Showing papers by "Beihang University published in 2016"

Disturbance-Observer-Based Control and Related Methods—An Overview

Abstract: Disturbance-observer-based control (DOBC) and related methods have been researched and applied in various industrial sectors in the last four decades. This survey, at first time, gives a systematic and comprehensive tutorial and summary on the existing disturbance/uncertainty estimation and attenuation techniques, most notably, DOBC, active disturbance rejection control, disturbance accommodation control, and composite hierarchical antidisturbance control. In all of these methods, disturbance and uncertainty are, in general, lumped together, and an observation mechanism is employed to estimate the total disturbance. This paper first reviews a number of widely used linear and nonlinear disturbance/uncertainty estimation techniques and then discusses and compares various compensation techniques and the procedures of integrating disturbance/uncertainty compensation with a (predesigned) linear/nonlinear controller. It also provides concise tutorials of the main methods in this area with clear descriptions of their features. The application of this group of methods in various industrial sections is reviewed, with emphasis on the commercialization of some algorithms. The survey is ended with the discussion of future directions.

Designing high-energy lithium–sulfur batteries

Abstract: Due to their high energy density and low material cost, lithium–sulfur batteries represent a promising energy storage system for a multitude of emerging applications, ranging from stationary grid storage to mobile electric vehicles. This review aims to summarize major developments in the field of lithium–sulfur batteries, starting from an overview of their electrochemistry, technical challenges and potential solutions, along with some theoretical calculation results to advance our understanding of the material interactions involved. Next, we examine the most extensively-used design strategy: encapsulation of sulfur cathodes in carbon host materials. Other emerging host materials, such as polymeric and inorganic materials, are discussed as well. This is followed by a survey of novel battery configurations, including the use of lithium sulfide cathodes and lithium polysulfide catholytes, as well as recent burgeoning efforts in the modification of separators and protection of lithium metal anodes. Finally, we conclude with an outlook section to offer some insight on the future directions and prospects of lithium–sulfur batteries.

Ultrahigh power factor and thermoelectric performance in hole-doped single-crystal SnSe

Abstract: Thermoelectric technology, harvesting electric power directly from heat, is a promising environmentally friendly means of energy savings and power generation. The thermoelectric efficiency is determined by the device dimensionless figure of merit ZT(dev), and optimizing this efficiency requires maximizing ZT values over a broad temperature range. Here, we report a record high ZT(dev) ∼1.34, with ZT ranging from 0.7 to 2.0 at 300 to 773 kelvin, realized in hole-doped tin selenide (SnSe) crystals. The exceptional performance arises from the ultrahigh power factor, which comes from a high electrical conductivity and a strongly enhanced Seebeck coefficient enabled by the contribution of multiple electronic valence bands present in SnSe. SnSe is a robust thermoelectric candidate for energy conversion applications in the low and moderate temperature range.

Rationally Designing High-Performance Bulk Thermoelectric Materials

Abstract: There has been a renaissance of interest in exploring highly efficient thermoelectric materials as a possible route to address the worldwide energy generation, utilization, and management. This review describes the recent advances in designing high-performance bulk thermoelectric materials. We begin with the fundamental stratagem of achieving the greatest thermoelectric figure of merit ZT of a given material by carrier concentration engineering, including Fermi level regulation and optimum carrier density stabilization. We proceed to discuss ways of maximizing ZT at a constant doping level, such as increase of band degeneracy (crystal structure symmetry, band convergence), enhancement of band effective mass (resonant levels, band flattening), improvement of carrier mobility (modulation doping, texturing), and decrease of lattice thermal conductivity (synergistic alloying, second-phase nanostructuring, mesostructuring, and all-length-scale hierarchical architectures). We then highlight the decoupling of th...

High-Performance Electron Acceptor with Thienyl Side Chains for Organic Photovoltaics.

Abstract: We develop an efficient fused-ring electron acceptor (ITIC-Th) based on indacenodithieno[3,2-b]thiophene core and thienyl side-chains for organic solar cells (OSCs). Relative to its counterpart with phenyl side-chains (ITIC), ITIC-Th shows lower energy levels (ITIC-Th: HOMO = −5.66 eV, LUMO = −3.93 eV; ITIC: HOMO = −5.48 eV, LUMO = −3.83 eV) due to the σ-inductive effect of thienyl side-chains, which can match with high-performance narrow-band-gap polymer donors and wide-band-gap polymer donors. ITIC-Th has higher electron mobility (6.1 × 10–4 cm2 V–1 s–1) than ITIC (2.6 × 10–4 cm2 V–1 s–1) due to enhanced intermolecular interaction induced by sulfur–sulfur interaction. We fabricate OSCs by blending ITIC-Th acceptor with two different low-band-gap and wide-band-gap polymer donors. In one case, a power conversion efficiency of 9.6% was observed, which rivals some of the highest efficiencies for single junction OSCs based on fullerene acceptors.

