Showing papers by "Cooperative Research Centre published in 2008"

Colony-stimulating factors in inflammation and autoimmunity.

Abstract: Although they were originally defined as haematopoietic-cell growth factors, colony-stimulating factors (CSFs) have been shown to have additional functions by acting directly on mature myeloid cells. Recent data from animal models indicate that the depletion of CSFs has therapeutic benefit in many inflammatory and/or autoimmune conditions and as a result, early-phase clinical trials targeting granulocyte/macrophage colony-stimulating factor and macrophage colony-stimulating factor have now commenced. The distinct biological features of CSFs offer opportunities for specific targeting, but with some associated risks. Here, I describe these biological features, discuss the probable specific outcomes of targeting CSFs in vivo and highlight outstanding questions that need to be addressed.

Improved estimates of upper-ocean warming and multi-decadal sea-level rise

Abstract: Changes in the climate system's energy budget are predominantly revealed in ocean temperatures and the associated thermal expansion contribution to sea-level rise. Climate models, however, do not reproduce the large decadal variability in globally averaged ocean heat content inferred from the sparse observational database, even when volcanic and other variable climate forcings are included. The sum of the observed contributions has also not adequately explained the overall multi-decadal rise. Here we report improved estimates of near-global ocean heat content and thermal expansion for the upper 300 m and 700 m of the ocean for 1950-2003, using statistical techniques that allow for sparse data coverage and applying recent corrections to reduce systematic biases in the most common ocean temperature observations. Our ocean warming and thermal expansion trends for 1961-2003 are about 50 per cent larger than earlier estimates but about 40 per cent smaller for 1993-2003, which is consistent with the recognition that previously estimated rates for the 1990s had a positive bias as a result of instrumental errors. On average, the decadal variability of the climate models with volcanic forcing now agrees approximately with the observations, but the modelled multi-decadal trends are smaller than observed. We add our observational estimate of upper-ocean thermal expansion to other contributions to sea-level rise and find that the sum of contributions from 1961 to 2003 is about 1.5 +/- 0.4 mm yr(-1), in good agreement with our updated estimate of near-global mean sea-level rise (using techniques established in earlier studies) of 1.6 +/- 0.2 mm yr(-1).

The response of the Antarctic Circumpolar Current to recent climate change

Abstract: Observations show a significant intensification of the Southern Hemisphere westerlies, the prevailing winds between the latitudes of 30° and 60° S, over the past decades. A continuation of this intensification trend is projected by climate scenarios for the twenty-first century. The response of the Antarctic Circumpolar Current and the carbon sink in the Southern Ocean to changes in wind stress and surface buoyancy fluxes is under debate. Here we analyse the Argo network of profiling floats and historical oceanographic data to detect coherent hemispheric-scale warming and freshening trends that extend to depths of more than 1,000 m. The warming and freshening is partly related to changes in the properties of the water masses that make up the Antarctic Circumpolar Current, which are consistent with the anthropogenic changes in heat and freshwater fluxes suggested by climate models. However, we detect no increase in the tilt of the surfaces of equal density across the Antarctic Circumpolar Current, in contrast to coarse-resolution model studies. Our results imply that the transport in the Antarctic Circumpolar Current and meridional overturning in the Southern Ocean are insensitive to decadal changes in wind stress.

