Showing papers by "Delft University of Technology published in 1998"

On combining classifiers

Abstract: We develop a common theoretical framework for combining classifiers which use distinct pattern representations and show that many existing schemes can be considered as special cases of compound classification where all the pattern representations are used jointly to make a decision. An experimental comparison of various classifier combination schemes demonstrates that the combination rule developed under the most restrictive assumptions-the sum rule-outperforms other classifier combinations schemes. A sensitivity analysis of the various schemes to estimation errors is carried out to show that this finding can be justified theoretically.

Room-temperature transistor based on a single carbon nanotube

Abstract: The use of individual molecules as functional electronic devices was first proposed in the 1970s (ref 1) Since then, molecular electronics2,3 has attracted much interest, particularly because it could lead to conceptually new miniaturization strategies in the electronics and computer industry The realization of single-molecule devices has remained challenging, largely owing to difficulties in achieving electrical contact to individual molecules Recent advances in nanotechnology, however, have resulted in electrical measurements on single molecules4,5,6,7 Here we report the fabrication of a field-effect transistor—a three-terminal switching device—that consists of one semiconducting8,9,10 single-wall carbon nanotube11,12 connected to two metal electrodes By applying a voltage to a gate electrode, the nanotube can be switched from a conducting to an insulating state We have previously reported5 similar behaviour for a metallic single-wall carbon nanotube operated at extremely low temperatures The present device, in contrast, operates at room temperature, thereby meeting an important requirement for potential practical applications Electrical measurements on the nanotube transistor indicate that its operation characteristics can be qualitatively described by the semiclassical band-bending models currently used for traditional semiconductor devices The fabrication of the three-terminal switching device at the level of a single molecule represents an important step towards molecular electronics

Electronic structure of atomically resolved carbon nanotubes

Abstract: Carbon nanotubes can be thought of as graphitic sheets with a hexagonal lattice that have been wrapped up into a seamless cylinder. Since their discovery in 19911, the peculiar electronic properties of these structures have attracted much attention. Their electronic conductivity, for example, has been predicted2,3,4 to depend sensitively on tube diameter and wrapping angle (a measure of the helicity of the tube lattice), with only slight differences in these parameters causing a shift from a metallic to a semiconducting state. In other words, similarly shaped molecules consisting of only one element (carbon) may have very different electronic behaviour. Although the electronic properties of multi-walled and single-walled nanotubes5,6,7,8,9,10,11,12 have been probed experimentally, it has not yet been possible to relate these observations to the corresponding structure. Here we present the results of scanning tunnelling microscopy and spectroscopy on individual single-walled nanotubes from which atomically resolved images allow us to examine electronic properties as afunction of tube diameter and wrapping angle. We observe bothmetallic and semiconducting carbon nanotubes and find thatthe electronic properties indeed depend sensitively on thewrapping angle. The bandgaps of both tube types are consistent with theoretical predictions. We also observe van Hove singularities at the onset of one-dimensional energy bands, confirming the strongly one-dimensional nature of conduction within nanotubes.

The sequencing batch reactor as a powerful tool for the study of slowly growing anaerobic ammonium-oxidizing microorganisms

Abstract: Currently available microbiological techniques are not designed to deal with very slowly growing microorganisms. The enrichment and study of such organisms demands a novel experimental approach. In the present investigation, the sequencing batch reactor (SBR) was applied and optimized for the enrichment and quantitative study of a very slowly growing microbial community which oxidizes ammonium anaerobically. The SBR was shown to be a powerful experimental set-up with the following strong points: (1) efficient biomass retention, (2) a homogeneous distribution of substrates, products and biomass aggregates over the reactor, (3) reliable operation for more than 1 year, and (4) stable conditions under substrate-limiting conditions. Together, these points made possible for the first time the determination of several important physiological parameters such as the biomass yield (0.066 ± 0.01 C-mol/mol ammonium), the maximum specific ammonium consumption rate (45 ± 5 nmol/mg protein/min) and the maximum specific growth rate (0.0027 · h−1, doubling time 11 days). In addition, the persisting stable and strongly selective conditions of the SBR led to a high degree of enrichment (74% of the desired microorganism). This study has demonstrated that the SBR is a powerful tool compared to other techniques used in the past. We suggest that the SBR could be used for the enrichment and quantitative study of a large number of slowly growing microorganisms that are currently out of reach for microbiological research.

A tunable kondo effect in quantum dots

Abstract: A tunable Kondo effect has been realized in small quantum dots. A dot can be switched from a Kondo system to a non-Kondo system as the number of electrons on the dot is changed from odd to even. The Kondo temperature can be tuned by means of a gate voltage as a single-particle energy state nears the Fermi energy. Measurements of the temperature and magnetic field dependence of a Coulomb-blockaded dot show good agreement with predictions of both equilibrium and nonequilibrium Kondo effects.

