Yiwu Quan

Bio: Yiwu Quan is an academic researcher from Nanjing University. The author has contributed to research in topics: Liquid crystal & Electrochemiluminescence. The author has an hindex of 20, co-authored 58 publications receiving 1175 citations.

Dual resonance energy transfer in triple-component polymer dots to enhance electrochemiluminescence for highly sensitive bioanalysis

Abstract: Polymer dots (Pdots) have become a type of attractive illuminant for electrochemiluminescence (ECL). However, the low ECL efficiency severely limits their practicability. Here, we design a dual intramolecular resonance energy transfer (RET) mechanism with newly synthesized triple-component Pdots to achieve great ECL enhancement. This mechanism efficiently shortens the path of energy transmission, thus greatly promoting the ECL amplification by 380 and 31 times compared to systems with no and single RET, and results in a relative ECL efficiency of 23.1% (vs. 1 mM Ru(bpy)32+). Using metal–organic frameworks to carry the triple-component Pdots, a highly luminescent probe is proposed. By integrating the probe with target-mediated enzymatic circulation amplification and DNA arrays, a highly sensitive ECL imaging method is designed for simultaneous visual analysis of two kinds of proteins, mucin 1 and human epidermal growth factor receptor 2, on living cells, which exhibited linear ranges of 1 pg mL−1 to 5 ng mL−1 and 5 pg mL−1 to 10 ng mL−1 with limits of detection of 1 pg mL−1 and 5 pg mL−1, respectively. The proposed strategy showed promising application in bioanalysis.

Donor–Acceptor Conjugated Polymer Dots for Tunable Electrochemiluminescence Activated by Aggregation-Induced Emission-Active Moieties

Abstract: Low-potential electrochemiluminescence (ECL) luminophores with excellent ECL behavior have attracted considerable interest in biological analysis. Herein, we describe the synthesis of two aggregation-induced emission (AIE)-active conjugated polymers with a donor-acceptor (D-A) system via a Suzuki coupling polymerization reaction. The intramolecular D-A pairs enhanced their luminescence intensity in aggregate states, which was beneficial for preparation of conjugated polymer dots (Pdots) as ECL materials. The ECL emission of the P-2 Pdots showed obvious red shift from 578 to 598 nm after the fluorene moiety (P-1) was replaced with a stronger electron-donating carbazole moiety. The ECL property could be regulated with intramolecular charge transfer of the D-A moieties, which led to a sharp decline (553 mV) of ECL anodic potential. Furthermore, the ECL intensity significantly increased about 6 times because of the low lowest unoccupied molecular orbital level, which facilitated the electron injection into the conjugated polymer backbone. This work provides an effective strategy for developing AIE-active ECL materials with low potential and high ECL emission intensity via adjusting the D-A electronic structure.

Principles Of Fluorescence Spectroscopy

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Supramolecular Helical Systems: Helical Assemblies of Small Molecules, Foldamers, and Polymers with Chiral Amplification and Their Functions

Abstract: In this review, we describe the recent advances in supramolecular helical assemblies formed from chiral and achiral small molecules, oligomers (foldamers), and helical and nonhelical polymers from the viewpoints of their formations with unique chiral phenomena, such as amplification of chirality during the dynamic helically assembled processes, properties, and specific functionalities, some of which have not been observed in or achieved by biological systems. In addition, a brief historical overview of the helical assemblies of small molecules and remarkable progress in the synthesis of single-stranded and multistranded helical foldamers and polymers, their properties, structures, and functions, mainly since 2009, will also be described.

Hydrogen Bonding in the Electronic Excited State

Abstract: Because of its fundamental importance in many branches of science, hydrogen bonding is a subject of intense contemporary research interest. The physical and chemical properties of hydrogen bonds in the ground state have been widely studied both experimentally and theoretically by chemists, physicists, and biologists. However, hydrogen bonding in the electronic excited state, which plays an important role in many photophysical processes and photochemical reactions, has scarcely been investigated.Upon electronic excitation of hydrogen-bonded systems by light, the hydrogen donor and acceptor molecules must reorganize in the electronic excited state because of the significant charge distribution difference between the different electronic states. The electronic excited-state hydrogen-bonding dynamics, which are predominantly determined by the vibrational motions of the hydrogen donor and acceptor groups, generally occur on ultrafast time scales of hundreds of femtoseconds. As a result, state-of-the-art femtos...

Aggregation-Induced Emission: New Vistas at the Aggregate Level

Abstract: Aggregation-induced emission (AIE) describes a photophysical phenomenon in which molecular aggregates exhibit stronger emission than the single molecules. Over the course of the last 20 years, AIE research has made great strides in material development, mechanistic study and high-tech applications. The achievements of AIE research demonstrate that molecular aggregates show many properties and functions that are absent in molecular species. In this review, we summarize the advances in the field of AIE and its related areas. We specifically focus on the new properties of materials attained by molecular aggregates beyond the microscopic molecular level. We hope this review will inspire more research into molecular ensembles at and beyond the meso level and lead to the significant progress in material and biological science.