Bioinspired Interfaces with Superwettability: From Materials to Chemistry

Abstract: Superwettability is a special case of the wetting phenomenon among liquids, gases, and solids. The superhydrophobic/superhydrophilic effect discovered initially has undergone a century of development based on materials science and biomimetics. With the rapid development of research on anti-wetting materials, superoleophobic/superoleophilic surfaces have been fabricated to repel organic liquids besides water. Further studies of underwater superoleophobic/superoleophilic/superaerophobic/superaerophilic materials provide an alternative way to fabricate anti-wetting surfaces rather than lowering the surface energy. Owing to a series of efforts on the studying of extreme wettabilities, a mature superwettability system gradually evolved and has since become a vibrant area of active research, covering topics of superhydrophobicity/superhydrophilicity, superoleophobicity/superoleophilicity in gas or under liquid, superaerophobicity/superaerophilicity under liquid, and combinations of these states. The kinetic stu...

A Facile Planar Fused-Ring Electron Acceptor for As-Cast Polymer Solar Cells with 8.71% Efficiency

Abstract: A planar fused-ring electron acceptor (IC-C6IDT-IC) based on indacenodithiophene is designed and synthesized. IC-C6IDT-IC shows strong absorption in 500–800 nm with extinction coefficient of up to 2.4 × 105 M–1 cm–1 and high electron mobility of 1.1 × 10–3 cm2 V–1 s–1. The as-cast polymer solar cells based on IC-C6IDT-IC without additional treatments exhibit power conversion efficiencies of up to 8.71%.

Continuous directional water transport on the peristome surface of Nepenthes alata

Abstract: Numerous natural systems contain surfaces or threads that enable directional water transport. This behaviour is usually ascribed to hierarchical structural features at the microscale and nanoscale, with gradients in surface energy and gradients in Laplace pressure thought to be the main driving forces. Here we study the prey-trapping pitcher organs of the carnivorous plant Nepenthes alata. We find that continuous, directional water transport occurs on the surface of the 'peristome'--the rim of the pitcher--because of its multiscale structure, which optimizes and enhances capillary rise in the transport direction, and prevents backflow by pinning in place any water front that is moving in the reverse direction. This results not only in unidirectional flow despite the absence of any surface-energy gradient, but also in a transport speed that is much higher than previously thought. We anticipate that the basic 'design' principles underlying this behaviour could be used to develop artificial fluid-transport systems with practical applications.

A Survey of Energy-Efficient Techniques for 5G Networks and Challenges Ahead

Abstract: After about a decade of intense research, spurred by both economic and operational considerations, and by environmental concerns, energy efficiency has now become a key pillar in the design of communication networks. With the advent of the fifth generation of wireless networks, with millions more base stations and billions of connected devices, the need for energy-efficient system design and operation will be even more compelling. This survey provides an overview of energy-efficient wireless communications, reviews seminal and recent contribution to the state-of-the-art, including the papers published in this special issue, and discusses the most relevant research challenges to be addressed in the future.

High-Performance Solution-Processed Non-Fullerene Organic Solar Cells Based on Selenophene-Containing Perylene Bisimide Acceptor

Abstract: Non-fullerene acceptors have recently attracted tremendous interest because of their potential as alternatives to fullerene derivatives in bulk heterojunction organic solar cells. However, the power conversion efficiencies (PCEs) have lagged far behind those of the polymer/fullerene system, mainly because of the low fill factor (FF) and photocurrent. Here we report a novel perylene bisimide (PBI) acceptor, SdiPBI-Se, in which selenium atoms were introduced into the perylene core. With a well-established wide-band-gap polymer (PDBT-T1) as the donor, a high efficiency of 8.4% with an unprecedented high FF of 70.2% is achieved for solution-processed non-fullerene organic solar cells. Efficient photon absorption, high and balanced charge carrier mobility, and ultrafast charge generation processes in PDBT-T1:SdiPBI-Se films account for the high photovoltaic performance. Our results suggest that non-fullerene acceptors have enormous potential to rival or even surpass the performance of their fullerene counterparts.

