Yu Chen

Bio: Yu Chen is an academic researcher from Delft University of Technology. The author has contributed to research in topics: Cementitious & Portland cement. The author has an hindex of 8, co-authored 15 publications receiving 227 citations.

Improving printability of limestone-calcined clay-based cementitious materials by using viscosity-modifying admixture

Abstract: In 3D concrete printing (3DCP), it is necessary to meet contradicting rheological requirements: high fluidity during pumping and extrusion, and high stability and viscosity at rest to build the layered structure. In this paper, the impact of the hydroxypropyl methylcellulose (HPMC)-based viscosity-modifying admixture (VMA) on the 3D printability and mechanical performance of a limestone and calcined clay based cementitious material is investigated. A combination of VMA and superplasticizer was used for that purpose. In this case, controlling the competitive effects between VMA and superplasticizer becomes critical. The main strategy for 3D printing in this study was to add an optimal dosage of VMA in the solid suspension that was already mixed with water and superplasticizer. A lab-scale 3DCP setup was developed and demonstrated as well. A series of tests was performed to characterize the effects of VMA on flowability, extrudability, open time, buildability, green strength, hydration, compressive strength, and air void content and distribution. Experiments performed in this study showed that the mixture containing 0.24% (of the binder mass) of VMA exhibited satisfactory 3D printability and optimal mechanical performance. Finally, the results, limitations, and perspectives of the current research were discussed.

The Effect of Viscosity-Modifying Admixture on the Extrudability of Limestone and Calcined Clay-Based Cementitious Material for Extrusion-Based 3D Concrete Printing

Abstract: To investigate the effects of viscosity-modifying admixture (VMA) on the extrudability of limestone and calcined clay-based cementitious materials, three mix designs with different dosages of VMA were proposed in this study. The ram extrusion was utilized as an extrusion model for exploring the fresh properties of printable materials. Two methods were used, based on the ram extruder setup—(a) extruding materials with the same extrusion speed at different rest times to determine how the pressure changes with time; (b) extruding materials with different extrusion speeds at the same rest time to investigate the material flow parameters using the Basterfield et al. model. The main findings of this study could be summarized as—(1) the extrusion pressure of all mix designs exhibited an increasing trend with time. At the same tested age, the extrusion pressure under 0.25 mm/s of piston speed was increased and the shape retention of the extruded filaments was enhanced by increasing the dosage of VMA; (2) the correlation between the experimental results and the Basterfield et al. model was excellent (R-squared value: 0.99). The mixture with a higher content of VMA showed an increased elongational yield stress, flow consistency, and shear yield stress.

Sustainable materials for 3D concrete printing

Abstract: This paper explores the sustainability aspects of binders used in concrete 3D concrete printing. Firstly, a prospective approach to conduct sustainability-assessment based on the life cycle of 3D printed structures is presented, which also highlights the importance of considering the functional requirements of the mixes used for 3D printing. The potential of the material production phase is emphasized to enhance the sustainability potential of 3DCP by reducing the embodied impacts. The literature on the different binder systems used for producing 3D printable mixtures is reviewed. This review includes binders based on portland cement and supplementary cementing materials (SCMs) such as fly ash, silica-fume and slag. Also, alternative binders such as geopolymer, calcium sulfo-aluminate cement (CSA), limestone calcined clay cement (LC3) and reactive magnesium oxide systems are explored. Finally, sustainability assessment by quantifying the environmental impacts in terms of energy consumed and CO2 emissions of mixtures is illustrated with different binder systems. This paper underlines the effect of using SCMs and alternative binder systems for improving the sustainability of 3D printed structures.

Limestone and Calcined Clay-Based Sustainable Cementitious Materials for 3D Concrete Printing : A Fundamental Study of Extrudability and Early-Age Strength Development

Abstract: The goal of this study is to investigate the effects of different grades of calcined clay on the extrudability and early-age strength development under ambient conditions. Four mix designs were proposed. Three of them contained high, medium, and low grades of calcined clay, respectively, and one was the reference without calcined clay. In terms of extrudability, an extrusion test method based on the ram extruder was introduced to observe the quality of extruded material filaments, and to determine the extrusion pressure of tested materials at different ages. For evaluating the very early-age strength development, the penetration resistance test, the green strength test, and the ultrasonic pulse velocity test were applied. Furthermore, the mechanical properties of the developed mix designs were determined by the compressive strength test at 1, 7 and 28 days. Finally, the main finding of this study was that increasing the metakaolin content in calcined clay could significantly increase the extrusion pressures and green strength, shorten the initial setting time and enhance the compressive strength at 1, 7, and 28 days.

