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Showing papers by "DSM published in 2000"


Journal ArticleDOI
TL;DR: In this article, the XPS coherent binding energy (BE) data basis for reference compounds that are representative of oxidation products formed onto the pyrite reactive surface was presented, and the data in BEs obtained from reference compounds have been exploited to show the surface species of an oxidized pyritic in a HCO3−2 M medium.

632 citations


Journal ArticleDOI
TL;DR: It is shown that it is possible to create a highly nonlinear three-dimensional force-free configuration consisting of a twisted magnetic flux rope representing the magnetic structure of a prominence and exhibiting an S-shaped structure, as observed in soft X-ray sigmoid structures.
Abstract: We present a new approach to the theory of large-scale solar eruptive phenomena such as coronal mass ejections and two-ribbon flares, in which twisted flux tubes play a crucial role. We show that it is possible to create a highly nonlinear three-dimensional force-free configuration consisting of a twisted magnetic flux rope representing the magnetic structure of a prominence (surrounded by an overlaying, almost potential, arcade) and exhibiting an S-shaped structure, as observed in soft X-ray sigmoid structures. We also show that this magnetic configuration cannot stay in equilibrium and that a considerable amount of magnetic energy is released during its disruption. Unlike most previous models, the amount of magnetic energy stored in the configuration prior to its disruption is so large that it may become comparable to the energy of the open field.

427 citations


Journal ArticleDOI
Delphine Porquet1, J Dubau
TL;DR: In this paper, He-like line ratios (resonance, inter-combination and forbidden lines) for totally and partially photoionized media are presented for the AGN.
Abstract: We present He-like line ratios (resonance, inter- combination and forbidden lines) for totally and partially photoionized media. For solar plasmas, these line ratios are already widely used for density and temperature di- agnostics of coronal (collisional) plasmas. In the case of totally and partially photoionized plasmas, He-like line ra- tios allow for the determination of the ionization processes involved in the plasma (photoionization with or without an additional collisional ionization process), as well as the density and the electronic temperature. With the new generation of X-ray satellites, Chandra/AXAF, XMM and Astro-E, it will be fea- sible to obtain both high spectral resolution and high sensitivity observations. Thus in the coming years, the ratios of these three components will be measurable for a large number of non-solar objects. In particular, these ratios could be applied to the Warm Absorber-Emitter, commonly present in Active Galactic Nuclei (AGN). A better understanding of the Warm Absorber connection to other regions (Broad Line Region, Narrow Line Region) in AGN (Seyferts type-1 and type-2, low- and high-redshift quasars...) will be an important key to obtaining strong constraints on unied schemes. We have calculated He-like line ratios, for Z =6 , 7, 8, 10, 12 and 14, taking into account the upper level radia- tive cascades which we have computed for radiative and dielectronic recombinations and collisional excitation. The atomic data are tabulated over a wide range of tempera- tures in order to be used for interpreting a large variety of astrophysical plasmas.

