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Yunjie Yan

Bio: Yunjie Yan is an academic researcher from Tsinghua University. The author has contributed to research in topics: Transmission electron microscopy & Carbon nanotube. The author has an hindex of 5, co-authored 5 publications receiving 1172 citations.

Papers
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Journal ArticleDOI
Changqiang Chen1, Yu Shi1, Yejin Zhang1, Jun Zhu1, Yunjie Yan1 
TL;DR: A core-shell composite NW model in terms of the surface stiffening effect correlated with significant bond length contractions occurred near the {1010} free surfaces is proposed to explore the origin of the size dependence, and it is possible to estimate the size-related elastic properties of GaN nanotubes and relative nanostructures by using this model.
Abstract: We report a size dependence of Young's modulus in [0001] oriented ZnO nanowires (NWs) with diameters ranging from 17 to 550 nm for the first time. The measured modulus for NWs with diameters smaller than about 120 nm is increasing dramatically with the decreasing diameters, and is significantly higher than that of the larger ones whose modulus tends to that of bulk ZnO. A core-shell composite NW model in terms of the surface stiffening effect correlated with significant bond length contractions occurred near the {1010} free surfaces (which extend several layers deep into the bulk and fade off slowly) is proposed to explore the origin of the size dependence, and present experimental result is well explained. Furthermore, it is possible to estimate the size-related elastic properties of GaN nanotubes and relative nanostructures by using this model.

995 citations

Journal ArticleDOI
Yingjiu Zhang1, Qi Zhang1, Nanlin Wang1, Yunjie Yan1, Huihua Zhou1, Jing Zhu1 
TL;DR: In this paper, the smallest diameter of the Si nanowires is about 10nm, which therefore makes them the thinnest Si-nowires fabricated by using SiCl 4 as Si source.

85 citations

Journal ArticleDOI
Yingjiu Zhang1, Jing Zhu1, Qi Zhang1, Yunjie Yan1, Nanlin Wang1, Xiaozhong Zhang1 
TL;DR: In this article, a carbon nanotubes-confined reaction was used to synthesize GeO 2 nanorods, which are perfect single hexagonal crystals covered by an amorphous layer of Ge and O, and have diameters of 50-200 nm and lengths of several μm.

69 citations

Journal ArticleDOI
Yingjiu Zhang1, Nanlin Wang1, Rongrui He1, Qi Zhang1, Jing Zhu1, Yunjie Yan1 
TL;DR: In this paper, a reversible bending phenomenon of Si3N4 nanowires on the conductive carbon-formalin microgrid under an illumination of electron beam was observed using a transmission electron microscope.
Abstract: A reversible bending phenomenon of Si3N4 nanowires on the conductive carbon–formalin microgrid under an illumination of electron beam was observed using a transmission electron microscope. The nanowires exhibit high flexibility. The bending deflection is approximately proportional to the square of the current density (J) of the electron beam. The bending strength of Si3N4 nanowire is much higher than that of bulk Si3N4 materials. The force that bent the nanowires may be an electrostatic force.

57 citations

Journal ArticleDOI
Rongrui He1, H.Z. Jin1, Jing Zhu1, Yunjie Yan1, Xi Chen1 
TL;DR: In this article, the π-bonding is proposed as inter-tube bonding in the bundles of single-walled carbon nanotubes and multilayer carbon nanophores.

32 citations


Cited by
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Journal ArticleDOI
TL;DR: In this article, a review highlights the recent advances in the field, using work from this laboratory for illustration, and the understanding of general nanocrystal growth mechanisms serves as the foundation for the rational synthetic control of one-dimensional nanoscale building blocks, novel properties characterization and device fabrication based on nanowire building blocks.
Abstract: ▪ Abstract Semiconductor nanowires and nanotubes exhibit novel electronic and optical properties owing to their unique structural one-dimensionality and possible quantum confinement effects in two dimensions. With a broad selection of compositions and band structures, these one-dimensional semiconductor nanostructures are considered to be the critical components in a wide range of potential nanoscale device applications. To fully exploit these one-dimensional nanostructures, current research has focused on rational synthetic control of one-dimensional nanoscale building blocks, novel properties characterization and device fabrication based on nanowire building blocks, and integration of nanowire elements into complex functional architectures. Significant progress has been made in a few short years. This review highlights the recent advances in the field, using work from this laboratory for illustration. The understanding of general nanocrystal growth mechanisms serves as the foundation for the rational sy...

1,407 citations

Journal ArticleDOI
TL;DR: In this article, a critical review presents the recent advances and progress in the design and synthesis of various semiconductor photocatalytic technology that converts solar energy into chemical fuel has been widely studied.
Abstract: To solve the problem of the global energy shortage and the pollution of the environment, in recent years, semiconductor photocatalytic technology that converts solar energy into chemical fuel has been widely studied. Regarding semiconductor-based photocatalysts, CdS has attracted extensive attention due to its relatively narrow bandgap for visible-light response and sufficiently negative potential of the conduction band edge for the reduction of protons. Studies have shown that CdS-based photocatalysts possess excellent photocatalytic performance in terms of solar-fuel generation and environmental purification. This critical review presents the recent advances and progress in the design and synthesis of various CdS and CdS-based photocatalysts. The basic physical and chemical properties of CdS and the related growth mechanism have been briefly summarized. Moreover, the applications of CdS-based photocatalysts have been discussed such as in photocatalytic hydrogen production, reduction of CO2 to hydrocarbon fuels and degradation of pollutants. Finally, a brief perspective on the challenges and future directions for the development of CdS and CdS-based photocatalysts are also presented.

1,054 citations

Journal ArticleDOI
TL;DR: In this paper, the characterization methods of carbon nanotubes which are most employed today are reviewed and the most interesting features of each technique are indexed for each technique, including the most important features of the most used techniques.
Abstract: Carbon nanotubes due to their specific atomic structure have interesting chemical and physical properties according to those of graphite and diamond. This review covers the characterization methods of carbon nanotubes which are most employed today. The structure of carbon nanotubes is first briefly summarized followed by a description of the characterization methods such as STM, TEM, neutron diffraction, X-ray diffraction, X-ray photoelectron spectroscopy, infrared and Raman spectroscopy. The most interesting features are indexed for each technique.

787 citations

Journal ArticleDOI
TL;DR: The BOLS correlation mechanism has been initiated and intensively verified as discussed by the authors, which has enabled the tunability of a variety of properties of a nanosolid to be universally reconciled to the effect of bond order deficiency of atoms at sites surrounding defects or near the surface edges of the nano-material.

775 citations