Dalian University of Technology

About: Dalian University of Technology is a education organization based out in Dalian, China. It is known for research contribution in the topics: Catalysis & Finite element method. The organization has 60890 authors who have published 71921 publications receiving 1188356 citations. The organization is also known as: Dàlián Lǐgōng Dàxué.

Hollow Iron–Vanadium Composite Spheres: A Highly Efficient Iron‐Based Water Oxidation Electrocatalyst without the Need for Nickel or Cobalt

Abstract: Noble-metal-free bimetal-based electrocatalysts have shown high efficiency for water oxidation. Ni and/or Co in these electrocatalysts are essential to provide a conductive, high-surface area and a chemically stable host. However, the necessity of Ni or Co limits the scope of low-cost electrocatalysts. Herein, we report a hierarchical hollow FeV composite, which is Ni- and Co-free and highly efficient for electrocatalytic water oxidation with low overpotential 390 mV (10 mA cm−2 catalytic current density), low Tafel slope of 36.7 mV dec−1, and a considerable durability. This work provides a novel and efficient catalyst, and greatly expands the scope of low-cost Fe-based electrocatalysts for water splitting without need of Ni or Co.

Design of multimaterial compliant mechanisms using level-set methods

Abstract: A monolithic compliant mechanism transmits applied forces from specified input ports to output ports by elastic deformation of its comprising materials, fulfilling required functions analogous to a rigid-body mechanism. In this paper, we propose a level-set method for designing monolithic compliant mechanisms made of multiple materials as an optimization of continuum heterogeneous structures. Central to the method is a multiphase level-set model that precisely specifies the distinct material regions and their sharp interfaces as well as the geometric boundary of the structure. Combined with the classical shape derivatives, the level-set method yields an Eulerian computational system of geometric partial differential equations, capable of performing topological changes and capturing geometric evolutions at the interface and the boundary. The proposed method is demonstrated for single-input and single-output mechanisms and illustrated with several two-dimensional examples of synthetics of multimaterial mechanisms of force inverters and gripping and clamping devices. An analysis on the formation of de facto hinges is presented based on the shape gradient information. A scheme to ensure a well-connected topology of the mechanism during the process of optimization is also presented.

Compressible Carbon Nanotube–Graphene Hybrid Aerogels with Superhydrophobicity and Superoleophilicity for Oil Sorption

Abstract: Spilled oil represents a menace to the aquatic ecosystem and the whole environment in general and requires timely cleanup. Among all the avaliable technologies, oil sorption has attracted the most attention because of its simplicity and high level of effectiveness. The key for the development of this technology is convenient fabrication of high-performance oil sorbents that can be used repeatedly. In this work, a fast microwave irradiation-mediated approach has been proposed for manufacturing multiwall carbon nanotube (MWCNT)–graphene hybrid aerogels, in which MWCNTs are vertically anchored on the surface of cell walls of graphene aerogels. The hybrid monoliths show superhydrophobicity and superoleophilicity, a large pore volume, a large pore size, and excellent compressibility, demonstrating outstanding performance for recyclable oil sorption.