Engineering surface atomic structure of single-crystal cobalt (II) oxide nanorods for superior electrocatalysis.

Abstract: Engineering the surface structure at the atomic level can be used to precisely and effectively manipulate the reactivity and durability of catalysts. Here we report tuning of the atomic structure of one-dimensional single-crystal cobalt (II) oxide (CoO) nanorods by creating oxygen vacancies on pyramidal nanofacets. These CoO nanorods exhibit superior catalytic activity and durability towards oxygen reduction/evolution reactions. The combined experimental studies, microscopic and spectroscopic characterization, and density functional theory calculations reveal that the origins of the electrochemical activity of single-crystal CoO nanorods are in the oxygen vacancies that can be readily created on the oxygen-terminated {111} nanofacets, which favourably affect the electronic structure of CoO, assuring a rapid charge transfer and optimal adsorption energies for intermediates of oxygen reduction/evolution reactions. These results show that the surface atomic structure engineering is important for the fabrication of efficient and durable electrocatalysts.

Electrochemical Intercalation of Potassium into Graphite

Abstract: Exceptional cycling performance of graphite anode in K-ion batteries is demonstrated with a reversible capacity of 246 mAh g–1 and 89% retention of the initial capacity after 200 cycles. Although the graphite anode experiences huge volume change and worse kinetics during K intercalation/deintercalation, the cycling stability delivered in K-ion batteries is comparable to that of Li-ion batteries using the same graphite anode. The combination of excellent electrochemical performance, the abundance and wide availability of K in earth's crust, and the well-developed technology of the graphite anode make the K-ion battery very attractive for offering a low cost battery chemistry for large-scale energy storage applications.

MXene: a promising photocatalyst for water splitting

Abstract: Identifying suitable photocatalysts for photocatalytic water splitting to produce hydrogen fuel via sunlight is an arduous task by the traditional trial-and-error method. Thanks to the progress of density functional theory, one can nowadays accelerate the process of finding candidate photocatalysts. In this work, by ab initio calculations, we investigated 48 two-dimensional (2D) transition metal carbides also referred to as MXenes to understand their photocatalytic properties. Our results highlight 2D Zr2CO2 and Hf2CO2 as the candidate single photocatalysts for possible high efficiency photocatalytic water splitting. A significant property of 2D Zr2CO2 and Hf2CO2 is that they exhibit unexpectedly high and directionally anisotropic carrier mobility, which may effectively facilitate the migration and separation of photogenerated electron–hole pairs. Meanwhile, these two MXenes also exhibit very good optical absorption performance in the wavelength ranging approximately from 300 to 500 nm. The stability of 2D Zr2CO2 and Hf2CO2 in liquid water is expected to be good based on ab initio molecular dynamics simulations. Finally, the adsorption and decomposition of water molecules on the 2D Zr2CO2 surface and the subsequent formation process of hydrogen were studied, which contributes to the unravelling of the micro-mechanism of photocatalytic hydrogen production on MXenes. Our findings will open a new way to facilitate the discovery and application of MXenes for photocatalytic water splitting.

Distributed robust finite-time nonlinear consensus protocols for multi-agent systems

Abstract: This paper investigates the robust finite-time consensus problem of multi-agent systems in networks with undirected topology. Global nonlinear consensus protocols augmented with a variable structure are constructed with the aid of Lyapunov functions for each single-integrator agent dynamics in the presence of external disturbances. In particular, it is shown that the finite settling time of the proposed general framework for robust consensus design is upper bounded for any initial condition. This makes it possible for network consensus problems to design and estimate the convergence time offline for a multi-agent team with a given undirected information flow. Finally, simulation results are presented to demonstrate the performance and effectiveness of our finite-time protocols.

Non-equilibrium processing leads to record high thermoelectric figure of merit in PbTe-SrTe.

Abstract: The broad-based implementation of thermoelectric materials in converting heat to electricity hinges on the achievement of high conversion efficiency. Here we demonstrate a thermoelectric figure of merit ZT of 2.5 at 923 K by the cumulative integration of several performance-enhancing concepts in a single material system. Using non-equilibrium processing we show that hole-doped samples of PbTe can be heavily alloyed with SrTe well beyond its thermodynamic solubility limit of <1 mol%. The much higher levels of Sr alloyed into the PbTe matrix widen the bandgap and create convergence of the two valence bands of PbTe, greatly boosting the power factors with maximal values over 30 μW cm(-1) K(-2). Exceeding the 5 mol% solubility limit leads to endotaxial SrTe nanostructures which produce extremely low lattice thermal conductivity of 0.5 W m(-1) K(-1) but preserve high hole mobilities because of the matrix/precipitate valence band alignment. The best composition is hole-doped PbTe-8%SrTe.