334 citations


Journal ArticleDOI
TL;DR: In this paper, radio imaging of the microquasar GRS 1915+105 with the Very Long Baseline Array (VLBA) over a range of wavelengths (13, 3.6, 2.0, and 0.6 mas) was used to detect the superluminal motion of the ejecta in a few hours.
Abstract: Radio imaging of the microquasar GRS 1915+105 with the Very Long Baseline Array (VLBA) over a range of wavelengths (13, 3.6, 2.0, and 0.7 cm), in different states of the black hole binary, always resolves the nucleus as a compact jet of length ~10λcm AU. The nucleus is best imaged at the shorter wavelengths, on scales of 2.5-7 AU (0.2-0.6 mas resolution). The brightness temperature of the core is TB ≥ 109 K, and its properties are better fitted by a conically expanding synchrotron jet model rather than a thermal jet. The nuclear jet varies in ~30 minutes during minor X-ray/radio outbursts and reestablishes within ~18 hr of a major outburst, indicating the robustness of the X-ray/radio (or disk/jet) system to disruption. At lower resolution (80-240 AU), more extended ejecta are imaged at ~500 AU separation from the stationary core. Time-lapse images clearly detect the superluminal motion of the ejecta in a few hours. The measured velocity is 1.5c ± 0.1c (D/12 kpc) for the approaching component and is consistent with ballistic motion of the ejecta from 500 AU outward, perhaps even since birth. The axis of the ejecta differs by ≤12° clockwise from the axis of the AU-scale jet, measured in the same observation. Both axes are stable in time (±5°), the AU scale for 2 yr and the large scale for over 4 yr. Astrometry over 2 yr relative to an extragalactic reference locates the black hole to ±1.5 mas, and its secular parallax due to Galactic rotation is 5.8 ± 1.5 mas yr-1, consistent with a distance of 12 kpc. Finally, a limit of ≤100 km s-1 is placed on its proper motion with respect to its neighborhood. Some accreting black holes of stellar mass (e.g., Cyg X-1, 1E 1740-2942, GRS 1758-258, GX 339-4) and supermassive black holes at the center of galaxies (e.g., Sgr A*) lack evidence of large flares and discrete transient ejecta but have compact radio cores with steady, flat-spectrum "plateau" states, like GRS 1915+105. To the present day GRS 1915+105 is the only system where both AU-scale steady jets and large-scale superluminal ejections have been unambiguously observed. Our observations suggest that the unresolved flat-spectrum radio cores of accreting black holes are compact quasi-continuous synchrotron jets.

287 citations


Journal ArticleDOI
TL;DR: In this article, the authors present Keck HIRES spectra of six late-M dwarfs and 11 L dwarfs, and assign effective temperatures to the objects using detailed atmospheric models and fine analysis of the alkali resonance absorption lines of Cs I and Rb I.
Abstract: We present Keck HIRES spectra of six late-M dwarfs and 11 L dwarfs. Our goal is to assign effective temperatures to the objects using detailed atmospheric models and fine analysis of the alkali resonance absorption lines of Cs I and Rb I. These yield mutually consistent results (?50 K) when we use cleared-dust models, which account for the removal of refractory species from the molecular states but do not include dust opacities. We find a tendency for the Rb I line to imply a slightly higher temperature, which we ascribe to an incomplete treatment of the overlying molecular opacities. The final Teff we adopt are based on the Cs I fits alone, though the Rb I fits support the Cs I temperature sequence. This work, in combination with results from the infrared, hints that dust in these atmospheres has settled out of the high atmosphere but is present in the deep photosphere. We also derive radial and rotational velocities for all the objects, finding that the previously discovered trend of rapid rotation for very low mass objects is quite pervasive. To improve on our analysis, there is a clear need for better molecular line lists and a more detailed understanding of dust formation and dynamics.

245 citations


Journal ArticleDOI
TL;DR: In this article, the American Astronomical Society published a survey of the state-of-the-art in astronomy and astronomy applications, focusing on the following topics: astronomy, astronomy, and astronomy.
Abstract: Original article can be found at: http://www.journals.uchicago.edu/AJ/--Copyright American Astronomical Society

242 citations


Journal ArticleDOI
TL;DR: In this article, it was shown that dust transport constitutes a large fraction of the annual atmospheric deposition in the eastern Mediterranean, with two deposition events of short duration accounting up to 30% of the total annual flux.

