responds to UV-A and violet-light in the solar spectrum. After activation, Ba5Si8O21:Eu(2+),Dy(3+) emits intense emission at 380-680 nm with persistent phosphorescence beyond 16 h. Moreover, it exhibits excellent and stable phosphorescence even in water, indicating that Ba5Si8O21:Eu(2+),Dy(3+) will be a all-weather material that can be effectively and repeatedly charged by natural daylight in all kinds of open-air environments. Furthermore, the quantum tunneling behavior was illustrated in the afterglow mechanism.

Phonon-Assisted Population Inversion in Lanthanide-Doped Upconversion Ba2 LaF7 Nanocrystals in Glass-Ceramics.

Abstract: The effective population inversion of 2 H11/2 from 4 S3/2 state of Er3+ ions can be achieved through the annihilation of phonons; random lasing action from BLF films embedded with Yb3+ /Er3+ codoped BLF nanocrystals is demonstrated and high ambient temperature (>433 K) operation lasers with a very low excitation threshold (<530 nJ cm-2 ) are realized.

Reproducible X-ray Imaging with a Perovskite Nanocrystal Scintillator Embedded in a Transparent Amorphous Network Structure

Abstract: Metal halide perovskites are emerging scintillator materials in X-ray detection and imaging. However, the vulnerable structure of perovskites triggers unreliable performance when they are utilized in X-ray detectors under cumulative dose irradiation. Herein, a self-limited growth strategy is proposed to construct CsPbBr3 nanocrystals that are embedded in a transparent amorphous network structure, featuring X-imaging with excellent resolution (≈16.8 lp mm-1 ), and fast decay time (τ = 27 ns). Interestingly, it is found that the performance degradation of the scintillator, caused by the damage from high-dose X-ray irradiation, can be fully recovered after a facile thermal treatment process. This indicates a superior recycling behavior of the explored perovskites scintillator for practical applications. The recoverability of the as-explored scintillator is attributed to the low atom-migration rate in the amorphous network with high-viscosity (1 × 1014 cP). This result highlights the practical settlement of the promising perovskites for long-term, cost-effective scintillator devices.

Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories

Abstract: It is conventionally assumed that the growth of monodisperse colloidal nanocrystals requires a temporally discrete nucleation followed by monomer attachment onto the existing nuclei. However, recent studies have reported violations of this classical growth model, and have suggested that inter-particle interactions are also involved during the growth. Mechanisms of nanocrystal growth still remain controversial. Using in situ transmission electron microscopy, we show that platinum nanocrystals can grow either by monomer attachment from solution onto the existing particles or by coalescence between the particles. Surprisingly, an initially broad size distribution of the nanocrystals can spontaneously narrow. We suggest that nanocrystals take different pathways of growth based on their size- and morphology-dependent internal energies. These observations are expected to be highly relevant for other nanocrystal systems.

Long persistent phosphors—from fundamentals to applications

Abstract: Owing to the unique mechanism of photoelectron storage and release, long persistent phosphorescence, also called long persistent luminescence or long lasting afterglow/phosphorescence, plays a pivotal role in the areas of spectroscopy, photochemistry, photonics and materials science. In recent years, more research has focused on the manipulation of the morphology, operational wavebands and persistent duration of long persistent phosphors (LPPs). These desired achievements stimulated the growing interest in designing bio-labels, photocatalysts, optical sensors, detectors and photonic devices. In this review, we present multidisciplinary research on synthetic methods, afterglow mechanisms, characterization techniques, materials system, and applications of LPPs. First, we introduce the recent developments in LPPs for the synthesis of nanoparticles from the aspects of particle sizes, monodispersity and homogeneity based on the urgent application of bio-imaging. In the later sections, we present the possible mechanisms, which involve the variation of trap distribution during the trapping and de-trapping process, complicated photo-ionization reaction of trap site levels and impurity centers together with their corresponding migration kinetics of carriers. Meanwhile, we emphasize the characterization techniques of defects, used to qualitatively or quantitatively describe the types, concentrations and depths of the traps. This review article also highlights the recent advances in suggested LPPs materials with a focus on the LPPs' hosts and optically active centers as well as their control, tuning and intrinsic links. We further discuss the classification of LPPs based on the different emission and excitation wavebands from the ultraviolet to the near-infrared region along with an overview of the activation mode of afterglow. Afterwards, we provide an exhibition of new products towards diverse application fields, including solar energy utilization, bio-imaging, diagnosis, and photocatalysts. Finally, we summarize the current achievements, discuss the problems and provide suggestions for potential future directions in the aforementioned parts.

Lanthanide-Activated Phosphors Based on 4f-5d Optical Transitions: Theoretical and Experimental Aspects.

Abstract: The synthesis of lanthanide-activated phosphors is pertinent to many emerging applications, ranging from high-resolution luminescence imaging to next-generation volumetric full-color display. In particular, the optical processes governed by the 4f-5d transitions of divalent and trivalent lanthanides have been the key to enabling precisely tuned color emission. The fundamental importance of lanthanide-activated phosphors for the physical and biomedical sciences has led to rapid development of novel synthetic methodologies and relevant tools that allow for probing the dynamics of energy transfer processes. Here, we review recent progress in developing methods for preparing lanthanide-activated phosphors, especially those featuring 4f-5d optical transitions. Particular attention will be devoted to two widely studied dopants, Ce3+ and Eu2+. The nature of the 4f-5d transition is examined by combining phenomenological theories with quantum mechanical calculations. An emphasis is placed on the correlation of hos...

A review of the structures of oxide glasses by Raman spectroscopy

Abstract: The family of oxide glasses is very wide and it is continuously developing. The rapid development of advanced and innovative glasses is under progress. Oxide glasses have a variety of applications in articles for daily use as well as in advanced technological fields such as X-ray protection, fibre glasses, optical instruments and lab glassware. Oxide glasses basically consist of network formers, such as borate, silicate, phosphate, borosilicate, borophosphate, and network modifiers such as alkali, alkaline earth and transition metals. In the present review article, Raman spectroscopy results for the structures of borate, silicate, phosphate, borosilicate, borophosphate, aluminosilicate, phosphosilicate, alumino-borosilicate and tellurite glasses are summarized.

Eu2+ Site Preferences in the Mixed Cation K2BaCa(PO4)2 and Thermally Stable Luminescence.

Abstract: Site preferences of dopant Eu2+ on the locations of K+, Ba2+, and Ca2+ in the mixed cation phosphate K2BaCa(PO4)2 (KBCP) are quantitatively analyzed via a combined experimental and theoretical method to develop a blue-emitting phosphor with thermally stable luminescence. Eu2+ ions are located at K2 (M2) and K3 (M3) sites of KBCP, with the latter occupation relatively more stable than the former, corresponding to emissions at 438 and 465 nm, respectively. KBCP:Eu2+ phosphor exhibits highly thermal stable luminescence even up to 200 °C, which is interpreted as due to a balance between thermal ionization and recombination of Eu2+ 5d excited-state centers with the involvement of electrons trapped at crystal defect levels. Our results can initiate more exploration of activator site engineering in phosphors and therefore allow predictive control of photoluminescence tuning and thermally stable luminescence for emerging applications in white LEDs.