Macroinvertebrate diversity in headwater streams: a review

Abstract: Summary 1. Headwater streams are ubiquitous in the landscape and are important sources of water, sediments and biota for downstream reaches. They are critical sites for organic matter processing and nutrient cycling, and may be vital for maintaining the ‘health’ of whole river networks. 2. Macroinvertebrates are an important component of biodiversity in stream ecosystems and studies of macroinvertebrate diversity in headwater streams have mostly viewed stream systems as linear reaches rather than as networks, although the latter may be more appropriate to the study of diversity patterns in headwater systems. 3. Studies of macroinvertebrate diversity in headwater streams from around the world illustrated that taxonomic richness is highly variable among continents and regions, and studies addressing longitudinal changes in taxonomic richness of macroinvertebrates generally found highest richness in mid-order streams. 4. When stream systems are viewed as networks at the landscape-scale, α-diversity may be low in individual headwater streams but high β-diversity among headwater streams within catchments and among catchments may generate high γ-diversity. 5. Differing ability and opportunity for dispersal of macroinvertebrates, great physical habitat heterogeneity in headwater streams, and a wide range in local environmental conditions may all contribute to high β-diversity among headwater streams both within and among catchments. 6. Moving beyond linear conceptual models of stream ecosystems to consider the role that spatial structure of river networks might play in determining diversity patterns at the landscape scale is a promising avenue for future research.

Wind speed climatology and trends for Australia, 1975-2006: Capturing the stilling phenomenon and comparison with near-surface reanalysis output

Abstract: [1] Near-surface wind speeds (u) measured by terrestrial anemometers show declines (a ‘stilling’) at a range of midlatitude sites, but two gridded u datasets (a NCEP/NCAR reanalysis output and a surface-pressure-based u model) have not reproduced the stilling observed at Australian stations. We developed Australia-wide 0.01 resolution daily u grids by interpolating measurements from an expanded anemometer network for 1975–2006. These new grids represented the magnitude and spatialvariability of observed u trends, whereas grids from reanalysis systems (NCEP/NCAR, NCEP/DOE and ERA40) essentially did not, even when minimising the sea-breeze impact. For these new grids, the Australianaveraged u trend for 1975–2006 was 0.009 m s 1 a 1 (agreeing with earlier site-based studies) with stilling over 88% of the land-surface. This new dataset can be used in numerous environmental applications, including benchmarking general circulation models to improve the representation of key parameters that govern u estimation. The methodology implemented here can be applied globally. Citation: McVicar, T. R., T. G. Van Niel, L. T. Li, M. L. Roderick, D. P. Rayner, L. Ricciardulli, and R. J. Donohue (2008), Wind speed climatology and trends for Australia, 1975 – 2006: Capturing the stilling phenomenon and comparison with near-surface reanalysis output, Geophys. Res. Lett., 35, L20403,

Capture of CO2 from high humidity flue gas by vacuum swing adsorption with zeolite 13X

Abstract: Capture of CO2 from flue gas streams using adsorption processes must deal with the prospect of high humidity streams containing bulk CO2 as well as other impurities such as SOx, NOx, etc. Most studies to date have ignored this aspect of CO2 capture. In this study, we have experimentally examined the capture of CO2 from a 12% synthetic flue gas stream at a relative humidity of 95% at 30 °C. A 13X adsorbent was used and the migration of the water and its subsequent impact on capture performance was evaluated. Binary breakthrough of CO2/water vapor was performed and indicated a significant effect of water on CO2 adsorption capacity, as expected. Cyclic experiments indicate that the water zone migrates a quarter of the way into the column and stabilizes its position so that CO2 capture is still possible although decreased. The formation of a water zone creates a “cold spot” which has implications for the system performance. The recovery of CO2 dropped from 78.5% to 60% when moving from dry to wet flue gas while the productivity dropped by 22%. Although the concentration of water leaving the bed under vacuum was 27%(vol), the low vacuum pressure prevented condensation of water in this stream. However, the vacuum pump acted as a condenser and separator to remove bulk water. An important consequence of the presence of a water zone was to elevate the vacuum level thereby reducing CO2 working capacity. Thus although there is a detrimental effect of water on CO2 capture, long term recovery of CO2 is still possible in a single VSA process. Pre-drying of the flue gas steam is not required. However, careful consideration of the impact of water and accommodation thereof must be made particularly when the feed stream temperature increases resulting in higher feed water concentration.

Enamel subsurface lesion remineralisation with casein phosphopeptide stabilised solutions of calcium, phosphate and fluoride.