Testing Semiconductor Memories: Theory and Practice

Abstract: Memory modeling functional testing: reduced functional RAM chip model functional RAM chip testing functional ROM chip testing functional memory array testing functional memory board testing electrical testing: parametric testing dynamic testing on chip testing conclusions: address line scrambling various proofs software package.

The anaerobic oxidation of ammonium

Abstract: From recent research it has become clear that at least two different possibilities for anaerobic ammonium oxidation exist in nature. 'Aerobic' ammonium oxidizers like Nitrosomonas eutropha were observed to reduce nitrite or nitrogen dioxide with hydroxylamine or ammonium as electron donor under anoxic conditions. The maximum rate for anaerobic ammonium oxidation was about 2 nmol NH4+ min-1 (mg protein)-1 using nitrogen dioxide as electron acceptor. This reaction, which may involve NO as an intermediate, is thought to generate energy sufficient for survival under anoxic conditions, but not for growth. A novel obligately anaerobic ammonium oxidation (Anammox) process was recently discovered in a denitrifying pilot plant reactor. From this system, a highly enriched microbial community with one dominating peculiar autotrophic organism was obtained. With nitrite as electron acceptor a maximum specific oxidation rate of 55 nmol NH4+ min-1 (mg protein)-1 was determined. Although this reaction is 25-fold faster than in Nitrosomonas, it allowed growth at a rate of only 0.003 h-1 (doubling time 11 days). 15N labeling studies showed that hydroxylamine and hydrazine were important intermediates in this new process. A novel type of hydroxylamine oxidoreductase containing an unusual P468 cytochrome has been purified from the Anammox culture. Microsensor studies have shown that at the oxic/anoxic interface of many ecosystems nitrite and ammonia occur in the absence of oxygen. In addition, the number of reports on unaccounted high nitrogen losses in wastewater treatment is gradually increasing, indicating that anaerobic ammonium oxidation may be more widespread than previously assumed. The recently developed nitrification systems in which oxidation of nitrite to nitrate is prevented form an ideal partner for the Anammox process. The combination of these partial nitrification and Anammox processes remains a challenge for future application in the removal of ammonium from wastewater with high ammonium concentrations.

Similarity measures in fuzzy rule base simplification

Abstract: In fuzzy rule-based models acquired from numerical data, redundancy may be present in the form of similar fuzzy sets that represent compatible concepts. This results in an unnecessarily complex and less transparent linguistic description of the system. By using a measure of similarity, a rule base simplification method is proposed that reduces the number of fuzzy sets in the model. Similar fuzzy sets are merged to create a common fuzzy set to replace them in the rule base. If the redundancy in the model is high, merging similar fuzzy sets might result in equal rules that also can be merged, thereby reducing the number of rules as well. The simplified rule base is computationally more efficient and linguistically more tractable. The approach has been successfully applied to fuzzy models of real world systems.

Mathematical modeling of biofilm structure with a hybrid differential-discrete cellular automaton approach.

Abstract: A hybrid differential-discrete mathematical model has been used to simulate biofilm structures (surface shape, roughness, porosity) as a result of microbial growth in different environmental conditions. In this study, quantitative two- and three-dimensional models were evaluated by introducing statistical measures to characterize the complete biofilm structure, both the surface structure and volume structure. The surface enlargement, coefficient of roughness, fractal dimension of surface, biofilm compactness, and solids hold-up were found to be good measures of biofilm structure complexity. Among many possible factors affecting the biofilm structure, the influence of biomass growth in relation to the diffusive substrate transport was investigated. Porous biofilms, with many channels and voids between the "finger-like" or "mushroom" outgrowth, were obtained in a substrate-transport-limited regime. Conversely, compact and dense biofilms occurred in systems limited by the biomass growth rate and not by the substrate transfer rate. The surface complexity measures (enlargement, roughness, fractal dimension) all increased with increased transport limitation, whereas the volume measures (compactness, solid hold-up) decreased, showing the change from a compact and dense to a highly porous and open biofilm.

