Showing papers by "Delft University of Technology published in 2007"

Spins in few-electron quantum dots

Abstract: The canonical example of a quantum-mechanical two-level system is spin. The simplest picture of spin is a magnetic moment pointing up or down. The full quantum properties of spin become apparent in phenomena such as superpositions of spin states, entanglement among spins, and quantum measurements. Many of these phenomena have been observed in experiments performed on ensembles of particles with spin. Only in recent years have systems been realized in which individual electrons can be trapped and their quantum properties can be studied, thus avoiding unnecessary ensemble averaging. This review describes experiments performed with quantum dots, which are nanometer-scale boxes defined in a semiconductor host material. Quantum dots can hold a precise but tunable number of electron spins starting with 0, 1, 2, etc. Electrical contacts can be made for charge transport measurements and electrostatic gates can be used for controlling the dot potential. This system provides virtually full control over individual electrons. This new, enabling technology is stimulating research on individual spins. This review describes the physics of spins in quantum dots containing one or two electrons, from an experimentalist’s viewpoint. Various methods for extracting spin properties from experiment are presented, restricted exclusively to electrical measurements. Furthermore, experimental techniques are discussed that allow for 1 the rotation of an electron spin into a superposition of up and down, 2 the measurement of the quantum state of an individual spin, and 3 the control of the interaction between two neighboring spins by the Heisenberg exchange interaction. Finally, the physics of the relevant relaxation and dephasing mechanisms is reviewed and experimental results are compared with theories for spin-orbit and hyperfine interactions. All these subjects are directly relevant for the fields of quantum information processing and spintronics with single spins i.e., single spintronics.

Solid-state nanopores

Abstract: The passage of individual molecules through nanosized pores in membranes is central to many processes in biology. Previously, experiments have been restricted to naturally occurring nanopores, but advances in technology now allow artificial solid-state nanopores to be fabricated in insulating membranes. By monitoring ion currents and forces as molecules pass through a solid-state nanopore, it is possible to investigate a wide range of phenomena involving DNA, RNA and proteins. The solid-state nanopore proves to be a surprisingly versatile new single-molecule tool for biophysics and biotechnology.

Enzyme immobilization: The quest for optimum performance

Abstract: Immobilization is often the key to optimizing the operational performance of an enzyme in industrial processes, particularly for use in non-aqueous media. Different methods for the immobilization of enzymes are critically reviewed. The methods are divided into three main categories, viz. (i) binding to a prefabricated support (carrier), (ii) entrapment in organic or inorganic polymer matrices, and (iii) cross-linking of enzyme molecules. Emphasis is placed on relatively recent developments, such as the use of novel supports, e.g., mesoporous silicas, hydrogels, and smart polymers, novel entrapment methods and cross-linked enzyme aggregates (CLEAs).

Biocatalysis in ionic liquids

Abstract: Roger Sheldon (1942) received a PhD in organic chemistry from the University of Leicester (UK) in 1967. This was followed by post-doctoral studies with Prof. Jay Kochi in the U.S. From 1969 to 1980 he was with Shell Research in Amsterdam and from 1980 to 1990 he was R&D Director of DSM Andeno. In 1991 he moved to his present position as Professor of organic chemistry and catalysis at the Delft University of Technology (The Netherlands). His primary research interests are in the application of catalytic methodologies—homogeneous, heterogeneous and enzymatic—in organic synthesis, particularly in relation to fine chemicals production. He developed the concepts of E factors and atom utilization for assessing the environmental impact of chemical processes.

Microbial Carbonate Precipitation as a Soil Improvement Technique

Abstract: In order to evaluate MCP as a soil strengthening process, a five meter sand column was treated with bacteria and reagents under conditions that were realistic for field applications. The injection and reaction parameters were monitored during the process and both bacteria and process reagents could be injected over the full column length at low pressures (hydraulic gradient < 1; a flow rate of approximately 7 m/day) without resulting in clogging of the material. After treatment, the column was subjected to mechanical testing, which indicated a significant improvement of strength and stiffness over several meters. Calcium carbonate was precipitated over the entire five meter treatment length. Improvement of the load bearing capacity of the soil without making the soil impermeable to fluids was shown with microbial carbonate precipitation, and this is a unique property compared to alternative soil treatment methods that are currently available for use in the subsurface.

