Showing papers presented at "International Conference Chemical and Material Engineering in 2016"

Experimental Study of a Cu-Mo Alloy Vapor Chamber

Abstract: In this research, the thermal behavior of a vapor chamber embedded in the base of a heat sink was experimentally analyzed considering the influence of the heat source position. The vapor chamber was produced by a copper and molybdenum alloy with length of 240 mm, width of 54 mm, thickness of 3 mm, and capillary structures composed by copper screen meshes. The working fluid used was de-ionized water. The pure aluminum heat sink was cooled by air forced convection and the evaporator vapor chamber was heated using an electrical resistor simulating integrated circuit power dissipation. The experimental tests were done in a suction type wind tunnel with open return for a heat load varying from 20 to 80 W, for an airflow velocity varying from 1 to 4 m/s, and for three different heat source positions. The experimental results showed that, independently of the heat source position, the considered vapor chamber worked successfully, maintaining low operating temperature.

Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts

Abstract: Even though platinum is known as an active electro-catalyst for ethanol oxidation at low temperatures (< 100 oC), choosing the electrode material for ethanol electro-oxidation is a crucial issue. It is due to its property which easily poisoned by a strong adsorbed species such as CO. PtSn-based electro-catalysts have been identified as better catalysts for ethanol electro-oxidation. The third material is supposed to improved binary catalysts performance. This work presents a study of the ethanol electro-oxidation on carbon supported Pt-Sn and Pt-Sn-Ni catalysts. These catalysts were prepared by alcohol reduction. Nano-particles with diameters between 2.5-5.0 nm were obtained. The peak of (220) crystalline face centred cubic (fcc) Pt phase for PtSn and PtSnNi alloys was repositioned due to the presence of Sn and/or Ni in the alloy. Furthermore, the modification of Pt with Sn and SnNi improved ethanol and CO electro-oxidation. Copyright © 2016 BCREC GROUP. All rights reserved Received: 10 th November 2015; Revised: 1 st February 2016; Accepted: 1 st February 2016 How to Cite : Hidayati, N., Scott, K. (2016). Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis , 11 (1): 10-20. (doi:10.9767/bcrec.11.1.399.10-20) Permalink/DOI : http://dx.doi.org/10.9767/bcrec.11.1.399.10-20 Article Metrics: (click on the button below to see citations in Scopus)

The Effect Of Fibre Layering Pattern In Resisting Bending Loads Of Natural Fibre-Based Hybrid Composite Materials

Abstract: The effect of fibre layering pattern and hybridization on the flexural properties of composite hybrid laminates between natural fibres of basalt, jute and flax with synthetic fibre of E-glass reinforced epoxy have been investigated experimentally. Results showed that the effect fibre layering pattern was highly significant on the flexural strength and modulus, which were strongly dependent on the hybrid configuration between sandwich-like (SL) and intercalation (IC) sequence of fibre layers. In addition, specific modulus based on the variation densities of the hybrid laminates was used to discover the best combination either basalt, jute or flax with E-glass exhibits superior properties concerning on the strength to weight-ratio. Generally, SL sequence of glass/basalt exhibited superior strength and stiffness compared with glass/jute and glass/flax in resisting bending loads. In terms of hybridization effect, glass/jute was found to be the best combination with E-glass compared to the rest of natural fibres investigated in the present study. Hence, the proper stacking sequences and material selection are among predominant factors that influence on mechanical properties and very crucial in designing composite hybrid system to meet the desired requirements.

Mechanical and morphological properties of nano filler polyester composites

Abstract: This research is focusing on mechanical and morphological properties of unsaturated polyester (UP) reinforced with two different types of filler which is nano size clay Cloisite 30B (C30B) and Carbon Black (CB). Samples were fabricated via hand lay-up and open molding technique. Percentages of Cloisite 30B & Carbon Black (CB) used vary from 0, 2, 4, 6, 8 and 10 wt%. The mechanical properties were evaluated by impact, flexural and hardness testing. Result shows that the mechanical strength of C30B was better compare to CB filled composite. The combination of UP with C30B helps to improve the properties due to the high surface area of nanosize filler in the matrix. The result shows that increasing of filler content had increased mechanical properties of composites. Optimum percentage represent good mechanical properties are 4% for both fillers. SEM images showed that rough surface image indicate to agglomeration of filler in the matrix for CB sample and smooth surface image on C30B sample indicate to homogenous blending between filler and matrix polyester. SEM images proved that mechanical properties result indicate that C30B polyester composite is a good reinforcement compare to CB polyester composite.

Kinetic Modeling of C3H6 Inhibition on NO Oxidation over Pt Catalyst

Abstract: Exhaust after treatment for lean burn and diesel engine is a complex catalytic system that consists of a number of catalytic units. Pt/Al2O3is often used as a model Diesel Oxidation Catalyst (DOC) that plays an important role to facilitate oxidation of NO to NO2. In the present study, we proposed a detailed kinetic model of NO oxidation as well as low temperature C3H6 inhibition to simulate temperatureprogrammed reaction (TPR) data for NO oxidation over Pt/Al2O3. A steady-state microkinetic model based on Langmuir-Hinshelwood mechanism for NO oxidation was proposed. In addition, low temperature C3H6inhibition was proposed as a result of site blocking as well as surface nitrite consumption. The model can explain the experimental data well over the studied temperature range.