Abstract: Casein phosphopeptide stabilised amorphous calcium phosphate (CPP-ACP) and amorphous calcium fluoride phosphate (CPP-ACFP) solutions have been shown to remineralise enamel subsurface lesions. The aim

Understanding global sea levels: past, present and future

Abstract: The coastal zone has changed profoundly during the 20th century and, as a result, society is becoming increasingly vulnerable to the impact of sea-level rise and variability. This demands improved understanding to facilitate appropriate planning to minimise potential losses. With this in mind, the World Climate Research Programme organised a workshop (held in June 2006) to document current understanding and to identify research and observations required to reduce current uncertainties associated with sea-level rise and variability. While sea levels have varied by over 120 m during glacial/interglacial cycles, there has been little net rise over the past several millennia until the 19th century and early 20th century, when geological and tide-gauge data indicate an increase in the rate of sea-level rise. Recent satellite-altimeter data and tide-gauge data have indicated that sea levels are now rising at over 3 mm year−1. The major contributions to 20th and 21st century sea-level rise are thought to be a result of ocean thermal expansion and the melting of glaciers and ice caps. Ice sheets are thought to have been a minor contributor to 20th century sea-level rise, but are potentially the largest contributor in the longer term. Sea levels are currently rising at the upper limit of the projections of the Third Assessment Report of the Intergovernmental Panel on Climate Change (TAR IPCC), and there is increasing concern of potentially large ice-sheet contributions during the 21st century and beyond, particularly if greenhouse gas emissions continue unabated. A suite of ongoing satellite and in situ observational activities need to be sustained and new activities supported. To the extent that we are able to sustain these observations, research programmes utilising the resulting data should be able to significantly improve our understanding and narrow projections of future sea-level rise and variability.

Salinity and sodicity effects on respiration and microbial biomass of soil

Abstract: An understanding of the effects of salinity and sodicity on soil carbon (C) stocks and fluxes is critical in environmental management, as the areal extents of salinity and sodicity are predicted to increase. The effects of salinity and sodicity on the soil microbial biomass (SMB) and soil respiration were assessed over 12weeks under controlled conditions by subjecting disturbed soil samples from a vegetated soil profile to leaching with one of six salt solutions; a combination of low-salinity (0.5dSm−1), mid-salinity (10dSm−1), or high-salinity (30dSm−1), with either low-sodicity (sodium adsorption ratio, SAR, 1), or high-sodicity (SAR 30) to give six treatments: control (low-salinity low-sodicity); low-salinity high-sodicity; mid-salinity low-sodicity; mid-salinity high-sodicity; high-salinity low-sodicity; and high-salinity high-sodicity. Soil respiration rate was highest (56–80mg CO2-C kg−1 soil) in the low-salinity treatments and lowest (1–5mg CO2-C kg−1 soil) in the mid-salinity treatments, while the SMB was highest in the high-salinity treatments (459–565mg kg−1 soil) and lowest in the low-salinity treatments (158–172mg kg−1 soil). This was attributed to increased substrate availability with high salt concentrations through either increased dispersion of soil aggregates or dissolution or hydrolysis of soil organic matter, which may offset some of the stresses placed on the microbial population from high salt concentrations. The apparent disparity in trends in respiration and the SMB may be due to an induced shift in the microbial population, from one dominated by more active microorganisms to one dominated by less active microorganisms.

Changing Expendable Bathythermograph Fall Rates and Their Impact on Estimates of Thermosteric Sea Level Rise

Abstract: A time-varying warm bias in the global XBT data archive is demonstrated to be largely due to changes in the fall rate of XBT probes likely associated with small manufacturing changes at the factory. Deep-reaching XBTs have a different fall rate history than shallow XBTs. Fall rates were fastest in the early 1970s, reached a minimum between 1975 and 1985, reached another maximum in the late 1980s and early 1990s, and have been declining since. Field XBT/CTD intercomparisons and a pseudoprofile technique based on satellite altimetry largely confirm this time history. A global correction is presented and applied to estimates of the thermosteric component of sea level rise. The XBT fall rate minimum from 1975 to 1985 appears as a 10-yr “warm period” in the global ocean in thermosteric sea level and heat content estimates using uncorrected data. Upon correction, the thermosteric sea level curve has reduced decadal variability and a larger, steadier long-term trend.