Microwave spectroscopy of a quantum-dot molecule

Abstract: Quantum dots are small conductive regions in a semiconductor, containing a variable number of electrons (from one to a thousand) that occupy well-defined, discrete quantum states—for which reason they are often referred to as artificial atoms1. Connecting them to current and voltage contacts allows the discrete energy spectra to be probed by charge-transport measurements. Two quantum dots can be connected to form an ‘artificial molecule’. Depending on the strength of the inter-dot coupling (which supports quantum-mechanical tunnelling of electrons between the dots), the two dots can form ‘ionic’ (26) or ‘covalent’ bonds. In the former case, the electrons are localized on individual dots, while in the latter, the electrons are delocalized over both dots. The covalent binding leads to bonding and antibonding states, whose energy difference is proportional to the degree of tunnelling. Here we report a transition from ionic bonding to covalent bonding in a quantum-dot ‘artificial molecule’ that is probed by microwave excitations5,6,7,8. Our results demonstrate controllable quantum coherence in single-electron devices, an essential requirement for practical applications of quantum-dot circuitry.

A simple model for turbulence induced flocculation of cohesive sediment

Abstract: The transport and fate of fine grained cohesive sediments in estuarine and coastal waters is influenced by the settling velocity of the sediment, which in turn is affected by flocculation effects. The flocculation processes depend on the physico-chemical properties of the sediment and the water, and on several physical mechanisms, of which turbulence is a major one. In the present paper the effects of turbulence are further analyzed. The floes are treated as self-similar fractal entities. As a result, the settling velocity is shown not to scale with the diameter D squared, as predicted by Stokes' law, but with Dnf-1 , where nf is the fractal dimension. Based on a collision frequency function and a floe breakup formulation, a simple flocculation model is proposed that can be solved analytically for uniform conditions. The flocculation and floe breakup coefficients were obtained from experiments described in literature. It is shown that the maximal attainable floe size and settling velocity are determined t...

The precision of proprioceptive position sense

Abstract: The purpose of this study was to determine the precision of proprioceptive localization of the hand in humans. We derived spatial probability distributions which describe the precision of localization on the basis of three different sources of information: proprioceptive information about the left hand, proprioceptive information about the right hand, and visual information. In the experiment subjects were seated at a table and had to perform three different position-matching tasks. In each task, the position of a target and the position of an indicator were available in a different combination of two of these three sources of information. From the spatial distributions of indicated positions in these three conditions, we derived spatial probability distributions for proprioceptive localization of the two hands and for visual localization. For proprioception we found that localization in the radial direction with respect to the shoulder is more precise than localization in the azimuthal direction. The distributions for proprioceptive localization also suggest that hand positions closer to the shoulder are localized more precisely than positions further away. These patterns can be understood from the geometry of the arm. In addition, the variability in the indicated positions suggests that the shoulder and elbow angles are known to the central nervous system with a precision of 0.6-1.1 degrees. This is a considerably better precision than the values reported in studies on perception of these angles. This implies that joint angles, or quantities equivalent to them, are represented in the central nervous system more precisely than they are consciously perceived. For visual localization we found that localization in the azimuthal direction with respect to the cyclopean eye is more precise than localization in the radial direction. The precision of the perception of visual direction is of the order of 0.2-0.6 degrees.

Success probability of integer GPS ambiguity rounding and bootstrapping

Abstract: Global Positioning System ambiguity resolution is usually based on the integer least-squares principle (Teunissen 1993). Solution of the integer least-squares problem requires both the execution of a search process and an ambiguity decorrelation step to enhance the efficiency of this search. Instead of opting for the integer least-squares principle, one might also want to consider less optimal integer solutions, such as those obtained through rounding or sequential rounding. Although these solutions are less optimal, they do have one advantage over the integer least-squares solution: they do not require a search and can therefore be computed directly. However, in order to be confident that these less optimal solutions are still good enough for the application at hand, one requires diagnostic measures to predict their rate of success. These measures of confidence are presented and it is shown how they can be computed and evaluated.

Reducing the peak-to-average power ratio of OFDM

Abstract: The distribution of the peak-to-average power (PAP) ratio of an OFDM signal is derived, showing that large PAP ratios only occur very infrequently. Because of this, PAP reducing techniques which distort the signal can be quite effective, since only a small fraction of the OFDM signal has to be distorted. One example of such a technique is peak windowing. It is shown that peak windowing can achieve PAP ratios around 4 dB for an arbitrary number of subcarriers, at the cost of a slight increase in the BER and out-of-band radiation. Simulations with realistic power amplifier models show that a backoff of about 5 dB is required to get an out-of-band radiation level of 30 dB below the in-band spectral density.

Liquid-crystal adaptive lenses with modal control.