Antiproton Flux, Antiproton-to-Proton Flux Ratio, and Properties of Elementary Particle Fluxes in Primary Cosmic Rays Measured with the Alpha Magnetic Spectrometer on the International Space Station

Abstract: A precision measurement by AMS of the antiproton flux and the antiproton-to-proton flux ratio in primary cosmic rays in the absolute rigidity range from 1 to 450 GV is presented based on 3.49 × 105 antiproton events and 2.42 × 109 proton events. The fluxes and flux ratios of charged elementary particles in cosmic rays are also presented. In the absolute rigidity range ∼60 to ∼500 GV, the antiproton ¯p, proton p, and positron eþ fluxes are found to have nearly identical rigidity dependence and the electron e− flux exhibits a different rigidity dependence. Below 60 GV, the ( ¯ p=p), ( ¯ p=eþ), and (p=eþ) flux ratios each reaches a maximum. From ∼60 to ∼500 GV, the ( ¯ p=p), ( ¯ p=eþ), and (p=eþ) flux ratios show no rigidity dependence. These are new observations of the properties of elementary particles in the cosmos.

Strain engineering of graphene: a review

Abstract: Graphene has intrigued the science community by many unique properties not found in conventional materials. In particular, it is the strongest two-dimensional material ever measured, being able to sustain reversible tensile elastic strain larger than 20%, which yields an interesting possibility to tune the properties of graphene by strain and thus opens a new field called "straintronics". In this article, the current progress in the strain engineering of graphene is reviewed. We first summarize the strain effects on the electronic structure and Raman spectra of graphene. We then highlight the electron-phonon coupling greatly enhanced by the biaxial strain and the strong pseudomagnetic field induced by the non-uniform strain with specific distribution. Finally, the potential application of strain-engineering in the self-assembly of foreign atoms on the graphene surface is also discussed. Given the short history of graphene straintronics research, the current progress has been notable, and many further advances in this field are expected.

Caching at the wireless edge: design aspects, challenges, and future directions

Abstract: Caching at the wireless edge is a promising way to boost spectral efficiency and reduce energy consumption of wireless systems. These improvements are rooted in the fact that popular contents are reused, asynchronously, by many users. In this article we first introduce methods to predict the popularity distributions and user preferences, and the impact of erroneous information. We then discuss the two aspects of caching systems, content placement and delivery. We expound the key differences between wired and wireless caching, and outline the differences in the system arising from where the caching takes place (e.g., at base stations or on the wireless devices themselves). Special attention is paid to the essential limitations in wireless caching, and possible trade-offs between spectral efficiency, energy efficiency, and cache size.

Biodegradable triboelectric nanogenerator as a life-time designed implantable power source

Abstract: Transient electronics built with degradable organic and inorganic materials is an emerging area and has shown great potential for in vivo sensors and therapeutic devices. However, most of these devices require external power sources to function, which may limit their applications for in vivo cases. We report a biodegradable triboelectric nanogenerator (BD-TENG) for in vivo biomechanical energy harvesting, which can be degraded and resorbed in an animal body after completing its work cycle without any adverse long-term effects. Tunable electrical output capabilities and degradation features were achieved by fabricated BD-TENG using different materials. When applying BD-TENG to power two complementary micrograting electrodes, a DC-pulsed electrical field was generated, and the nerve cell growth was successfully orientated, showing its feasibility for neuron-repairing process. Our work demonstrates the potential of BD-TENG as a power source for transient medical devices.

Enabling UAV cellular with millimeter-wave communication: potentials and approaches

Abstract: To support high data rate urgent or ad hoc communications, we consider mmWave UAV cellular networks and the associated challenges and solutions. To enable fast beamforming training and tracking, we first investigate a hierarchical structure of beamforming codebooks and design of hierarchical codebooks with different beam widths via sub-array techniques. We next examine the Doppler effect as a result of UAV movement and find that the Doppler effect may not be catastrophic when high gain directional transmission is used. We further explore the use of mmWave spatial-division multiple access and demonstrate its clear advantage in improving the cellular network capacity. We also explore different ways of dealing with signal blockage and point out that possible adaptive UAV cruising algorithms would be necessary to counteract signal blockage. Finally, we identify a close relationship between UAV positioning and directional mmWave user discovery, where update of the former may directly impact the latter and vice versa.