Cyanobacterial poisoning in livestock, wild mammals and birds--an overview.

Abstract: Poisoning of livestock by toxic cyanobacteria was first reported in the 19th century, and throughout the 20th century cyanobacteria–related poisonings of livestock and wildlife in all continents have been described. Some mass mortality events involving unrelated fauna in prehistoric times have also been attributed to cyanotoxin poisoning; if correct, this serves as a reminder that toxic cyanobacteria blooms predate anthropogenic manipulation of the environment, though there is probably general agreement that human intervention has led to increases in the frequency and extent of cyanobacteria blooms. Many of the early reports of cyanobacteria poisoning were anecdotal and circumstantial, albeit with good descriptions of the appearance and behaviour of cyanobacteria blooms that preceded or coincided with illness and death in exposed animals. Early necropsy findings of hepatotoxicity were subsequently confirmed by experimental investigations. More recent reports supplement clinical and post–mortem findings with investigative chemistry techniques to identify cyanotoxins in stomach contents and tissue fluids.

Differential MHC class II synthesis and ubiquitination confers distinct antigen-presenting properties on conventional and plasmacytoid dendritic cells

Abstract: The importance of conventional dendritic cells (cDCs) in the processing and presentation of antigen is well established, but the contribution of plasmacytoid dendritic cells (pDCs) to these processes, and hence to T cell immunity, remains unclear. Here we showed that unlike cDCs, pDCs continued to synthesize major histocompatibility complex (MHC) class II molecules and the MHC class II ubiquitin ligase MARCH1 long after activation. Sustained MHC class II-peptide complex formation, ubiquitination and turnover rendered pDCs inefficient in the presentation of exogenous antigens but enabled pDCs to continuously present endogenous viral antigens in their activated state. As the antigen-presenting abilities of cDCs and pDCs are fundamentally distinct, these two cell types may activate largely nonoverlapping repertoires of CD4(+) T cells.

Evidence of Henipavirus Infection in West African Fruit Bats

Abstract: Henipaviruses are emerging RNA viruses of fruit bat origin that can cause fatal encephalitis in man. Ghanaian fruit bats (megachiroptera) were tested for antibodies to henipaviruses. Using a Luminex multiplexed microsphere assay, antibodies were detected in sera of Eidolon helvum to both Nipah (39%, 95% confidence interval: 27–51%) and Hendra (22%, 95% CI: 11–33%) viruses. Virus neutralization tests further confirmed seropositivity for 30% (7/23) of Luminex positive serum samples. Our results indicate that henipavirus is present within West Africa.

Capture of CO2 from flue gas streams with zeolite 13X by vacuum-pressure swing adsorption

