Boston College

About: Boston College is a education organization based out in Boston, Massachusetts, United States. It is known for research contribution in the topics: Population & Poison control. The organization has 9749 authors who have published 25406 publications receiving 1105145 citations. The organization is also known as: BC.

Manipulation of ionized impurity scattering for achieving high thermoelectric performance in n-type Mg3Sb2-based materials.

Abstract: Achieving higher carrier mobility plays a pivotal role for obtaining potentially high thermoelectric performance. In principle, the carrier mobility is governed by the band structure as well as by the carrier scattering mechanism. Here, we demonstrate that by manipulating the carrier scattering mechanism in n-type Mg3Sb2-based materials, a substantial improvement in carrier mobility, and hence the power factor, can be achieved. In this work, Fe, Co, Hf, and Ta are doped on the Mg site of Mg3.2Sb1.5Bi0.49Te0.01, where the ionized impurity scattering crosses over to mixed ionized impurity and acoustic phonon scattering. A significant improvement in Hall mobility from ∼16 to ∼81 cm2⋅V-1⋅s-1 is obtained, thus leading to a notably enhanced power factor of ∼13 μW⋅cm-1⋅K-2 from ∼5 μW⋅cm-1⋅K-2 A simultaneous reduction in thermal conductivity is also achieved. Collectively, a figure of merit (ZT) of ∼1.7 is obtained at 773 K in Mg3.1Co0.1Sb1.5Bi0.49Te0.01 The concept of manipulating the carrier scattering mechanism to improve the mobility should also be applicable to other material systems.

On the origin of solar metric type II bursts

Abstract: The vast majority of solar flares are not associated with metric Type II radio bursts. For example, for the period February 1980–July 1982, corresponding to the first two and one-half years of the Solar Maximum Mission, 95% of the ∼2500 flares with peak >25 keV count rates >100 c s−1lacked associated Type II emission. Even the ∼360 largest flares, i.e., those having >25 keV peak count rates >1000 c s−1, had a Type II association rate of only 24%. The lack of a close correlation between flare size and Type II occurrence implies the need for a 'special condition' that distinguishes flares that are accompanied by metric Type II radio bursts from those of comparable size that are not. The leading candidates for this special condition are: (1) an unusually low Alfven speed in the flaring region; and (2) fast material motion. We present evidence based on SMM and GOES X-ray data and Solwind coronagraph data that argues against the first of these hypotheses and supports the second. Type II bursts linked to flares within 30° of the solar limb are well associated (64%; 49/76) with fast (>400 km s−1) coronal mass ejections (CMEs); for Type II flares within 15° of the limb, the association rate is 79% (30/38). An examination of the characteristics of 'non-CME' flares associated with Type IIs does not support the flare-initiated blast wave picture that has been proposed for these events and suggests instead that CMEs may have escaped detection. While the degree of Type II–CME association increases with flare size, there are notable cases of small Type II flares whose outstanding attribute is a fast CME. Thus we argue that metric Type II bursts (as well as the Moreton waves and kilometric Type II bursts that may accompany them) have their root cause in fast coronal mass ejections.

Household Debt and Income Inequality, 1963-2003

Abstract: I construct an economy with heterogeneous agents that mimics the time-series behavior of the earnings distribution in the United States from 1963 to 2003. Agents face aggregate and idiosyncratic shocks and accumulate real and financial assets. I estimate the shocks that drive the model using data on income inequality, aggregate income, and measures of financial liberalization. I show how the model economy can replicate two empirical facts: the trend and cyclical behavior of household debt and the diverging patterns in consumption and wealth inequality over time. While business cycle fluctuations can account for the short-run changes in household debt, its prolonged rise of the 1980s and the 1990s can be quantitatively explained only by the concurrent increase in income inequality.

The State of the Art in Azaborine Chemistry: New Synthetic Methods and Applications.

Abstract: Boron–nitrogen heteroarenes hold great promise for practical application in many areas of chemistry. Enduring interest in realizing this potential has in turn driven perennial innovation with respect to these compounds’ synthesis. This Perspective discusses in detail the most recent advances in methods pertaining to the preparation of BN-isosteres of benzene, naphthalene, and their derivatives. Additional focus is placed on the progress enabled by these syntheses toward functional utility of such BN-heterocycles in biochemistry and pharmacology, materials science, and transition-metal-based catalysis. The prospects for future research efforts in these and related fields are also assessed.