222 citations


Journal ArticleDOI
TL;DR: In this article, high-resolution transmission electron microscopy and electron diffraction were performed in order to explain the structure of the rods, which were held to be truncated decahedra with a fivefold symmetry, i.e., the fivefold axis very often was parallel to the surface of the substrate.
Abstract: Well-defined long Cu rods having a length of the order of 1 \ensuremath{\mu}m and diameters of several nanometers were prepared by reduction of copper compounds. After deposition on amorphous carbon films, high-resolution transmission electron microscopy and electron diffraction were performed in order to explain the structure of the rods. By applying computer simulations with multislice calculations, the particle structure was obtained. The rods were held to be truncated decahedra with a fivefold symmetry. It could be shown that most particles were oriented in the [001] direction with respect to the substrate for one of the five deformed tetrahedral subunits, i.e., the fivefold axis very often was parallel to the surface of the substrate. It was also proven that the Cu fcc bulk structure containing stacking faults had to be excluded as a possible structural model. Also, truncated icosahedral structures or icosahedra with additional intermediate planes did not serve to explain the experimental process. Icosahedra are often observed together with decahedral structures for particles with a spherical-like morphology. Due to the presence of surfactant, only growth in the direction of the fivefold axis of decahedra was possible, resulting in long needlelike rods.

215 citations


Journal ArticleDOI
Hans G. Drexler1, S M Gignac1, R von Wasielewski, Martin Werner, Wilhelm G. Dirks1 
01 Sep 2000-Leukemia
TL;DR: The fact that patients with ALK lymphomas experience significantly better overall survival than ALK− ALCL demonstrates further that analysis of ALK expression has important prognostic implications.
Abstract: Despite its clinical and histological heterogeneity, anaplastic large cell lymphoma (ALCL) is now a well-recognized clinicopathological entity accounting for 2% of all adult non-Hodgkin's lymphomas (NHL) and about 13% of pediatric NHL. Immunophenotypically, ALCL are of T cell (predominantly) or Null cell type; by definition, cases expressing B cell antigens are officially not included in this entity. The translocation (2;5)(p23;q35) is a recurring abnormality in ALCL; 46% of the ALCL patients bear this signature translocation. This translocation creates a fusion gene composed of nucleophosmin (NPM) and a novel receptor tyrosine kinase gene, named anaplastic lymphoma kinase (ALK). The NPM-ALK chimeric gene encodes a constitutively activated tyrosine kinase that has been shown to be a potent oncogene. The exact pathogenetic mechanisms leading to lymphomagenesis remain elusive; however, the synopsis of evidence obtained to date provides an outline of likely scenarios. Several t(2;5) variants have been described; in some instances, the breakpoints have been cloned and the genes forming a new fusion gene with ALK have been identified: ATIC-ALK, TFG-ALK and TPM3-ALK. Cloning the translocation breakpoint and identifying the ALK and NPM genes provided tools for screening material from patients with ALCL using various approaches at the chromosome, DNA, RNA, or protein level: positive signals in the reverse transcriptase-polymerase chain reaction (RT-PCR) and the immunostaining with anti-ALK monoclonal antibodies (McAb) serve as the most convenient tests for detection of the t(2;5) NPM-ALK since the fusion gene and ALK protein expression do not occur in normal or reactive lymphoid tissue. The wide range of NPM-ALK positivity reported in different series appears to be dependent on the inclusion and selection criteria of the ALCL cases studied. Overall, however, 43% of ALCL cases were NPM-ALK+ (83% of pediatric ALCL vs 31% of adult ALCL). Occasional non-ALCL B cell lymphomas (4%) with diffuse large cell and immunoblastic histology and Hodgkin's disease cases (3%) were NPM-ALK-, but these data are questionable. The aggregate results indicate that, in contrast to primary nodal (systemic) ALCL, the t(2;5) may be present in only 10-20% of primary cutaneous ALCL and rarely, if at all, in lymphomatoid papulosis, a potential precursor lesion; however, these 10-20% positive cases were not confirmed by anti-ALK McAb immunostaining and may represent an overestimate. Positivity for NPM-ALK is associated to various degrees with the following parameters: 44% and 45% of ALCL cases with T cell and Null cell immunophenotype, respectively, are positive, whereas only 8% of cases with a B cell immunoprofile are positive; the mean age of positive patients is significantly younger than that of negative patients; positive cases carry a better overall prognosis (but not in all studies). Recently, the homogenous category of ALK lymphoma ('ALKoma') has emerged as a distinct pathological entity within the heterogenous group of ALCL. The fact that patients with ALK lymphomas experience significantly better overall survival than ALK- ALCL demonstrates further that analysis of ALK expression has important prognostic implications. The term ALK lymphoma signifies a switch in the use of the diagnostic criteria: cases are selected on the basis of a genetic abnormality (the ALK rearrangement), instead of the review of morphological or immunophenotypical features which are clearly more prone to disagreement and controversy. Since its initial description in 1985 ALCL has become one of the best characterized lymphoma entities.