Genome sequencing and analysis of the versatile cell factory Aspergillus niger CBS 513.88

Abstract: The filamentous fungus Aspergillus niger is widely exploited by the fermentation industry for the production of enzymes and organic acids, particularly citric acid. We sequenced the 33.9-megabase genome of A. niger CBS 513.88, the ancestor of currently used enzyme production strains. A high level of synteny was observed with other aspergilli sequenced. Strong function predictions were made for 6,506 of the 14,165 open reading frames identified. A detailed description of the components of the protein secretion pathway was made and striking differences in the hydrolytic enzyme spectra of aspergilli were observed. A reconstructed metabolic network comprising 1,069 unique reactions illustrates the versatile metabolism of A. niger. Noteworthy is the large number of major facilitator superfamily transporters and fungal zinc binuclear cluster transcription factors, and the presence of putative gene clusters for fumonisin and ochratoxin A synthesis.

Bipolar supercurrent in graphene

Abstract: Graphene--a recently discovered form of graphite only one atomic layer thick--constitutes a new model system in condensed matter physics, because it is the first material in which charge carriers behave as massless chiral relativistic particles. The anomalous quantization of the Hall conductance, which is now understood theoretically, is one of the experimental signatures of the peculiar transport properties of relativistic electrons in graphene. Other unusual phenomena, like the finite conductivity of order 4e(2)/h (where e is the electron charge and h is Planck's constant) at the charge neutrality (or Dirac) point, have come as a surprise and remain to be explained. Here we experimentally study the Josephson effect in mesoscopic junctions consisting of a graphene layer contacted by two closely spaced superconducting electrodes. The charge density in the graphene layer can be controlled by means of a gate electrode. We observe a supercurrent that, depending on the gate voltage, is carried by either electrons in the conduction band or by holes in the valence band. More importantly, we find that not only the normal state conductance of graphene is finite, but also a finite supercurrent can flow at zero charge density. Our observations shed light on the special role of time reversal symmetry in graphene, and demonstrate phase coherent electronic transport at the Dirac point.

Coherent Control of a Single Electron Spin with Electric Fields

Abstract: Manipulation of single spins is essential for spin-based quantum information processing Electrical control instead of magnetic control is particularly appealing for this purpose, because electric fields are easy to generate locally on-chip We experimentally realized coherent control of a single-electron spin in a quantum dot using an oscillating electric field generated by a local gate The electric field induced coherent transitions (Rabi oscillations) between spin-up and spin-down with 90 degrees rotations as fast as approximately 55 nanoseconds Our analysis indicated that the electrically induced spin transitions were mediated by the spin-orbit interaction Taken together with the recently demonstrated coherent exchange of two neighboring spins, our results establish the feasibility of fully electrical manipulation of spin qubits

HVDC Connection of Offshore Wind Farms to the Transmission System

Abstract: This paper presents a technical and economic analysis to evaluate the benefits and drawbacks of grid connecting offshore wind farms through a dc link. A first case, concerning a 100-MW wind farm, is thoroughly investigated and cases of larger wind farms (200 and 500 MW) are presented. Three different transmission solutions are compared: 150-kV ac, 400-kV ac, and high-voltage dc based on voltage sourced converters (VSC-HVDC). After a brief overview of the features of these connection solutions, the related operational aspects are evaluated. An economic assessment compares the dc connection option to the ac alternatives, taking into account the investment, operation, and maintenance costs, and the negative valorization of losses and energy not supplied. Economic assessment includes sensitivity analyses of parameters, which could impact the 100-MW wind farm: distance, component costs, dc converter reliability, and dc converter losses