Abstract: Vacuum swing adsorption (VSA) capture of CO2 from flue gas streams is a promising technology for greenhouse gas mitigation. In this study we use a detailed, validated numerical model of the CO2VSA process to study the effect of a range of operating and design parameters on the system performance. The adsorbent used is 13X and a feed stream of 12% CO2 and dry air is used to mimic flue gas. Feed pressures of 1.2 bar are used to minimize flue gas compression. A 9-step cycle with two equalisations and a 12-step cycle including product purge were both used to understand the impact of several cycle changes on performance. The ultimate vacuum level used is one of the most important parameters in dictating CO2 purity, recovery and power consumption. For vacuum levels of 4 kPa and lower, CO2 purities of >90% are achievable with a recovery of greater than 70%. Both purity and recovery drop quickly as the vacuum level is raised to 10 kPa. Total power consumption decreases as the vacuum pressure is raised, as expected, but the recovery decreases even quicker leading to a net increase in the specific power. The specific power appears to minimize at a vacuum pressure of approximately 4 kPa for the operating conditions used in our study. In addition to the ultimate vacuum level, vacuum time and feed time are found to impact the results for differing reasons. Longer evacuation times (to the same pressure level) imply lower flow rates and less pressure drop providing improved performance. Longer feed times led to partial breakthrough of the CO2 front and reduced recovery but improved purity. The starting pressure of evacuation (which is not necessarily equal to the feed pressure) was also found to be important since the gas phase was enriched in CO2 prior to removal by vacuum leading to improved CO2 purity. A 12-step cycle including product purge was able to produce high purity CO2 (>95%) with minimal impact on recovery. Finally, it was found that for 13X, the optimal feed temperature was around 67°C to maximize system purity. This is a consequence of the temperature dependence of the working selectivity and working capacity of 13X. In summary, our numerical model indicates that there is considerable scope for improvement and use of the VSA process for CO2 capture from flue gas streams.

A novel cationic‐peptide coating for the prevention of microbial colonization on contact lenses

Abstract: Aims To develop an antimicrobial peptide with broad spectrum activity against bacteria implicated in biomaterial infection of low toxicity to mammalian cells and retaining its antimicrobial activity when covalently bound to a biomaterial surface. Methods and results A synthetic peptide (melimine) was produced by combining portions of the antimicrobial cationic peptides mellitin and protamine. In contrast to the parent peptide melittin which lysed sheep red blood cells at >10 microg ml(-1), melimine lysed sheep red blood cells only at concentrations >2500 microg ml(-1), well above bactericidal concentrations. Additionally, melimine was found to be stable to heat sterilization. Evaluation by electron microscopy showed that exposure of both Pseudomonas aeruginosa and Staphylococcus aureus to melimine at the minimal inhibitory concentration (MIC) produced changes in the structure of the bacterial membranes. Further, repeated passage of these bacteria in sub-MIC concentrations of melimine did not result in an increase in the MIC. Melimine was tested for its ability to reduce bacterial adhesion to contact lenses when adsorbed or covalently attached. Approximately 80% reduction in viable bacteria was seen against both P. aeruginosa and S. aureus for 500 microg per lens adsorbed melimine. Covalently linked melimine (18 +/- 4 microg per lens) showed >70% reduction of these bacteria to the lens. Conclusions We have designed and tested a synthetic peptide melimine incorporating active regions of protamine and mellitin which may represent a good candidate for development as an antimicrobial coating for biomaterials. Significance and impact of the study Infection associated with the use of biomaterials remains a major barrier to the long-term use of medical devices. The antimicrobial peptide melimine is an excellent candidate for development as an antimicrobial coating for such devices.

Using remote sensing to predict grape phenolics and colour at harvest in a Cabernet Sauvignon vineyard: Timing observations against vine phenology and optimising image resolution

Abstract: Optical remote sensing can provide a synoptic view of grapevine photosynthetically-active biomass over entire vineyards both rapidly and cost-effectively. Such output offers viticulturists and winemakers a management tool of enormous potential with red grape varieties, especially if canopy architecture (defined in this way) can be linked to production of phenolics and colour in ripe grapes. Accordingly, this paper describes such associations for a Cabernet Sauvignon vineyard in Australia's cool-climate Coonawarra region. A link is established between physical descriptors of grapevine canopies (derived from remotely-sensed images), and subsequent measurements of grape phenolics and colour. High-resolution images were acquired on three occasions during each of two consecutive growing seasons and post-processed to a range of on-ground resolutions. The strength of correlation between those images and berry properties (both total phenolics, and colour levels at harvest), varied according to spatial resolution and vine phenology at the time of imaging. An image resolution corresponding approximately to row spacing resulted in the strongest correlations between berry constituents and image-based data on all occasions. Referenced to grapevine phenology, correlations were initially weak (insignificant) at bud-burst, reached maximum strength at veraison, then diminished somewhat as grapes ripened. Prospects for applying such remotely-sensed imagery (at an appropriate resolution and timing), to predict berry phenolics and colour at harvest, are discussed.

