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Yu. N. Shebeko

Bio: Yu. N. Shebeko is an academic researcher from Russian Ministry of the Emergency Situations. The author has contributed to research in topics: Combustion & Hydrogen. The author has an hindex of 9, co-authored 92 publications receiving 471 citations.


Papers
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Journal ArticleDOI
TL;DR: In this paper, the physical nature of flammability limits is considered using some peculiarities of the chemical kinetics of combustion of gaseous organic substances in air, and new features of lower flammable limits and compositions of mixtures near peak points of FL curves are revealed.

82 citations

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TL;DR: In this paper, burning velocities and flammability limits of gaseous mixtures of combustible gas (hydrogen and methane), oxidizer (oxygen and air), and diluent (nitrogen, argon, helium, carbon dioxide, steam, water aerosol formed by evaporation of superheated water) have been measured at elevated temperatures ( up to 250°C) and pressures (up to 4.0 MPa).

77 citations

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TL;DR: In this article, the influence of various fluorinated inhibitors on the combustion characteristics of mixtures of hydrogen and air and also of methane and air in a closed vessel has been investigated experimentally.

69 citations

Journal ArticleDOI
TL;DR: The considered methods for protection of LPG vessels are promising in regard to prevention of explosions in these vessels at the fire engulfment, according to a simple mathematical model.

28 citations

Journal ArticleDOI
TL;DR: In this article, potential, individual and social risks were calculated for a large-scale oil terminal in the Russian Federation, and the potential risk was defined as a frequency of occurrence of hazardous factors of fires and explosions in a given point of space (the so-called risk contours).
Abstract: Now in Russian Federation and other countries large-scale oil terminals (volume of one tank exceeds 100 000 m 3 , total volume of tanks exceeds 300 000 m 3 ) are designed and constructed. Therefore fire safety of such objects becomes a very important task, solution of which is hardly possible without detail fire risk assessment. This study is aimed to a solution of this problem. Potential, individual and social risks were calculated. The potential risk was defined as a frequency of occurrence of hazardous factors of fires and explosions in a given point of space (the so-called risk contours). The individual risk was defined as a frequency of injuring a given person by hazardous factors of fires and explosions. Time of presence of this person in hazardous zones (near the hazardous installation) is taken into account during calculations of the individual risk. Social risk was defined as a dependence of frequency of injuring a given number of people by hazardous factors of fires and explosions on this number. In practice the social risk is usually determined on injuring not less than 10 people. The oil terminal under consideration includes the following main parts: crude oil storage consisting of three tanks of volume 100 000 m 3 each, input crude oil pipeline of diameter 0.6 m, crude oil pumps, output crude oil pipeline of diameter 0.8 m, auxiliary buildings and facilities. The following main scenarios of tank fires have been considered: rim seal fire, pool fire on a surface of a floating roof, pool fire on a total cross-section surface of the tank, pool fire in a dyke, explosions in closed or semiclosed volumes. Fires and explosions in other parts of the terminal are also taken into account. Effects of escalation of accidents are considered. Risk contours have been calculated both for the territory of the terminal and for the neighbouring space. The potential risk for the storage zone is near 10 −4 –10 −5 year −1 , and at a distance 500 m from the terminal the potential risk values do not exceed 10 −6 year −1 . The values of the individual risk for various categories of workers are in the range of 10 −5 –10 −6 year −1 . Because of low number of the workers on the terminal and large distances to towns and villages the social risk value is negligible. These risk values are consistent with practice of the best oil companies, and fire hazard level of the terminal can be accepted as tolerable.

24 citations


Cited by
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Journal ArticleDOI
TL;DR: In this article, the authors highlight previous influential studies and ongoing research to use this chemical as a viable energy vector for power applications, emphasizing the challenges that each of the reviewed technologies faces before implementation and commercial deployment is achieved at a larger scale.

908 citations

Journal ArticleDOI
01 Sep 1938-Nature
TL;DR: Bone, Newitt and Townend as mentioned in this paper published a comprehensive monograph "Flame and Combustion in Gases" by Prof. W. de C. Ellis and W. A. Townend.
Abstract: ELEVEN years ago appeared the comprehensive monograph entitled “Flame and Combustion in Gases” by Prof. W. A. Bone and D. T. A. Townend, followed a year or two later by “Gaseous Combustion at High Pressures” by Bone, Newitt and Townend. Except for a small volume on "Flame"by 0. C. de C. Ellis and W. A. Kirkby (1936), the subject has not since been treated as a whole in English, until the recent appearance of the work by Bernard Lewis and G. von Elbe now under review. Combustion, Flames and Explosions of Gases By Dr. Bernard Lewis Dr. Guenther von Elbe. (The Cambridge Series of Physical Chemistry.) Pp. xiv + 415. (Cambridge: At the University Press, 1938.) 21s. net.

290 citations

Journal ArticleDOI
TL;DR: In this article, a modified test rig has been developed from the former Cardiff University ‘Cloud Chamber’ for this experimental study, which comprises of a 250-mm length cylindrical stainless steel explosion bomb enclosed at one end with a stainless steel plug which houses an internal stirrer to allow mixing.

281 citations

Journal ArticleDOI
TL;DR: In this paper, flammability maps of hydrogen-methane-ammonia-nitrous oxide-oxygen-nitrogen mixtures were determined and the influence of small amounts of oxygen on the flammable properties of these mixtures has been investigated.

238 citations

Journal ArticleDOI
Jun Li1, Hongyu Huang1, Noriyuki Kobayashi1, Zhaohong He, Yoshihiro Nagai1 
TL;DR: In this article, the potential of hydrogen (H-2) and ammonia (NH3) as carbon-free fuels was evaluated, and the results showed that NH3 burning velocity improved because of increased amounts of hydrogen atom in flame with the addition of H-2 atom.
Abstract: This paper evaluates the potential of hydrogen (H-2) and ammonia (NH3) as carbon-free fuels The combustion characteristics and NOx formation in the combustion of H-2 and NH3 at different air-fuel equivalence ratios and initial H-2 concentrations in the fuel gas were experimentally studied NH3 burning velocity improved because of increased amounts of H-2 atom in flame with the addition of H-2 NH3 burning velocity could be moderately improved and could be applied to the commercial gas engine together with H-2 as fuels H-2 has an accelerant role in H-2-NH3-air combustion, whereas NH3 has a major effect on the maximum burning velocity of H-2-NH3-air In addition, fuel-NOx has a dominant role and thermal-NOx has a negligible role in H-2-NH3-air combustion Thermal-NOx decreases in H-2-NH3-air combustion compared with pure H-2-air combustion NOx concentration reaches its maximum at stoichiometric combustion Furthermore, H-2 is detected at an air-fuel equivalence ratio of 100 for the decomposition of NH3 in flame Hence, the stoichiometric combustion of H-2 and NH3 should be carefully considered in the practical utilization of H-2 and NH3 as fuels H-2 as fuel for improving burning performance with moderate burning velocity and NOx emission enables the utilization of H-2 and NH3 as promising fuels Copyright (C) 2014 John Wiley & Sons, Ltd

226 citations