193 citations


Journal ArticleDOI
TL;DR: In this article, the first published maps of magnetic fields in prestellar cores were presented to test theoretical ideas about the way in which the magnetic field geometry affects the star formation process.
Abstract: We present the first published maps of magnetic fields in prestellar cores to test theoretical ideas about the way in which the magnetic field geometry affects the star formation process. The observations are JCMT-SCUBA maps of λ850 μm thermal emission from dust. Linear polarizations at typically 10 or more independent positions in each of three objects, L1544, L183, and L43, were measured, and the geometries of the magnetic fields in the plane of the sky were mapped from the polarization directions. The observed polarizations in all three objects appear smooth and fairly uniform. In L1544 and L183 the mean magnetic fields are at an angle of ~30° to the minor axes of the cores. The L43 B-field appears to have been influenced in its southern half such that it is parallel to the wall of a cavity produced by a CO outflow from a nearby T Tauri star, while in the northern half the field appears less disturbed and has an angle 44° to the core minor axis. We briefly compare our results with published models of magnetized cloud cores and conclude that no current model can explain these observations simultaneously with previous ISOCAM data.

191 citations


Journal ArticleDOI
TL;DR: In this article, femtosecond fluorescence and absorption spectroscopies are used to probe the early events of photoinduced proton transfer (PT) from pyranine to water.

Journal ArticleDOI
Delphine Porquet1, J Dubau
TL;DR: In this article, He-like line ratios (resonance, intercombination and forbidden lines) for totally and partially photoionized media have been presented, for Z = 6, 7, 8, 10, 12 and 14, taking into account the upper level radiative cascades which have computed for radiative and dielectronic recombinations and collisional excitation.
Abstract: We present He-like line ratios (resonance, intercombination and forbidden lines) for totally and partially photoionized media. For solar plasmas, these line ratios are already widely used for density and temperature diagnostics of coronal (collisional) plasmas. In the case of totally and partially photoionized plasmas, He-like line ratios allow for the determination of the ionization processes involved in the plasma (photoionization with or without an additional collisional ionization process), as well as the density and the electronic temperature. With the new generation of X-ray satellites, Chandra/AXAF, XMM and Astro-E, it will be feasible to obtain both high spectral resolution and high sensitivity observations. Thus in the coming years, the ratios of these three components will be measurable for a large number of non-solar objects. In particular, these ratios could be applied to the Warm Absorber-Emitter, commonly present in Active Galactic Nuclei (AGN). A better understanding of the Warm Absorber connection to other regions (Broad Line Region, Narrow Line Region) in AGN (Seyferts type-1 and type-2, low- and high-redshift quasars...) will be an important key to obtaining strong constraints on unified schemes. We have calculated He-like line ratios, for Z=6, 7, 8, 10, 12 and 14, taking into account the upper level radiative cascades which we have computed for radiative and dielectronic recombinations and collisional excitation. The atomic data are tabulated over a wide range of temperatures in order to be used for interpreting a large variety of astrophysical plasmas.