The Anticariogenic Effect of Sugar-Free Gum Containing CPP-ACP Nanocomplexes on Approximal Caries Determined Using Digital Bitewing Radiography

Abstract: This study investigated, using digital bitewing radiography, the progression and regression of approximal caries in adolescent subjects chewing a sugar-free gum containing 54 mg CPP-ACP relative to th

Bimodal Distribution of Gold in Pyrite and Arsenopyrite: Examples from the Archean Boorara and Bardoc Shear Systems, Yilgarn Craton, Western Australia

Abstract: This study investigates the microstructures, geochemistry, and hydrothermal evolution of gold-bearing pyrite and arsenopyrite from six orogenic gold deposits in the Archean Eastern Goldfields Province, Western Australia. Scanning electron microscope (SEM), electron microprobe (EMP) and laser ablation-inductively coupled plasma-mass spectroscopy (LA-ICP-MS) analyses show that the gold-bearing minerals possess a number of similar textural features, including the occurrence of invisible gold within initial phases of growth, and later-stage visible gold associated with alteration rims. The alteration rims are characterized by a higher-than-average atomic mass (mainly owing to arsenic enrichment) and are preferentially located along fractures and grain boundaries in the pyrite and arsenopyrite. These observations suggest that visible gold formation is associated with hydrothermal alteration of preexisting pyrite and arsenopyrite. Textural observations and LA-ICP-MS data suggest that some invisible gold was remobilized from early-formed pyrite and arsenopyrite to form visible gold during development of these alteration rims. Gold may also have been added by hydrothermal fluids during a later stage of mineralization. In situ geochemistry and phase relationships of alteration rims are used to further constrain the hydrothermal process responsible for formation of alteration rims and visible gold in fractures. Based on sulfide stability relations, our data indicate that development of arsenopyrite alteration rims associated with late-stage visible gold formation was related to an increase in temperature (maximum increase from 310° to 415°C) and up to of sic orders of magnitude increase in sulfur fugacity, whereas changes in oxygen fugacity were less important. LA-ICP-MS analyses show that the relative and absolute variations in selected trace element (Au, Ag, Sb, Bi, Ba, Te, Pb, Co, and Mo) concentrations can also be used to distinguish between unaltered and altered pyrite and arsenopyrite. In general, trace elements within pyrite and arsenopyrite have a relatively uniform distribution, whereas later-stage alteration rims have more variable trace element distributions. Although the observed textures are typical of prograde metamorphic coronae, we suggest that they are the consequence of variations in fluid conditions and chemistry, and that mineralization occurred in response to syn- and/or postpeak metamorphic fluid infiltration.

Phenolic Metabolites in Leaves of the Invasive Shrub, Lonicera maackii, and Their Potential Phytotoxic and Anti-Herbivore Effects

Abstract: Lonicera maackii is an invasive shrub in North America for which allelopathic effects toward other plants or herbivores have been suspected. We characterized the major phenolic metabolites present in methanol extracts of L. maackii leaves. In addition, we examined the effects of methanol–water extracts of L. maackii leaves on seed germination of a target plant species and on feeding preference and growth rate of a generalist insect herbivore. A total of 13 individual major and minor compounds were detected in crude leaf extracts by high-performance liquid chromatography coupled to electronspray ionization-tandem mass spectrometry (ESI-MS/MS). Extracts were dominated by two major flavones, apigenin and luteolin, and their glucoside derivatives, apigenin-7-glucoside and luteolin-7-glucoside. Quantities of these compounds, along with chlorogenic acid, varied between two sampling points. Leaf extracts that contained these compounds were inhibitory to seed germination of Arabidopsis thaliana. In addition, treatment of artificial diet with leaf extracts deterred feeding of the generalist herbivore, Spodoptera exigua, in choice experiments but had no effect on growth rate in short-term no-choice bioassays. Purified apigenin tended to deter feeding by S. exigua and inhibited seed germination of A. thaliana. We conclude that leaves of L. maackii contain phenolic compounds, including apigenin and chlorogenic acid, capable of having biological effects on other plants and insects.