Abstract: We report on a novel approach to the realization of nematic liquid-crystal (LC) phase correctors to form spherical and cylindrical wave fronts. A LC cell with a distributed reactive electrical impedance was driven by an ac voltage applied to the cell boundary to yield the desired spatial distribution of the refractive index. The two-dimensional function of the phase delay introduced into the light beam depends on the frequency of the ac control voltage, the geometry of the boundary electrode surrounding the LC cell, and the electrical parameters of the cell. We realized a cylindrical adaptive lens with a clear aperture of 15 mm x 4mm and a spherical adaptive lens with circular aperture of 6.5 mm. Both devices are capable of focusing collimated light in the range infinity...0.5 m.

Joint angle and delay estimation using shift-invariance techniques

Abstract: In a multipath communication scenario, it is often relevant to estimate the directions and relative delays of each multipath ray. We derive a closed-form subspace-based method for the simultaneous estimation of these parameters from an estimated channel impulse response, using knowledge of the transmitted pulse shape function. The algorithm uses a two-dimensional (2-D) ESPRIT-like shift-invariance technique to separate and estimate the phase shifts due to delay and direction of incidence with automatic pairing of the two parameter sets. Improved resolution is obtained by enlarging the data matrix with shifted and conjugated copies of itself.

Antarctic Elevation Change from 1992 to 1996

Abstract: Satellite radar altimeter measurements show that the average elevation of the Antarctic Ice Sheet interior fell by 0.9 +/- 0.5 centimeters per year from 1992 to 1996. If the variability of snowfall observed in Antarctic ice cores is allowed for, the mass imbalance of the interior this century is only -0.06 +/- 0.08 of the mean mass accumulation rate.

Effect of specific growth rate on fermentative capacity of baker's yeast.

Abstract: The specific growth rate is a key control parameter in the industrial production of baker’s yeast. Nevertheless, quantitative data describing its effect on fermentative capacity are not available from the literature. In this study, the effect of the specific growth rate on the physiology and fermentative capacity of an industrial Saccharomyces cerevisiae strain in aerobic, glucose-limited chemostat cultures was investigated. At specific growth rates (dilution rates, D) below 0.28 h−1, glucose metabolism was fully respiratory. Above this dilution rate, respirofermentative metabolism set in, with ethanol production rates of up to 14 mmol of ethanol · g of biomass−1 · h−1 at D = 0.40 h−1. A substantial fermentative capacity (assayed offline as ethanol production rate under anaerobic conditions) was found in cultures in which no ethanol was detectable (D < 0.28 h−1). This fermentative capacity increased with increasing dilution rates, from 10.0 mmol of ethanol · g of dry yeast biomass−1 · h−1 at D = 0.025 h−1 to 20.5 mmol of ethanol · g of dry yeast biomass−1 · h−1 at D = 0.28 h−1. At even higher dilution rates, the fermentative capacity showed only a small further increase, up to 22.0 mmol of ethanol · g of dry yeast biomass−1 · h−1 at D = 0.40 h−1. The activities of all glycolytic enzymes, pyruvate decarboxylase, and alcohol dehydrogenase were determined in cell extracts. Only the in vitro activities of pyruvate decarboxylase and phosphofructokinase showed a clear positive correlation with fermentative capacity. These enzymes are interesting targets for overexpression in attempts to improve the fermentative capacity of aerobic cultures grown at low specific growth rates.

Rule-based modeling: precision and transparency

Abstract: This article is a reaction to recent publications on rule-based modeling using fuzzy set theory and fuzzy logic. The interest in fuzzy systems has recently shifted from the seminal ideas about complexity reduction toward data-driven construction of fuzzy systems. Many algorithms have been introduced that aim at numerical approximation of functions by rules, but pay little attention to the interpretability of the resulting rule base. We show that fuzzy rule-based models acquired from measurements can be both accurate and transparent by using a low number of rules. The rules are generated by product-space clustering and describe the system in terms of the characteristic local behavior of the system in regions identified by the clustering algorithm. The fuzzy transition between rules makes it possible to achieve precision along with a good qualitative description in linguistic terms. The latter is useful for expert evaluation, rule-base maintenance, operator training, control systems design, user interfacing, etc. We demonstrate the approach on a modeling problem from a recently published article.

Superconductor‐Insulator Transitions in the Two‐Dimensional Limit

Abstract: The investigation of superconductivity in the presence of disorder began 60 years ago with the work of Alexander Shal'nikov at the Institute for Physical Problems in Moscow. The subject has played an ongoing role in condensed matter physics over the years. Interest has recently been heightened by the possibility that the disorder‐driven or magnetic‐field‐driven quenching of superconductivity in systems at the limit of zero temperature and two dimensions might be quantum phase transitions. That would link the physics of the superconductor‐insulator transition in thin films to other systems believed to exhibit quantum phase transitions—for example, helium‐4 in porous media, high temperature superconductors, Josephson‐junction arrays, two‐dimensional electron gases and various spin systems.