Journal ArticleDOI
TL;DR: In this paper, the authors presented new aperture synthesis CO maps of the Antennae (NGC 4038/39) obtained with the Caltech Millimeter Array, revealing the large extent of the extranuclear region of star formation (the "overlap region"), which dominates the CO emission from this system.
Abstract: We present new aperture synthesis CO maps of the Antennae (NGC 4038/39) obtained with the Caltech Millimeter Array. These sensitive images show molecular emission associated with the two nuclei and a partial ring of star formation to the west of NGC 4038, as well as revealing the large extent of the extranuclear region of star formation (the "overlap region"), which dominates the CO emission from this system. The largest molecular complexes have masses of × 108 M☉, typically an order of magnitude larger than the largest structures seen to date in more quiescent galaxy disks. The extremely red luminous star clusters identified previously with the Hubble Space Telescope are well correlated with the CO emission, which supports the conclusion that they are highly embedded young objects rather than old globular clusters. There is an excellent correlation between the CO emission and the 15 μm emission seen with the Infrared Space Observatory, particularly for the brightest regions. The most massive complexes in the overlap region have similar [Ne III]/[Ne II] ratios, which implies that all these regions are forming many massive stars. However, only the brightest mid-infrared peak shows strong, rising continuum emission longward of 10 μm, indicative of very small dust grains heated to high temperatures by their proximity to nearby luminous stars. Since these grains are expected to be removed rapidly from the immediate environment of the massive stars, it is possible that this region contains very young (<1 Myr) sites of star formation. Alternatively, fresh dust grains could be driven into the sphere of influence of the massive stars, perhaps by the bulk motions of two giant molecular complexes. The kinematics and morphology of the CO emission in this region provide some support for this second scenario.

Journal ArticleDOI
Heinrich Dr. Horacek1, Stefan Pieh1
TL;DR: A review of recent developments in the applications and actions of intumescent fire-retardance is given in this paper, where the Berthelot number is defined as the product of heat of vaporization or decomposition and volume of gases evolved.
Abstract: A review of recent developments in the applications and actions of intumescent fire-retardance is given. An attempt has been made to classify the main systems of importance such as melamine, ammonium polyphosphate, melamine phosphate, pentaerythritol phosphate, sodium silicate, vermiculite, expandable graphite and microbeads. They are defined in terms of the Berthelot number which is the product of heat of vaporization or decomposition and volume of gases evolved. In principle, only two kinds of gases are produced from this group, namely water vapour and ammonia (from melamine). The heats of decomposition are readily calculated from heats of formation. An important aspect which is not included in the Berthelot number is the ignition residue in the shape of glassy foam or a cellular enamel.

Journal ArticleDOI
TL;DR: The photon tagging beamline installed in experimental Hall B at the Thomas Jefferson National Accelerator Facility (JLab) is described in this paper, where a single dipole magnet is combined with a hodoscope containing two planar arrays of plastic scintillators to detect energy-degraded electrons from a thin bremsstrahlung radiator.
Abstract: We describe the design and commissioning of the photon tagging beamline installed in experimental Hall B at the Thomas Jefferson National Accelerator Facility (JLab). This system can tag photon energies over a range from 20% to 95% of the incident electron energy, and is capable of operation with beam energies up to 6.1 GeV. A single dipole magnet is combined with a hodoscope containing two planar arrays of plastic scintillators to detect energy-degraded electrons from a thin bremsstrahlung radiator. The first layer of 384 partially overlapping small scintillators provides photon energy resolution, while the second layer of 61 larger scintillators provides the timing resolution necessary to form a coincidence with the corresponding nuclear interaction triggered by the tagged photon. The definitions of overlap channels in the first counter plane and of geometric correlation between the two planes are determined using digitized time information from the individual counters. Auxiliary beamline devices are briefly described, and performance results to date under real operating conditions are presented. The entire photon-tagging system has met or exceeded its design goals.