Effect of different grade levels of calcined clays on fresh and hardened properties of ternary-blended cementitious materials for 3D printing

Abstract: This study aims to investigate the influences of different grades of calcined clay on 3D printability, compressive strength (7 days), and hydration of limestone and calcined clay-based cementitious materials. Calcined clays that contained various amounts of metakaolin were achieved by blending low-grade calcined clay (LGCC) and high-grade calcined clay (HGCC) in three different proportions. The results revealed that increasing the HGCC% ranging from 0 wt% to 50 wt% in calcined clay could: (1) increase the flow consistency; (2) impressively improve the buildability, and reduce the printability window of the fresh mixtures; (3) enhance and accelerate the cement hydration. The reduction of mean interparticle distance induced by increasing HGCC% may be the primary reason for the enhancement of buildability and very early-age hydration. However, increasing HGCC% led to an increase of air void content in the interface region of the printed sample, which weakened the compressive strength of the printed sample at 7 days. Besides, it confirmed that the cold-joint/weak interface was easily formed by using the fresh mixture with a high structuration rate.

Extrusion-based concrete 3D printing from a material perspective : a state-of-the-art review

Abstract: This paper provides a comprehensive review of the material behaviour for extrusion-based concrete 3D printing spanning from the early age to long-term performance. We begin with a discussion on the recent progress on the understanding of early-age behaviour. Following this, the mechanical response in the hardened state, and the different strategies to introduce reinforcement are reviewed. Finally, we present insights and perspectives on the transport mechanisms in printed concrete to assess the long-term performance, and also discuss the overall impact of construction by concrete 3D printing on sustainability.

Extrusion and rheology characterization of geopolymer nanocomposites used in 3D printing

Abstract: This study focused on the suitability of geopolymer mixes for extrusion-based additive manufacturing applications. Geopolymer mixes including alkaline potassium silicate activator with different molar ratios were prepared and evaluated for their rheological responses (e.g. yield stress, viscosity and thixotropy) that influenced their extrudability and buildability. Due to the low yield stress of geopolymers, nanoclay was introduced to enhance their thixotropy, which was assessed by structural breakdown and viscosity recovery tests. An activator-to-binder ratio of 0.35 and water-to-solid ratio of 0.30 were found to work well with a clay addition of 0.5% (i.e. by mass of total binder component). The addition of nanoclay led to an improvement in the rheological properties of geopolymer nanocomposites, which was attributed to the flocculation characteristic of the clay particles. A small-scale bathroom unit was printed by using the developed geopolymer nanocomposite, indicating the suitability of the proposed mix design to be used in 3D printing applications.

The Effect of Material Fresh Properties and Process Parameters on Buildability and Interlayer Adhesion of 3D Printed Concrete

Abstract: The advent of digital concrete fabrication calls for advancing our understanding of the interaction of 3D printing with material rheology and print parameters, in addition to developing new measurement and control techniques. Thixotropy is the main challenge associated with printable material, which offers high yield strength and low viscosity. The higher the thixotropy, the better the shape stability and the higher buildability. However, exceeding a minimum value of thixotropy can cause high extrusion pressure and poor interface bond strength if the printing parameters are not optimized to the part design. This paper aims to investigate the effects of both material and process parameters on the buildability and inter-layer adhesion properties of 3D printed cementitious materials, produced with different thixotropy and print head standoff distances. Nano particles are used to increase the thixotropy and, in this context, a lower standoff distance is found to be useful for improving the bond strength. The low viscosity “control” sample is unaffected by the variation in standoff distances, which is attributed to its flowability and low yield stress characteristics that lead to strong interfacial bonding. This is supported by our microscopic observations.

Improving printability of limestone-calcined clay-based cementitious materials by using viscosity-modifying admixture

Abstract: In 3D concrete printing (3DCP), it is necessary to meet contradicting rheological requirements: high fluidity during pumping and extrusion, and high stability and viscosity at rest to build the layered structure. In this paper, the impact of the hydroxypropyl methylcellulose (HPMC)-based viscosity-modifying admixture (VMA) on the 3D printability and mechanical performance of a limestone and calcined clay based cementitious material is investigated. A combination of VMA and superplasticizer was used for that purpose. In this case, controlling the competitive effects between VMA and superplasticizer becomes critical. The main strategy for 3D printing in this study was to add an optimal dosage of VMA in the solid suspension that was already mixed with water and superplasticizer. A lab-scale 3DCP setup was developed and demonstrated as well. A series of tests was performed to characterize the effects of VMA on flowability, extrudability, open time, buildability, green strength, hydration, compressive strength, and air void content and distribution. Experiments performed in this study showed that the mixture containing 0.24% (of the binder mass) of VMA exhibited satisfactory 3D printability and optimal mechanical performance. Finally, the results, limitations, and perspectives of the current research were discussed.