Yangting Sun

Bio: Yangting Sun is an academic researcher from Fudan University. The author has contributed to research in topics: Materials science & Corrosion. The author has an hindex of 6, co-authored 25 publications receiving 163 citations.

Recent advances and challenges in divalent and multivalent metal electrodes for metal–air batteries

Abstract: Metal–air batteries (MABs), which possess exceptionally high energy density and exhibit other ideal features such as low cost, environmental benignity and safety, are regarded as promising candidates for the next generation of power sources. The performance of MABs and the challenges involved in these systems are primarily related to metal electrodes. In the present work, different types of MABs are overviewed from the perspective of the metal electrodes. Most metal electrodes that have been studied in recent years are reviewed, among which Zn, Al, Mg and Fe are highlighted. The advantages and disadvantages of each system are presented, and recent advances that address challenges such as corrosion, passivation and dendrite growth are introduced. In addition, investigations focused on revealing interactions between the metal electrodes and electrolytes or exploring electrolytes to improve the performance of metal electrodes are also discussed. Finally, a general perspective on the current situation of this field and on future research directions is provided.

Strategies to Enhance Corrosion Resistance of Zn Electrodes for Next Generation Batteries

Abstract: Zn is an important negative electrode material in our battery industry and next-generation Zn based batteries are prospective to compete with lithium-ion batteries on cost and energy density. Corrosion is a severe challenge facing Zn electrodes, which can decrease the capacity, cyclability and shelf life of batteries. More attention should be paid to Zn electrode corrosion in developing rechargeable and high energy density Zn batteries. In this mini review, the fundamental electrochemical behavior and corrosion of Zn electrodes in aqueous environment are retrospected. Then main strategies in recent studies to mitigate Zn electrode corrosion including electrolyte additives usage, electrode composition design and electrode morphology modification are reviewed.

A comparative study on potentiodynamic and potentiostatic critical pitting temperature of austenitic stainless steels

Abstract: Temperature and potential effect on pitting occurrence of four austenitic stainless steels in 1 M sodium chloride solution are plotted, then the influence of scan rate and chloride concentration on potentiodynamic critical pitting temperature (CPT) are investigated. Basing on the independence and reliability analysis, the potentiodynamic CPT and potentiostatic CPT are compared. To improve the reproducibility of potentiostatic CPT, an elevated potential should be applied. On the other hand, crevice corrosion induced by transpassive etching is clarified, indicating the upper limit of applied potential in potentiostatic test. Consequently, a potential of 800 or 850 mV(SCE) is recommended for austenitic stainless steels. Additionally, regression analysis is carried out to confirm the linear relationship between potentiodynamic CPT and pitting resistance equivalent.

Challenges in Zinc Electrodes for Alkaline Zinc–Air Batteries: Obstacles to Commercialization

Abstract: Alkaline zinc–air batteries are promising energy storage technologies with the advantages of low cost, ecological friendliness, and high energy density. However, the rechargeable zinc–air battery has not been used on a commercial scale because the zinc electrode suffers from critical problems such as passivation, dendrite growth, and hydrogen evolution reaction, which limit the practical applications of zinc–air batteries. Herein, the Perspective summaries the solutions to minimize the negative effects of zinc electrodes on discharge performance, cycling life, and shelf life. The future direction of academic research based on current studies of the existing challenges is proposed.

Applications of Lithium-Ion Batteries in Grid-Scale Energy Storage Systems

Abstract: In the electrical energy transformation process, the grid-level energy storage system plays an essential role in balancing power generation and utilization. Batteries have considerable potential for application to grid-level energy storage systems because of their rapid response, modularization, and flexible installation. Among several battery technologies, lithium-ion batteries (LIBs) exhibit high energy efficiency, long cycle life, and relatively high energy density. In this perspective, the properties of LIBs, including their operation mechanism, battery design and construction, and advantages and disadvantages, have been analyzed in detail. Moreover, the performance of LIBs applied to grid-level energy storage systems is analyzed in terms of the following grid services: (1) frequency regulation; (2) peak shifting; (3) integration with renewable energy sources; and (4) power management. In addition, the challenges encountered in the application of LIBs are discussed and possible research directions aimed at overcoming these challenges are proposed to provide insight into the development of grid-level energy storage systems.