Journal ArticleDOI
TL;DR: The enantioselective outcome of transfer hydrogenation reactions that are catalysed by ruthenium(II) amino alcohol complexes was studied by means of a systematically varied series of ligands and it was found that both the substituent at the 1-position in the 2-amino-1-alcohol ligand and the substitution at the amine functionality influence the enantiOSElectivity of the reaction to a large extent.
Abstract: The enantioselective outcome of transfer hydrogenation reactions that are catalysed by ruthenium(II) amino alcohol complexes was studied by means of a systematically varied series of ligands. It was found that both the substituent at the 1-position in the 2-amino-1-alcohol ligand and the substituent at the amine functionality influence the enantioselectivity of the reaction to a large extent: enantioselectivities (ee values) of up to 95 % were obtained for the reduction of acetophenone. The catalytic cycle of ruthenium(II) amino alcohol catalysed transfer hydrogenation was examined at the density functional theory level. The formation of a hydrogen bond between the carbonyl functionality of the substrate and the amine proton of the ligand, as well as the formation of an intramolecular H⋅⋅⋅H bond and a planar H-Ru-NH moiety are crucially important for the reaction mechanism. The enantioselective outcome of the reaction can be illustrated with the aid of molecular modelling by the visualisation of the steric interactions between the ketone and the ligand backbone in the ruthenium(II) catalysts.

Journal ArticleDOI
TL;DR: A polyphasic approach, including classical phenotyping, whole-cell protein electrophoresis, 16 and 23S r DNA RFLP, 16S rDNA sequence analysis, and DNA-DNA reassociation analysis, was used for the identification of the dominant Leuconostoc species.
Abstract: Lactic acid bacteria (LAB) associated with gaseous spoilage of modified-atmosphere-packaged, raw, tomato-marinated broiler meat strips were identified on the basis of a restriction fragment length polymorphism (RFLP) (ribotyping) database containing DNAs coding for 16S and 23S rRNAs (rDNAs). A mixed LAB population dominated by a Leuconostoc species resembling Leuconostoc gelidum caused the spoilage of the product. Lactobacillus sakei, Lactobacillus curvatus, and a gram-positive rod phenotypically similar to heterofermentative Lactobacillus species were the other main organisms detected. An increase in pH together with the extreme bulging of packages suggested a rare LAB spoilage type called "protein swell." This spoilage is characterized by excessive production of gas due to amino acid decarboxylation, and the rise in pH is attributed to the subsequent deamination of amino acids. Protein swell has not previously been associated with any kind of meat product. A polyphasic approach, including classical phenotyping, whole-cell protein electrophoresis, 16 and 23S rDNA RFLP, 16S rDNA sequence analysis, and DNA-DNA reassociation analysis, was used for the identification of the dominant Leuconostoc species. In addition to the RFLP analysis, phenotyping, whole-cell protein analysis, and 16S rDNA sequence homology indicated that L. gelidum was most similar to the spoilage-associated species. The two spoilage strains studied possessed 98.8 and 99.0% 16S rDNA sequence homology with the L. gelidum type strain. DNA-DNA reassociation, however, clearly distinguished the two species. The same strains showed only 22 and 34% hybridization with the L. gelidum type strain. These results warrant a separate species status, and we propose the name Leuconostoc gasicomitatum sp. nov. for this spoilage-associated Leuconostoc species.