Moving beyond heterogeneity and process complexity: A new vision for watershed hydrology

Abstract: Field studies in watershed hydrology continue to characterize and catalogue the enormous heterogeneity and complexity of rainfall runoff processes in more and more watersheds, in different hydroclimatic regimes, and at different scales. Nevertheless, the ability to generalize these findings to ungauged regions remains out of reach. In spite of their apparent physical basis and complexity, the current generation of detailed models is process weak. Their representations of the internal states and process dynamics are still at odds with many experimental findings. In order to make continued progress in watershed hydrology and to bring greater coherence to the science, we need to move beyond the status quo of having to explicitly characterize or prescribe landscape heterogeneity in our (highly calibrated) models and in this way reproduce process complexity and instead explore the set of organizing principles that might underlie the heterogeneity and complexity. This commentary addresses a number of related new avenues for research in watershed science, including the use of comparative analysis, classification, optimality principles, and network theory, all with the intent of defining, understanding, and predicting watershed function and enunciating important watershed functional traits.

On the Accuracy of Spectrum-based Fault Localization

Abstract: Spectrum-based fault localization shortens the test- diagnose-repair cycle by reducing the debugging effort. As a light-weight automated diagnosis technique it can easily be integrated with existing testing schemes. However, as no model of the system is taken into account, its diagnostic accuracy is inherently limited. Using the Siemens Set benchmark, we investigate this diagnostic accuracy as a function of several parameters (such as quality and quantity of the program spectra collected during the execution of the system), some of which directly relate to test design. Our results indicate that the superior performance of a particular similarity coefficient, used to analyze the program spectra, is largely independent of test design. Furthermore, near- optimal diagnostic accuracy (exonerating about 80% of the blocks of code on average) is already obtained for low-quality error observations and limited numbers of test cases. The influence of the number of test cases is of primary importance for continuous (embedded) processing applications, where only limited observation horizons can be maintained.

Large Impact of Particle Size on Insertion Reactions. A Case for Anatase LixTiO2

Abstract: Insertion reactions are of key importance for Li ion and hydrogen storage materials and energy storage devices. The particle size dependence of insertion reactions has been investigated for lithiated anatase TiO2, revealing progressively increasing Li capacity and Li-ion solubility for decreasing particle sizes, strongly deviating from the expected Li-rich and Li-poor phase separation as occurs in the bulk material. The phase diagram alters significantly, changing the materials properties already at sizes as large as 40 nm. A rationale is found in the surface strain that occurs between the different intercalated phases, which becomes energetically too costly in small particles. In particular the observed particle size-induced solid solution behavior is expected to have fundamental and practical implications for two-phase lithium or hydrogen insertion reactions.

Impacts of Wind Power on Thermal Generation Unit Commitment and Dispatch

Abstract: This paper proposes a new simulation method that can fully assess the impacts of large-scale wind power on system operations from cost, reliability, and environmental perspectives. The method uses a time series of observed and predicted 15-min average wind speeds at foreseen onshore- and offshore-wind farm locations. A Unit Commitment and Economic Dispatch (UC-ED) tool is adapted to allow for frequent revisions of conventional generation unit schedules, using information on current wind energy output and forecasts for the next 36 h. This is deemed the most faithful way of simulating actual operations and short-term planning activities for a system with large wind power penetration. The problem formulation includes ramp-rate constraints for generation schedules and for reserve activation, and minimum up-time and down-time of conventional units. Results are shown for a realistic future scenario of the Dutch power system. It is shown that problems such as insufficient regulating and reserve power-which are typically associated with the variability and limited predictability of wind power-can only be assessed in conjunction with the specifics of the conventional generation system that wind power is integrated into. For the thermal system with a large share of combined heat and power (CHP) investigated here, wind power forecasting does not provide significant benefits for optimal unit commitment and dispatch. Minimum load problems do occur, which result in wasted wind in amounts increasing with the wind power installed

Filtering and System Identification: A Least Squares Approach

Abstract: Preface 1. Introduction 2. Linear algebra 3. Discrete-time signals and systems 4. Random variables and signals 5. Kalman filtering 6. Estimation of spectra and frequency response functions 7. Output-error parametric model estimation 8. Prediction-error parametric model estimation 9. Subspace model identification 10. The system identification cycle Notation and symbols List of abbreviations References Index.

