scispace - formally typeset
Search or ask a question
Author

Zhigang Suo

Other affiliations: Brown University, Hansung University, Seoul National University  ...read more
Bio: Zhigang Suo is an academic researcher from Harvard University. The author has contributed to research in topics: Self-healing hydrogels & Dielectric. The author has an hindex of 124, co-authored 510 publications receiving 56487 citations. Previous affiliations of Zhigang Suo include Brown University & Hansung University.


Papers
More filters
Journal ArticleDOI
06 Sep 2012-Nature
TL;DR: The synthesis of hydrogels from polymers forming ionically and covalently crosslinked networks is reported, finding that these gels’ toughness is attributed to the synergy of two mechanisms: crack bridging by the network of covalent crosslinks, and hysteresis by unzipping thenetwork of ionic crosslinks.
Abstract: Hydrogels with improved mechanical properties, made by combining polymer networks with ionic and covalent crosslinks, should expand the scope of applications, and may serve as model systems to explore mechanisms of deformation and energy dissipation. Hydrogels are used in flexible contact lenses, as scaffolds for tissue engineering and in drug delivery. Their poor mechanical properties have so far limited the scope of their applications, but new strong and stretchy materials reported here could take hydrogels into uncharted territories. The new system involves a double-network gel, with one network forming ionic crosslinks and the other forming covalent crosslinks. The fracture energy of these materials is very high: they can stretch to beyond 17 times their own length even when containing defects that usually initiate crack formation in hydrogels. The materials' toughness is attributed to crack bridging by the covalent network accompanied by energy dissipation through unzipping of the ionic crosslinks in the second network. Hydrogels are used as scaffolds for tissue engineering1, vehicles for drug delivery2, actuators for optics and fluidics3, and model extracellular matrices for biological studies4. The scope of hydrogel applications, however, is often severely limited by their mechanical behaviour5. Most hydrogels do not exhibit high stretchability; for example, an alginate hydrogel ruptures when stretched to about 1.2 times its original length. Some synthetic elastic hydrogels6,7 have achieved stretches in the range 10–20, but these values are markedly reduced in samples containing notches. Most hydrogels are brittle, with fracture energies of about 10 J m−2 (ref. 8), as compared with ∼1,000 J m−2 for cartilage9 and ∼10,000 J m−2 for natural rubbers10. Intense efforts are devoted to synthesizing hydrogels with improved mechanical properties11,12,13,14,15,16,17,18; certain synthetic gels have reached fracture energies of 100–1,000 J m−2 (refs 11, 14, 17). Here we report the synthesis of hydrogels from polymers forming ionically and covalently crosslinked networks. Although such gels contain ∼90% water, they can be stretched beyond 20 times their initial length, and have fracture energies of ∼9,000 J m−2. Even for samples containing notches, a stretch of 17 is demonstrated. We attribute the gels’ toughness to the synergy of two mechanisms: crack bridging by the network of covalent crosslinks, and hysteresis by unzipping the network of ionic crosslinks. Furthermore, the network of covalent crosslinks preserves the memory of the initial state, so that much of the large deformation is removed on unloading. The unzipped ionic crosslinks cause internal damage, which heals by re-zipping. These gels may serve as model systems to explore mechanisms of deformation and energy dissipation, and expand the scope of hydrogel applications.

3,856 citations

Book ChapterDOI
TL;DR: In this article, the authors describe the mixed mode cracking in layered materials and elaborates some of the basic results on the characterization of crack tip fields and on the specification of interface toughness, showing that cracks in brittle, isotropic, homogeneous materials propagate such that pure mode I conditions are maintained at the crack tip.
Abstract: Publisher Summary This chapter describes the mixed mode cracking in layered materials. There is ample experimental evidence that cracks in brittle, isotropic, homogeneous materials propagate such that pure mode I conditions are maintained at the crack tip. An unloaded crack subsequently subject to a combination of modes I and II will initiate growth by kinking in such a direction that the advancing tip is in mode I. The chapter also elaborates some of the basic results on the characterization of crack tip fields and on the specification of interface toughness. The competition between crack advance within the interface and kinking out of the interface depends on the relative toughness of the interface to that of the adjoining material. The interface stress intensity factors play precisely the same role as their counterparts in elastic fracture mechanics for homogeneous, isotropic solids. When an interface between a bimaterial system is actually a very thin layer of a third phase, the details of the cracking morphology in the thin interface layer can also play a role in determining the mixed mode toughness. The elasticity solutions for cracks in multilayers are also elaborated.

