International Conference on Nanoscience and Nanotechnology 

About: International Conference on Nanoscience and Nanotechnology is an academic conference. The conference publishes majorly in the area(s): Thin film & Carbon nanotube. Over the lifetime, 838 publications have been published by the conference receiving 2880 citations.

Plant Extract as Reducing Agent in Synthesis of Metallic Nanoparticles: A Review

Abstract: The aim of this paper is to discuss on the roles of plant extract in the synthesis of metallic nanoparticles. Synthesis of metallic nanoparticles has started few decades ago through physical and chemical methods. Recently, green technology through biosynthesis method has drawn great attention compared to the physical and chemical method. Biosynthesis was found to be more energy efficient and able to eliminate the use of hazardous chemicals. The biosynthesis studies involved the application of fungi, bacteria, yeast, algae and plant extract. Plant extract has several advantages since the use of microorganism required stringent control on cell culture. Furthermore, the reaction rate is much faster as compared to that of the microorganism methods. The important compounds in the plant extract are hydroxyl and carbonyl groups. Both functional groups allowed plant extract to act as reducing agent as well as stabilizing agent. Several studies have been carried out to optimize the extraction of these compounds such as plant drying technique, extraction temperature and type of extractions solvent. The common method used to quantify the concentration of reducing agents in the extract is through Folin-Ciocalteu method. Utilization of plant extract not only capable of producing well dispersed monometallic nanoparticles, but also bimetallic nanoparticles. Previous studies revealed that concentration of plant extract has significant effect on particle size and shape as well as particle distribution.

Soluble carbon nanotubes and their applications

Abstract: Carbon nanotubes (CNTs) have been the forefront of nanoscience and nanotechnology due to their unique electrical and mechanical properties and specific functions. However, due to their poor solubility in solvents, the applications using the materials have been limited. Therefore, strategic approaches toward the solubilization of CNTs are important in wide fields including chemistry, physics, biochemistry, biology, pharmaceuticals, and medical sciences. In this article, we summarize: (i) the strategic approaches toward the solubilization of CNTs using chemical and physical modifications, (ii) nanocomposites of CNTs and biological molecules including DNA, (iii) formation of CNTs with topological structures, (iv) separation of metallic and semiconducting nanotubes, (v) the preparations of films and fibers of CNTs and hybrid materials of CNTs and organic and inorganic molecules.

The synthesis of metallic nanoparticles inside live plants

Abstract: There is increasing commercial demand for nanoparticles because of their wide applicability in a growing number of fields, e.g. electronics, catalysis, chemistry, energy, and medicine. Metallic nanoparticles are traditionally synthesized by wet chemical techniques, where the chemicals used are quite often toxic and flammable. In this work, we describe a cost effective and environmentally sound technique for the synthesis of metallic nanoparticles using live plants. We have adopted the generic term, phytosynthesis to describe this process. Nanoparticles of common heavy metal ions, e.g. Ag, Cu, Co, Zn and Ni, were synthesized by exposing plants to aqueous metal salt solutions. These experiments were used to evaluate the potential of two known hyperaccumulator species Brassica juncea, Helianthus annus and Medicago sativa for producing nanoparticles. The influence of exposure time, substrate metal ion concentration and chelating agent addition were all investigated. Brassica juncea was found to be the best plant for sequestering metals from aqueous solutions and depositing them as intracellular nanoparticles. Metal concentrations were determined by atomic absorption and inductively coupled plasma spectroscopy. Transmission electron microscopy was used to measure the size and shape of the nanoparticles formed.

Deposition of gold nanoparticles on electrospun MgTiO3 ceramic nanofibers.

Abstract: A simple method to deposit spherical gold nanoparticles on the surface of MgTiO3 ceramic nanofibers is presented. Electrospun MgTiO3/poly(vinyl acetate) (PVAc) hybrid nanofibers were calcined at 650 degrees C to obtain phase pure ceramic MgTiO3 nanofibers with 100-150 nm diameters. These ceramic nanofibers were immersed in an aqueous solution of HAuCl4 containing poly(vinyl alcohol) (PVA) as capping agent followed by photoreduction at 365 nm to get a novel Au-MgTiO3 nanocomposite. The formation of gold nanoparticles upon irradiation was confirmed by the appearance of a surface plasmon band (SPB) at 590 nm in the UV-visible absorption spectra. The surface morphology and elemental compositions were analyzed by the scanning electron microscope (SEM) equipped with energy dispersive X-ray (EDX), and transmission electron microscope (TEM). X-ray diffraction (XRD) and selected area diffraction (SAED) pattern in TEM revealed the crystallization of gold by exhibiting strong diffractions correspond to Au(111) and Au(200) crystalline planes in addition to the MgTiO3 diffraction.

Extracellular synthesis of magnetite and metal-substituted magnetite nanoparticles.

Abstract: We have developed a novel microbial process that exploits the ability of Fe(III)-reducing microorganisms to produce copious amounts of extracellular magentites and metal-substituted magnetite nanoparticles. The Fe(III)-reducing bacteria (Theroanaerobacter ethanolicus and Shewanella sp.) have the ability to reduce Fe(III) and various metals in aqueous media and form various sized magnetite and metal-substituted magnetite nano-crystals. The Fe(III)-reducing bacteria formed metalsubstituted magnetites using iron oxide plus metals (e.g., Co, Cr, Mn, Ni) under conditions of relatively low temperature (<70 degrees C), ambient pressure, and pH values near neutral to slightly basic (pH = 6.5 to 9). Precise biological control over activation and regulation of the biosolid-state processes can produce magnetite particles of well-defined size (typically tens of nanometers) and crystallographic morphology, containing selected dopant metals into the magnetite (Fe(3-y)XyO4) structure (where X = Co, Cr, Mn, Ni). Magnetite yields of up to 20 g/L per day have been observed in 20-L vessels. Water-based ferrofluids were formed with the nanometer sized, magnetite, and metal-substituted biomagnetite particles.