Three-Bladed Rylene Propellers with Three-Dimensional Network Assembly for Organic Electronics.

Abstract: Two kinds of conjugated C3-symmetric perylene dyes, namely, triperylene hexaimides (TPH) and selenium-annulated triperylene hexaimides (TPH-Se), are efficiently synthesized. Both TPH and TPH-Se have broad and strong absorption in the region 300–600 nm together with suitable LUMO levels of about −3.8 eV. Single-crystal X-ray diffraction studies show that TPH displays an extremely twisted three-bladed propeller configuration and a unique 3D network assembly in which three PBI subunits in one TPH molecule have strong π–π intermolecular interactions with PBI subunits in neighboring molecules. The integration of selenophene to TPH endows TPH-Se with a more distorted propeller configuration and a more compact 3D network assembly due to the Se···O interactions. A single-crystal transistor confirms that both TPH and TPH-Se possess good electron-transport ability. TPH and TPH-Se acceptor-based solar cells show high power conversion efficiency of 8.28% and 9.28%, respectively, which mainly results from the combined...

Single-pixel three-dimensional imaging with time-based depth resolution

Abstract: A three-dimensional imaging system which distributes the optical illumination over the full field-of-view is sought after. Here, the authors demonstrate the capability of reconstructing 128 × 128 pixel resolution three-dimensional scenes to an accuracy of 3 mm as well as real-time video with a frame-rate up to 12 Hz.

Robust Anti-Icing Performance of a Flexible Superhydrophobic Surface

Abstract: A material with superhydrophobic and anti-ice/de-icing properties, which has a micro-/nanostructured surface, is produced by a straightforward method. This material comprises a poly(dimethylsiloxane) (PDMS) microstructure with ZnO nanohairs and shows excellent water and ice repellency even at low temperatures (-20 °C) and relatively high humidity (90%) for over three months. These results are expected to be helpful for designing smart, non-wetting materials that can be adapted to low-temperature environments for the development of anti-icing systems.

Porous CNTs/Co Composite Derived from Zeolitic Imidazolate Framework: A Lightweight, Ultrathin, and Highly Efficient Electromagnetic Wave Absorber

Abstract: Porous carbon nanotubes/cobalt nanoparticles (CNTs/Co) composite with dodecahedron morphology was synthesized by in situ pyrolysis of the Co-based zeolitic imidazolate framework in a reducing atmosphere. The morphology and microstructure of the composite can be well tuned by controlling the pyrolysis conditions. At lower pyrolysis temperature, the CNTs/Co composite is composed of well-dispersed Co nanoparticles and short CNT clusters with low graphitic degree. The increase of pyrolysis temperature/time promotes the growth and graphitization of CNTs and leads to the aggregation of Co nanoparticles. The optimized CNTs/Co composite exhibits strong dielectric and magnetic losses as well as a good impedance matching property. Interestingly, the CNTs/Co composite displays extremely strong electromagnetic wave absorption with a maximum reflection loss of −60.4 dB. More importantly, the matching thickness of the absorber is as thin as 1.81 mm, and the filler loading of composite in the matrix is only 20 wt %. The...

SnSe: a remarkable new thermoelectric material

Abstract: The deceptively simple material SnSe has surprised the scientific community by showing an unexpectedly low thermal conductivity and high power factor and it has become a very promising thermoelectric material. Both the electrical and thermal transport properties of SnSe are outstanding. It is remarkable that a binary compound exhibits strong anharmonic and anisotropic bonding, and after hole doping it shows an exceptionally high power factor because of a high electrical conductivity and a strongly enhanced Seebeck coefficient. The latter is enabled by the contribution of multiple electronic valence bands. In this perspective, we discuss the natural features of SnSe, including crystal structures, electronic band structures, and physical and chemical properties. We also compare the electrical transport properties of single crystals and polycrystalline SnSe. The thermal conductivities of polycrystalline samples show wide variation from laboratory to laboratory, with some values being higher than those of single crystals and some lower, which has caused confusion and controversy. To address the issues regarding the thermal transport properties of SnSe, we systematically summarize the reports for SnSe variants, discuss them along with some of our own new results, and offer possible explanations. Finally, some possible strategies are proposed toward future enhancements of the thermoelectric figure of merit of SnSe.