3,828 citations

Journal ArticleDOI
30 Aug 2013-Science
TL;DR: A class of devices enabled by ionic conductors that are highly stretchable, fully transparent to light of all colors, and capable of operation at frequencies beyond 10 kilohertz and voltages above 10 kilovolts are described.
Abstract: Existing stretchable, transparent conductors are mostly electronic conductors. They limit the performance of interconnects, sensors, and actuators as components of stretchable electronics and soft machines. We describe a class of devices enabled by ionic conductors that are highly stretchable, fully transparent to light of all colors, and capable of operation at frequencies beyond 10 kilohertz and voltages above 10 kilovolts. We demonstrate a transparent actuator that can generate large strains and a transparent loudspeaker that produces sound over the entire audible range. The electromechanical transduction is achieved without electrochemical reaction. The ionic conductors have higher resistivity than many electronic conductors; however, when large stretchability and high transmittance are required, the ionic conductors have lower sheet resistance than all existing electronic conductors.

1,331 citations

Journal ArticleDOI
TL;DR: In this paper, the authors study cracks either in piezoelectrics, or on interfaces between the materials such as metal electrodes or polymer matrices, and derive the macroscopic field regarding the crack tip as a physically structureless point.
Abstract: We Study cracks either in piezoelectrics, or on interfaces between piezoelectrics and other materials such as metal electrodes or polymer matrices. The projected applications include ferroelectric actuators operating statically or cyclically, over the major portion of the samples, in the linear regime of the constitutive curve, but the elevated field around defects causes the materials to undergo hysteresis locally. The fracture mechanics viewpoint is adopted—that is, except for a region localized at the crack tip, the materials are taken to be linearly piezoelectric. The problem thus breaks into two subproblems: (i) determining the macroscopic field regarding the crack tip as a physically structureless point, and (ii) considering the hysteresis and other irreversible processes near the crack tip at a relevant microscopic level. The first Subproblem, which prompts a phenomenological fracture theory, receives a thorough investigation in this paper. Griffith's energy accounting is extended to include energy change due to both deformation and polarization. Four modes of square root singularities are identified at the tip of a crack in a homogeneous piezoelectric. A new type of singularity is discovered around interface crack tips. Specifically, the singularities in general form two pairs: r1/2±ieand r1/2±ie, where e. and k are real numbers depending on the constitutive constants. Also solved is a class of boundary value problems involving many cracks on the interface between half-spaces. Fracture mechanics are established for ferroelectric ceramics under smallscale hysteresis conditions, which facilitates the experimental study of fracture resistance and fatigue crack growth under combined mechanical and electrical loading. Both poled and unpoled fcrroelectrie ceramics are discussed.

1,112 citations

Journal ArticleDOI
TL;DR: In this paper, thin gold films are made on an elastomeric substrate with built-in compressive stress to form surface waves, which function as elastic electrical conductors.
Abstract: Stripes of thin gold films are made on an elastomeric substrate with built-in compressive stress to form surface waves. Because these waves can be stretched flat they function as elastic electrical conductors. Surprisingly, we observe electrical continuity not only up to an external strain of ∼2% reached by stretching the films first flat (∼0.4%) and then to the fracture strain of free-standing gold films (∼1%), but up to ∼22%. Such large strains will permit making stretchable electric conductors that will be essential to three-dimensional electronic circuits.

939 citations


Cited by
More filters
Journal ArticleDOI

[...]

08 Dec 2001-BMJ
TL;DR: There is, I think, something ethereal about i —the square root of minus one, which seems an odd beast at that time—an intruder hovering on the edge of reality.
Abstract: There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality. Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

33,785 citations

28 Jul 2005
TL;DR: PfPMP1)与感染红细胞、树突状组胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作�ly.
Abstract: 抗原变异可使得多种致病微生物易于逃避宿主免疫应答。表达在感染红细胞表面的恶性疟原虫红细胞表面蛋白1(PfPMP1)与感染红细胞、内皮细胞、树突状细胞以及胎盘的单个或多个受体作用,在黏附及免疫逃避中起关键的作用。每个单倍体基因组var基因家族编码约60种成员,通过启动转录不同的var基因变异体为抗原变异提供了分子基础。

18,940 citations

Journal ArticleDOI
01 Apr 1988-Nature
TL;DR: In this paper, a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) is presented.
Abstract: Deposits of clastic carbonate-dominated (calciclastic) sedimentary slope systems in the rock record have been identified mostly as linearly-consistent carbonate apron deposits, even though most ancient clastic carbonate slope deposits fit the submarine fan systems better. Calciclastic submarine fans are consequently rarely described and are poorly understood. Subsequently, very little is known especially in mud-dominated calciclastic submarine fan systems. Presented in this study are a sedimentological core and petrographic characterisation of samples from eleven boreholes from the Lower Carboniferous of Bowland Basin (Northwest England) that reveals a >250 m thick calciturbidite complex deposited in a calciclastic submarine fan setting. Seven facies are recognised from core and thin section characterisation and are grouped into three carbonate turbidite sequences. They include: 1) Calciturbidites, comprising mostly of highto low-density, wavy-laminated bioclast-rich facies; 2) low-density densite mudstones which are characterised by planar laminated and unlaminated muddominated facies; and 3) Calcidebrites which are muddy or hyper-concentrated debrisflow deposits occurring as poorly-sorted, chaotic, mud-supported floatstones. These

9,929 citations