Photoluminescence and Conductivity of Self-Assembled π–π Stacks of Perylene Bisimide Dyes

Abstract: The self-assembly of a new, highly fluorescent perylene bisimide dye 2 into pi stacks, both in solution and condensed phase, has been studied in detail by NMR spectroscopy, vapor pressure osmometry (VPO), UV/Vis and fluorescence spectroscopy, differential scanning calorimetry (DSC), optical polarizing microscopy (OPM) and X-ray diffraction. The NMR and VPO measurements revealed the formation of extended pi-pi stacks of the dye molecules in solution. The aggregate size determined from VPO and DOSY NMR measurements agree well with that obtained from the concentration and temperature-dependent UV/Vis spectral data by employing the isodesmic model (equal K model). In the condensed state, dye 2 possesses a hexagonal columnar liquid crystalline (LC) phase as confirmed by X-ray diffraction analysis. The columnar stacking of this dye has been further explored by atomic force microscopy (AFM). Well-resolved columnar nanostructures of the compound are observed on graphite surface. A color-tunable luminescence from green to red has been observed upon aggregation which is accompanied by an increase of the fluorescence lifetime and depolarization. The observed absorption properties can be explained in terms of molecular exciton theory. The charge transport properties of dye 2 have been investigated by pulse radiolysis-time resolved microwave conductivity measurements and a 1D charge carrier mobility up to 0.42 cm(2) V(-1) s(-1) is obtained. Considering the promising self-assembly, semiconducting, and luminescence properties of this dye, it might serve as a useful functional material for nano(opto)electronics.

Anammox bacteria disguised as denitrifiers: nitrate reduction to dinitrogen gas via nitrite and ammonium

Abstract: Anaerobic ammonium-oxidizing (anammox) bacteria oxidize ammonium with nitrite and produce N(2). They reside in many natural ecosystems and contribute significantly to the cycling of marine nitrogen. Anammox bacteria generally live under ammonium limitation, and it was assumed that in nature anammox bacteria depend on other biochemical processes for ammonium. In this study we investigated the possibility of dissimilatory nitrate reduction to ammonium by anammox bacteria. Physically purified Kuenenia stuttgartiensis cells reduced (15)NO(3) (-) to (15)NH(4) (+) via (15)NO(2) (-) as the intermediate. This was followed by the anaerobic oxidation of the produced ammonium and nitrite. The overall end-product of this metabolism of anammox bacteria was (15)N(15)N dinitrogen gas. The nitrate reduction to nitrite proceeds at a rate of 0.3 +/- 0.02 fmol cell(-1) day(-1) (10% of the 'normal' anammox rate). A calcium-dependent cytochrome c protein with a high (305 mumol min(-1) mg protein(-1)) rate of nitrite reduction to ammonium was partially purified. We present evidence that dissimilatory nitrate reduction to ammonium occurs in Benguela upwelling system at the same site where anammox bacteria were previously detected. This indicates that anammox bacteria could be mediating dissimilatory nitrate reduction to ammonium in natural ecosystems.

