Yogesh M. Joshi

Bio: Yogesh M. Joshi is an academic researcher from Indian Institute of Technology Kanpur. The author has contributed to research in topics: Viscoelasticity & Creep. The author has an hindex of 31, co-authored 143 publications receiving 2718 citations. Previous affiliations of Yogesh M. Joshi include Council of Scientific and Industrial Research & Indian Institutes of Technology.

Dynamics of colloidal glasses and gels.

Abstract: Many household and industrially important soft colloidal materials, such as pastes, concentrated suspensions and emulsions, foams, slurries, inks, and paints, are very viscous and do not flow over practical timescales until sufficient stress is applied. This behavior originates from restricted mobility of the constituents arrested in disordered structures of varying length scales, termed colloidal glasses and gels. Usually these materials are thermodynamically out of equilibrium, which induces a time-dependent evolution of the structure and the properties. This review presents an overview of the rheological behavior of this class of materials. We discuss the experimental observations and theoretical developments regarding the microstructure of these materials, emphasizing the complex coupling between the deformation field and nonequilibrium structures in colloidal glasses and gels, which leads to a rich array of rheological behaviors with profound implications for various industrial processes and products.

Rheological Behavior of Aqueous Suspensions of Laponite: New Insights into the Ageing Phenomena

Abstract: In this paper, ageing behavior of suspensions of laponite with varying salt concentration is investigated using rheological tools. It is observed that the ageing is accompanied by an increase in the complex viscosity. The succeeding creep experiments performed at various ages showed damped oscillations in the strain. The characteristic time-scale of the damped oscillations, retardation time, showed a prominent decrease with the age of the system. However, this dependence weakens with an increase in the salt concentration, which is known to change microstructure of the system from glass-like to gel-like. We postulate that a decrease in the retardation time can be represented as a decrease in the viscosity (friction) of the dissipative environment surrounding the arrested entities that opposes elastic deformation of the system. We believe that ageing in colloidal glass leads to a greater ordering that enhances relative spacing between the constituents thereby reducing the frictional resistance. However, since a gel state is inherently different in structure (fractal network) than that of a glass (disordered), ageing in the same does not induce ordering. Consequently, we observe inverse dependence of retardation time on age becoming weaker with an increase in the salt concentration. We analyze these results from a perspective of ageing dynamics of both glass state and gel state of laponite suspensions.

Rheological behaviour of aqueous suspensions of laponite: new insights into the ageing phenomena

Abstract: In this paper, the ageing behaviour of suspensions of laponite with varying salt concentration is investigated using rheological tools. It is observed that ageing is accompanied by an increase in the complex viscosity. The creep experiments performed at various ages show damped oscillations in the strain. The characteristic time scale of the damped oscillations, the retardation time, shows a prominent decrease with increasing age of the system. However, this dependence weakens with an increase in the salt concentration, which is known to change the microstructure of the system from glass like to gel like. We postulate that a decrease in the retardation time can be represented as a decrease in the viscosity (friction) of the dissipative environment surrounding the arrested entities that oppose elastic deformation of the system. We believe that ageing in colloidal glass leads to a greater ordering that enhances relative spacing between the constituents, thereby reducing the frictional resistance. However, since a gel state is inherently different in structure (fractal network) to that of a glass state (disordered), ageing in the gel does not induce ordering. Consequently, we observe an inverse dependence of retardation time on age, which becomes weaker with an increase in the salt concentration. We analyse these results from the perspective of ageing dynamics of both glass and gel states of laponite suspensions.

Mechanism of silk processing in insects and spiders

Abstract: Silk spinning by insects and spiders leads to the formation of fibres that exhibit high strength and toughness. The lack of understanding of the protein processing in silk glands has prevented the recapitulation of these properties in vitro from reconstituted or genetically engineered silks. Here we report the identification of emulsion formation and micellar structures from aqueous solutions of reconstituted silkworm silk fibroin as a first step in the process to control water and protein-protein interactions. The sizes (100-200 nm diameter) of these structures could be predicted from hydrophobicity plots of silk protein primary sequence. These micelles subsequently aggregated into larger 'globules' and gel-like states as the concentration of silk fibroin increased, while maintaining solubility owing to the hydrophilic regions of the protein interspersed among the larger hydrophobic regions. Upon physical shearing or stretching structural transitions, increased birefringence and morphological alignment were demonstrated, indicating that this process mimics the behaviour of similar native silk proteins in vivo. Final morphological features of these silk materials are similar to those observed in native silkworm fibres.

Створення порталу інформаційно-довідкових ресурсів міністерства освіти і науки україни

Abstract: Premises of creation of Internet portal designed to provide access to participants of educational and scientific process for the joint creation, consolidation, concentration and rapid spreading of educational and scientific information resources in its own depository are considered. CMS-based portal content management systems’ potentiality is investigated. Architecture for Internet portal of MES of Ukraine’s information resources is offered.

A Benchmark Study on the Thermal Conductivity of Nanofluids

Abstract: This article reports on the International Nanofluid Property Benchmark Exercise, or INPBE, in which the thermal conductivity of identical samples of colloidally stable dispersions of nanoparticles or “nanofluids,” was measured by over 30 organizations worldwide, using a variety of experimental approaches, including the transient hot wire method, steady-state methods, and optical methods. The nanofluids tested in the exercise were comprised of aqueous and nonaqueous basefluids, metal and metal oxide particles, near-spherical and elongated particles, at low and high particle concentrations. The data analysis reveals that the data from most organizations lie within a relatively narrow band (±10% or less) about the sample average with only few outliers. The thermal conductivity of the nanofluids was found to increase with particle concentration and aspect ratio, as expected from classical theory. There are (small) systematic differences in the absolute values of the nanofluid thermal conductivity among the various experimental approaches; however, such differences tend to disappear when the data are normalized to the measured thermal conductivity of the basefluid. The effective medium theory developed for dispersed particles by Maxwell in 1881 and recently generalized by Nan et al. [J. Appl. Phys. 81, 6692 (1997)], was found to be in good agreement with the experimental data, suggesting that no anomalous enhancement of thermal conductivity was achieved in the nanofluids tested in this exercise.

Nature in London

Abstract: The article tells about the diversity of green spaces in London, the citizens’ attitude toward these spaces, and what Russian cities can learn from this experience.