Big fires and their ecological impacts in Australian savannas: size and frequency matters

Abstract: Savannas are the most fire-prone of the earth’s major biomes. The availability of various broad-scale satellite-derived fire mapping and regional datasets provides a framework with which to examine the seasonality, extent and implications of large fires with particular reference to biodiversity values in the tropical savannas of northern Australia. We document the significance of savanna fires in the fire-prone ‘Top End’ region of the Northern Territory, Australia, using 9 years (1997–2005) of National Oceanic and Atmospheric Administration (NOAA)-Advanced Very High Resolution Radiometer (AVHRR)-, Landsat Thematic Mapper (TM)- and Enhanced Thematic Mapper (ETM+)-derived fire mapping. Fire (patch) sizes from both AVHRR- and Landsat-scale mapping increased through the calendar year associated with progressive curing of grass and litter fuels. Fire frequency data at both satellite sensor scales indicate that regional fire regimes in higher rainfall regions are dominated by large (>1000 km2) fires occurring typically at short (~2–3 years) fire return intervals. In discussion, we consider the ecological implications of these patch size distributions on regional fire-sensitive biota. Collectively, assembled data illustrate that many northern Australian savanna flora, fauna and habitats embedded within the savanna matrix are vulnerable to extensive and frequent fires, especially longer-lived obligate seeder plant taxa and relatively immobile vertebrate fauna with small home ranges.

Copper fungicide residues in Australian vineyard soils.

Abstract: Copper (Cu) concentrations were measured in Australian vineyard soils to assess the extent and magnitude of Cu accumulation resulting from the use of Cu-based fungicides and to indicate the likely risks to long-term soil fertility. Soil samples were collected from 98 vineyards across 10 grape-growing regions of Australia and analyzed for total Cu concentrations. Ninety-six percent of vineyards surveyed had elevated Cu concentrations in soil compared to the background Cu concentrations in nearby soil in its native state. Concentrations of total B, Co, Cr, Pb, and Zn were similar to background concentrations and below reported toxicity guideline values. Cu concentrations in Australian vineyard soils were generally much lower (6-150 mg kg-1) than those reported in the soils of vineyards in parts of Europe (i.e., 130-1280 mg kg-1). Concentrations of total Cu were generally below those concentrations reported to cause lethal effects to soil invertebrates; however, Cu exceeded concentrations known to cause sublethal effects (i.e., inhibit growth, affect reproduction, induce avoidance behavior) to those (or related) invertebrates.

Large fires, fire effects and the fire-regime concept

Abstract: ‘Large’ fires may be declared so because of their absolute or relative area. Huge fires – with areas of more than 106 ha (104 km2) have occurred across a wide spectrum of Australian environments and are known on other continents. Such large fires are rare whereas fires with much smaller areas are common. Large fires are initiated by single or multiple ignitions and become large because of some combination of: rapid rates of spread; long ‘life’; merging, and failure of initial suppression operations. Fires as ecological ‘events’ occur within a ‘regime’ – an historical series. Both events and regimes have effects that may be discerned in terms of water, land, air or organisms. What have been regarded as the components of ‘regimes’ have differed between observers, the main issue being whether or not spatial variables need to be included; ‘area’ involvement is briefly addressed. The current trend toward fire-regime control through fuel treatment, including management (prescribed) burning, and fire suppression may be expected to continue. These trends, among others, can be expected to change fire regimes. What is regarded as ‘large’ among fires may change as the planet becomes increasingly human-dominated.