Short-Circuit Current of Wind Turbines With Doubly Fed Induction Generator

Abstract: The short-circuit current contribution of wind turbines has not received much attention so far. This paper considers the short-circuit behavior, especially the short-circuit current of wind turbines with a doubly fed induction generator. Mostly, these wind turbines have a crowbar to protect the power electronic converter that is connected to the rotor windings of the induction generator. First, the maximum value of the short-circuit current of a conventional induction machine is determined. The differences between a crowbar-protected doubly fed induction generator and a conventional induction generator are highlighted and approximate equations for the maximum short-circuit current of a doubly fed induction generator are determined. The values obtained in this way are compared to the values obtained from time domain simulations. The differences are less then 15%

Improving catalytic function by ProSAR-driven enzyme evolution

Abstract: We describe a directed evolution approach that should find broad application in generating enzymes that meet predefined process-design criteria. It augments recombination-based directed evolution by incorporating a strategy for statistical analysis of protein sequence activity relationships (ProSAR). This combination facilitates mutation-oriented enzyme optimization by permitting the capture of additional information contained in the sequence-activity data. The method thus enables identification of beneficial mutations even in variants with reduced function. We use this hybrid approach to evolve a bacterial halohydrin dehalogenase that improves the volumetric productivity of a cyanation process ∼4,000-fold. This improvement was required to meet the practical design criteria for a commercially relevant biocatalytic process involved in the synthesis of a cholesterol-lowering drug, atorvastatin (Lipitor), and was obtained by variants that had at least 35 mutations.

Motor proteins at work for nanotechnology.

Abstract: The biological cell is equipped with a variety of molecular machines that perform complex mechanical tasks such as cell division or intracellular transport. One can envision employing these biological motors in artificial environments. We review the progress that has been made in using motor proteins for powering or manipulating nanoscale components. In particular, kinesin and myosin biomotors that move along linear biofilaments have been widely explored as active components. Currently realized applications are merely proof-of-principle demonstrations. Yet, the sheer availability of an entire ready-to-use toolbox of nanosized biological motors is a great opportunity that calls for exploration.

A decade of GPS in Southeast Asia: Resolving Sundaland motion and boundaries

Abstract: A unique GPS velocity field that spans the entire Southeast Asia region is presented. It is based on 10 years (1994–2004) of GPS data at more than 100 sites in Indonesia, Malaysia, Thailand, Myanmar, the Philippines, and Vietnam. The majority of the horizontal velocity vectors have a demonstrated global accuracy of ?1 mm/yr (at 95% confidence level). The results have been used to (better) characterize the Sundaland block boundaries and to derive a new geokinematic model for the region. The rotation pole of the undeformed core of the Sundaland block is located at 49.0°N–94.2°E, with a clockwise rotation rate of 0.34°/Myr. With respect to both geodetically and geophysically defined Eurasia plate models, Sundaland moves eastward at a velocity of 6 ± 1 to 10 ± 1 mm/yr from south to north, respectively. Contrary to previous studies, Sundaland is shown to move independently with respect to South China, the eastern part of Java, the island of Sulawesi, and the northern tip of Borneo. The Red River fault in South China and Vietnam is still active and accommodates a strike?slip motion of ?2 mm/yr. Although Sundaland internal deformation is general very small (less than 7 nanostrain/yr), important accumulation of elastic deformation occurs along its boundaries with fast?moving neighboring plates. In particular in northern Sumatra and Malaysia, inland?pointing trench?perpendicular residual velocities were detected prior to the megathrust earthquake of 26 December 2004. Earlier studies in Sumatra already showed this but underestimated the extent of the deformation zone, which reaches more than 600 km away from the trench. This study shows that only a regional Southeast Asia network spanning thousands of kilometers can provide a reference frame solid enough to analyze intraplate and interplate deformation in detail.

Power generation by pressure-driven transport of ions in nanofluidic channels.

Abstract: We report on the efficiency of electrical power generation in individual rectangular nanochannels by means of streaming currents, the pressure-driven transport of counterions in the electrical double layer. Our experimental study as a function of channel height and salt concentration reveals that the highest efficiency occurs when double layers overlap, which corresponds to nanoscale fluidic channels filled with aqueous solutions of low ionic strength. The highest efficiency of approximately 3% was found for a 75 nm high channel, the smallest channel measured. The data are well described by Poisson-Boltzmann theory with an additional electrical conductance of the Stern layer.