Dalian University of Technology

About: Dalian University of Technology is a education organization based out in Dalian, China. It is known for research contribution in the topics: Catalysis & Finite element method. The organization has 60890 authors who have published 71921 publications receiving 1188356 citations. The organization is also known as: Dàlián Lǐgōng Dàxué.

A Riccati-Bernoulli sub-ODE method for nonlinear partial differential equations and its application

Abstract: The Riccati-Bernoulli sub-ODE method is firstly proposed to construct exact traveling wave solutions, solitary wave solutions, and peaked wave solutions for nonlinear partial differential equations. A Backlund transformation of the Riccati-Bernoulli equation is given. By using a traveling wave transformation and the Riccati-Bernoulli equation, nonlinear partial differential equations can be converted into a set of algebraic equations. Exact solutions of nonlinear partial differential equations can be obtained by solving a set of algebraic equations. By applying the Riccati-Bernoulli sub-ODE method to the Eckhaus equation, the nonlinear fractional Klein-Gordon equation, the generalized Ostrovsky equation, and the generalized Zakharov-Kuznetsov-Burgers equation, traveling solutions, solitary wave solutions, and peaked wave solutions are obtained directly. Applying a Backlund transformation of the Riccati-Bernoulli equation, an infinite sequence of solutions of the above equations is obtained. The proposed method provides a powerful and simple mathematical tool for solving some nonlinear partial differential equations in mathematical physics.

Formaldehyde sensing properties of electrospun NiO-doped SnO2 nanofibers

Abstract: Formaldehyde is a kind of hazardous gases dangerous to human health. Hence, gas sensor is an essential device to monitor formaldehyde in air, especially in indoor ambient. Semiconductor metal oxides are studied as gas-sensing material to detect most of key gases for decade years. For the purpose of actual application and meeting a variety of conditions, diverse additives added into host material are expected to improve the performance of gas sensors. The formaldehyde gas-sensing characteristics of undoped and NiO-doped SnO 2 (NSO) nanofibers synthesized via a simple electrospinning method were investigated in this study. It is noticed that the addition of NiO causes the distortion at the surface of SnO 2 nanofibers, which is responsible to adjust activation energy, grain sizes and chemical states of host material. The sensors fabricated from NSO nanofibers exhibited good formaldehyde sensing properties at operating temperature 200 °C, and the minimum-detection-limit was down to 0.08 ppm. The response time and recovery time of the sensors were about 50 s and 80 s to 10 ppm formaldehyde, respectively. The sensor shows a good long-term stability in 90 days. The simple preparation and excellent properties significantly advance the viability of electrospun nanofibers as gas sensing materials. The sensing mechanisms of NSO nanofibers to formaldehyde were discussed. The results indicated that NSO nanofibers could be used as a candidate to fabricate formaldehyde sensors in practice.

Low Pressure CO2 Hydrogenation to Methanol over Gold Nanoparticles Activated on a CeOx/TiO2 Interface

Abstract: Capture and recycling of CO2 into valuable chemicals such as alcohols could help mitigate its emissions into the atmosphere. Due to its inert nature, the activation of CO2 is a critical step in improving the overall reaction kinetics during its chemical conversion. Although pure gold is an inert noble metal and cannot catalyze hydrogenation reactions, it can be activated when deposited as nanoparticles on the appropriate oxide support. In this combined experimental and theoretical study, it is shown that an electronic polarization at the metal-oxide interface of Au nanoparticles anchored and stabilized on a CeO(x)/TiO2 substrate generates active centers for CO2 adsorption and its low pressure hydrogenation, leading to a higher selectivity toward methanol. This study illustrates the importance of localized electronic properties and structure in catalysis for achieving higher alcohol selectivity from CO2 hydrogenation.

Impact of oxygen vacancy occupancy on piezo-catalytic activity of BaTiO3 nanobelt

Abstract: BaTiO3 nanobelt featuring controlled oxygen vacancies, namely BTO-OV-X (X represents time (h) of vacuum heat-treatment), were prepared to systematically investigate the effect of oxygen vacancies occupancy on pizeocatalytic performance for degradation of organic pollutant. Remarkably, the creation of oxygen vacancies on BaTiO3 can mediate the piezocatalytic activity. The piezocatalytic activity exhibited a volcano-type trend with increasing oxygen vacancies. Results from first-principles density functional theoretical (DFT) calculations and O2-temperature programmed desorption (O2-TPD) measurement indicated that the presence of oxygen vacancies could efficiently adsorb and activate O2 on the surface of BaTiO3 nanobelt and consequently enhance piezocatalytic activity. Importantly, with the aid of piezoresponse force microscopy (PFM) measurement, the intrinsic reason of volcano-type trend of oxygen vacancy-activity was well unveiled. This work reveals the effect and mechanism of oxygen vacancy occupancy on enhancing piezocatalytic activity of BaTiO3 nanobelt and will shed light on design of efficient piezocatalysts in the future.