Fixed-Time Attitude Control for Rigid Spacecraft With Actuator Saturation and Faults

Abstract: This brief investigates the finite-time control problem associated with attitude stabilization of a rigid spacecraft subject to external disturbance, actuator faults, and input saturation. More specifically, a novel fixed-time sliding mode surface is developed, and the settling time of the defined surface is shown to be independent of the initial conditions of the system. Then, a finite-time controller is derived to guarantee that the closed-loop system is stable in the sense of the fixed-time concept. The actuator-magnitude constraints are rigorously enforced and the attitude of the rigid spacecraft converges to the equilibrium in a finite time even in the presence of external disturbances and actuator faults. Numerical simulations illustrate the spacecraft performance obtained using the proposed controller.

Attribution of Extreme Weather Events in the Context of Climate Change

Abstract: Extreme weather and climate-related events occur in a particular place, by definition, infrequently. It is therefore challenging to detect systematic changes in their occurrence given the relative shortness of observational records. However, there is a clear interest from outside the climate science community in the extent to which recent damaging extreme events can be linked to human-induced climate change or natural climate variability. Event attribution studies seek to determine to what extent anthropogenic climate change has altered the probability or magnitude of particular events. They have shown clear evidence for human influence having increased the probability of many extremely warm seasonal temperatures and reduced the probability of extremely cold seasonal temperatures in many parts of the world. The evidence for human influence on the probability of extreme precipitation events, droughts, and storms is more mixed. Although the science of event attribution has developed rapidly in recent years, geographical coverage of events remains patchy and based on the interests and capabilities of individual research groups. The development of operational event attribution would allow a more timely and methodical production of attribution assessments than currently obtained on an ad hoc basis. For event attribution assessments to be most useful, remaining scientific uncertainties need to be robustly assessed and the results clearly communicated. This requires the continuing development of methodologies to assess the reliability of event attribution results and further work to understand the potential utility of event attribution for stakeholder groups and decision makers.

Pyridinic-Nitrogen-Dominated Graphene Aerogels with Fe–N–C Coordination for Highly Efficient Oxygen Reduction Reaction

Abstract: Here, pyridinic nitrogen dominated graphene aerogels with/without iron incorporation (Fe-NG and NG) are prepared via a facile and effective process including freeze-drying of chemically reduced graphene oxide with/without iron precursor and thermal treatment in NH3. A high doping level of nitrogen has been achieved (up to 12.2 at% for NG and 11.3 at% for Fe-NG) with striking enrichment of pyridinic nitrogen (up to 90.4% of the total nitrogen content for NG, and 82.4% for Fe-NG). It is found that the Fe-NG catalysts display a more positive onset potential, higher current density, and better four-electron selectivity for ORR than their counterpart without iron incorporation. The most active Fe-NG exhibits outstanding ORR catalytic activity, high durability, and methanol tolerance ability that are comparable to or even superior to those of the commercial Pt/C catalyst at the same catalyst loading in alkaline environment. The excellent ORR performance can be ascribed to the synergistic effect of pyridinic N and Fe-N x sites (where iron probably coordinates with pyridinic N) that serve as active centers for ORR. Our Fe-NG can be developed into cost-effective and durable catalysts as viable replacements of the expensive Pt-based catalysts in practical fuel cell applications.

Cu 2 O/CuO Bilayered Composite as a High-Efficiency Photocathode for Photoelectrochemical Hydrogen Evolution Reaction

Abstract: Solar powered hydrogen evolution reaction (HER) is one of the key reactions in solar-to-chemical energy conversion. It is desirable to develop photocathodic materials that exhibit high activity toward photoelectrochemical (PEC) HER at more positive potentials because a higher potential means a lower overpotential for HER. In this work, the Cu2O/CuO bilayered composites were prepared by a facile method that involved an electrodeposition and a subsequent thermal oxidation. The resulting Cu2O/CuO bilayered composites exhibited a surprisingly high activity and good stability toward PEC HER, expecially at high potentials in alkaline solution. The photocurrent density for HER was 3.15 mA·cm−2 at the potential of 0.40 V vs. RHE, which was one of the two highest reported at the same potential on copper-oxide-based photocathode. The high photoactivity of the bilayered composite was ascribed to the following three advantages of the Cu2O/CuO heterojunction: (1) the broadened light absorption band that made more efficient use of solar energy, (2) the large space-charge-region potential that enabled a high efficiency for electron-hole separation, and (3) the high majority carrier density that ensured a faster charge transportation rate. This work reveals the potential of the Cu2O/CuO bilayered composite as a promising photocathodic material for solar water splitting.