Journal ArticleDOI
TL;DR: It was found that, for growth on glucose, ethanol, and acetate, the flux partitioning around these nodes differed significantly, but this had hardly any effect on penicillin productivity, showing that primary carbon metabolism is not likely to contain potential bottlenecks.
Abstract: A detailed stoichiometric model was developed for growth and penicillin-G production in Penicillium chrysogenum. From an a priori metabolic flux analysis using this model it appeared that penicillin production requires significant changes in fluxes through the primary metabolic pathways. This is brought about by the biosynthesis of carbon precursors for the β-lactan nucleus and an increased demand for NADPH, mainly for sulfate reduction. As a result, significant changes in flux partitioning occur around four principal nodes in primary metabolism. These are located at: (1) glucose-6-phosphate; (2) 3-phosphoglycerate; (3) mitochondrial pyruvate; and (4) mitochondrial isocitrate. These nodes should be regarded as potential bottlenecks for increased productivity. The flexibility of these principal nodes was investigated by experimental manipulation of the fluxes through the central metabolic pathways using a high-producing strain of P. chrysogenum. Metabolic fluxes were manipulated through growth of the cells on different substrates in carbon-limited chemostat culture. Metabolic flux analysis, based on measured input and output fluxes, was used to calculate the fluxes around the principal nodes. It was found that, for growth on glucose, ethanol, and acetate, the flux partitioning around these nodes differed significantly. However, this had hardly any effect on penicillin productivity, showing that primary carbon metabolism is not likely to contain potential bottlenecks. Further experiments were performed to manipulate the total metabolic demand for the cofactor nicotinamide adenine dinucleotide phosphate (NADPH). NADPH demand was increased stepwise by cultivating the cells on glucose or xylose as the carbon source combined with either ammonia or nitrate as the nitrogen source, which resulted in a stepwise decrease of penicillin production. This clearly shows that, in penicillin fermentation, possible limitations in primary metabolism reside in the supply/regeneration of cofactors (NADPH) rather than in the supply of carbon precursors. © 2000 John Wiley & Sons, Inc. Biotechnol Bioeng 68: 602–618, 2000.

Journal ArticleDOI
C. Adloff, H. Henschel, Wolfram Erdmann1, P. Dixon2  +339 moreInstitutions (27)
TL;DR: In this article, cross sections for elastic photoproduction of J / ψ and ϒ mesons are presented, and the energy dependence on the photon-proton center-of-mass energy W γp is analyzed in an extended range with respect to previous measurements of 26≤W −1 ≤ 285 GeV.

Journal ArticleDOI
TL;DR: In this paper, the masses of 31 neutron-rich nuclei in the range A = 29-47 have been measured and the precision of 19 masses has been significantly improved and 12 masses were measured for the first time.
Abstract: The masses of 31 neutron-rich nuclei in the range A = 29-47 have been measured. The precision of 19 masses has been significantly improved and 12 masses were measured for the first time. The neutron-rich Cl, S, and P isotopes are seen to exhibit a change in shell structure around N = 28. Comparison with shell model and relativistic mean field calculations demonstrate that the observed effects arise from deformed prolate ground state configurations associated with shape coexistence. Evidence for shape coexistence is provided by the observation of an isomer in 43S.

Journal ArticleDOI
TL;DR: In this paper, the effect of the applied field orientation relative to the substrate surface on the magnetization curves of cobalt nanocrystals has been investigated and compared to a volumic random distribution of nanocrystal at vanishing concentration.
Abstract: Numerical calculations of magnetization curves versus applied field based on a simple model taking into account dipolar interactions were performed for cobalt nanocrystals deposited on a substrate and organized in a hexagonal network. A random distribution of the easy axes orientations of the nanocrystals is considered. The study is focused on the effect of the applied field orientation relative to the substrate surface. Two orientations were chosen: parallel and perpendicular to the surface. The corresponding hysteresis loops are compared to that of a volumic random distribution of nanocrystals at vanishing concentration. The calculation results are compared to experimental data for spherical cobalt nanocrystals coated by lauric acid $({\mathrm{C}}_{12}{\mathrm{H}}_{25}{\mathrm{COO}}^{\mathrm{\ensuremath{-}}}).$ The particles are either dispersed in hexane (considered as randomly distributed) or deposited in a hexagonal network on a highly oriented pyrolithic graphite substrate. The changes in the magnetization curves with the applied field orientation on the one hand and when going from dispersed to deposited particles on the other hand were calculated and measured. Qualitative agreement is obtained.

