Showing papers by "Yu. N. Ogibin published in 1970"
TL;DR: The kinetics of the decomposition of tertiary butyl hydroperoxide and the rate of generation of free radicals from it at 130° in methyl caproate and its chlorobenzene solutions were studied in this paper.
Abstract: 1.
The kinetics of the decomposition of tertiary butyl hydroperoxide and the rate of generation of free radicals from it at 130° in methyl caproate and its chlorobenzene solutions was studied.
2.
In thermal decomposition in esters, tert-butyl hydroperoxide decomposes chiefly through its acylation by the ester, followed by homolysis of the intermediate perester formed.
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