Acid-Degradable Core-Crosslinked Micelles Prepared from Thermosensitive Glycopolymers Synthesized via RAFT Polymerization

Abstract: A thermoresponsive block copolymer, namely poly(acryloyl glucosamine)-block-poly(N-isopropylacryamide) (PAGA(180)-b-PNIPAAM(350))was simultaneously self-assembled and cross-linked in aqueous medium via RAFT polymerization at 60 degrees C to afford core-crosslinked micelles exhibiting a glycopolymer corona and a PNIPAAM stimuli-responsive core. An acid-labile crosslinking agent, 3,9-divinyl-2,4,8,10-tetraoxaspiro[5.5]-undecane, was employed to generate thermosensitive and acid-degradable core-shell nanoparticles. Stable against crosslinked micelles readily hydrolyzed block copolymers at lower pH (30 min and 12 h respectively pH = 2 and 4).

Formation and export of dense shelf water from the Adélie Depression, East Antarctica

Abstract: [1] Coastal polynyas in the Adelie Depression are an important source of Antarctic Bottom Water to the Australian-Antarctic Basin. We present time series (April 1998 to May 1999 and August 1999 to February 2000) of data from temperature-salinity sensors, in both the Adelie Depression and the known outflow region of the Adelie Sill, to describe the annual cycle of shelf water densities. From April through September, salinification beneath the polynya produces dense shelf waters. During September–October, shelf water densities in the depression peak at 27.94 kg m−3, and the cooling and freshening signature of Ice Shelf Water is observed north of Buchanan Bay. In November–December, shelf water densities decrease as intrusions of warm and relatively fresh modified Circumpolar Deep Water enter east of the Adelie Sill. From January–March the surface layer is conditioned by the cooling of the atmosphere, which overturns the upper water column. At the Adelie Sill, observed daily mean currents were approximately 10 cm s−1 with intense instantaneous currents greater than 50 cm s−1 at the sill depth. Using an idealized outflow region with a rectangular cross-sectional area (6 × 106 m2), we present the first estimates of shelf water export by potential density class. Assuming shelf water with a minimum density of 27.88 kg m−3 has sufficient negative buoyancy for downslope mixing and a fourfold volume increase (1:3 mixing ratio) from entrainment, the dense shelf water export of 0.1–0.5 Sv results in an annual average production of bottom water in this region of between 0.4 and 2.0 Sv. The wide range in bottom water estimate results from data limitations, and a narrowing of this range requires further mooring observations.

Cycle development and design for CO2 capture from flue gas by vacuum swing adsorption

Abstract: CO2 capture and storage is an important component in the development of clean power generation processes One CO2 capture technology is gas-phase adsorption, specifically pressure (or vacuum) swing adsorption The complexity of these processes makes evaluation and assessment of new adsorbents difficult and time-consuming In this study, we have developed a simple model specifically targeted at CO2 capture by pressure swing adsorption and validated our model by comparison with data from a fully instrumented pilot-scale pressure swing adsorption process The model captures nonisothermal effects as well as nonlinear adsorption and nitrogen coadsorption Using the model and our apparatus, we have designed and studied a large number of cycles for CO2 capture We demonstrate that by careful management of adsorption fronts and assembly of cycles based on understanding of the roles of individual steps, we are able to quickly assess the effect of adsorbents and process parameters on capture performance and identify optimal operating regimes and cycles We recommend this approach in contrast to exhaustive parametric studies which tend to depend on specifics of the chosen cycle and adsorbent We show that appropriate combinations of process steps can yield excellent process performance and demonstrate how the pressure drop, and heat loss, etc affect process performance through their effect on adsorption fronts and profiles Finally, cyclic temperature profiles along the adsorption column can be readily used to infer concentration profiles-this has proved to be a very useful tool in cyclic function definition Our research reveals excellent promise for the application of pressure/vacuum swing adsorption technology in the arena of CO2 capture from flue gases