Journal ArticleDOI
01 Sep 2000-Tellus B
TL;DR: In this paper, the authors report on results from a World Climate Research Program workshop on representations of scavenging and deposition processes in global transport models of the atmosphere and provide a survey on the simulation diVerences between models.
Abstract: We report on results from a World Climate Research Program workshop on representations of scavenging and deposition processes in global transport models of the atmosphere. 15 models were evaluated by comparing simulations of radon, lead, sulfur dioxide, and sulfate against each other, and against observations of these constituents. This paper provides a survey on the simulation diVerences between models. It identifies circumstances where models are consistent with observations or with each other, and where they diVer from observations or with each other. The comparison shows that most models are able to simulate seasonal species concentrations near the surface over continental sites to within a factor of 2 over many regions of the globe. Models tend to agree more closely over source (continental) regions than for remote (polar and oceanic) regions. Model simulations diVer most strongly in the upper troposphere for species undergoing wet scavenging processes. There are not a suYcient number of observations to characterize the climatology (long-term average) of species undergoing wet scavenging in the upper troposphere. This highlights the need for either a diVerent strategy for model evaluation (e.g., comparisons on an event by event basis) or many more observations of a few carefully chosen constituents.

Journal ArticleDOI
TL;DR: In this article, the effect of substitution in the aromatic ring of N-hydroxyphthalimide on the oxidation of ethylbenzene has been studied and shown that removing substituents can accelerate the oxidation and promote the formation of acetophenone.

Journal ArticleDOI
TL;DR: Analysis of mycelium harvested from liquid-grown cultures by transmission electron microscopy showed that septum formation had strongly increased in ssgA-overexpressing strains in comparison to wild-type S. coelicolor and that spore-like compartments were produced at high frequency, which underline the important role for ssGA in Streptomyces cell division.
Abstract: The role of ssgA in cell division and development of streptomycetes was analyzed. An ssgA null mutant of Streptomyces coelicolor produced aerial hyphae but failed to sporulate, and ssgA can therefore be regarded as a novel whi gene. In addition to the morphological changes, antibiotic production was also disturbed, with strongly reduced actinorhodin production. These defects could be complemented by plasmid-borne ssgA. In the wild-type strain, transcription of ssgA was induced by nutritional shift-down and was shown to be linked to that of the upstream-located gene ssgR, which belongs to the family of iclR-type transcriptional regulator genes. Analysis of mycelium harvested from liquid-grown cultures by transmission electron microscopy showed that septum formation had strongly increased in ssgA-overexpressing strains in comparison to wild-type S. coelicolor and that spore-like compartments were produced at high frequency. Furthermore, the hyphae were significantly wider and contained irregular and often extremely thick septa. These data underline the important role for ssgA in Streptomyces cell division.

Journal ArticleDOI
TL;DR: In this paper, almost-simultaneous detections of Cygnus X-1 in the radio and mm regimes, obtained during the low/hard X-ray state, were presented.
Abstract: We present almost-simultaneous detections of Cygnus X-1 in the radio and mm regimes, obtained during the low/hard X-ray state. The source displays a flat spectrum between 2 and 220 GHz, with a spectral index |α|0.15 (3σ). There is no evidence for either a low- or high-frequency cut-off, but in the mid-infrared (∼30 μm) thermal emission from the OB-type companion star becomes dominant. The integrated luminosity of this flat-spectrum emission in quiescence is 2×1031 erg s−1 (2×1024 W). Assuming the emission originates in a jet for which non-radiative (e.g. adiabatic expansion) losses dominate, this is a very conservative lower limit on the power required to maintain the jet. A comparison with Cyg X-3 and GRS 1915+105, the other X-ray binaries for which a flat spectrum at shorter than cm wavelengths has been observed, shows that the jet in Cyg X-1 is significantly less luminous and less variable, and is probably our best example to date of a continuous, steady, outflow from an X-ray binary. The emissive mechanism responsible for such a flat spectral component remains uncertain. Specifically, we note that the radio–mm spectra observed from these X-ray binaries are much flatter than those of the ‘flat-spectrum’ AGN, and that existing models of synchrotron emission from partially self-absorbed radio cores, which predict a high-frequency cut-off in the mm regime, are not directly applicable.

Journal ArticleDOI
M Trotta1
TL;DR: The fusion-fission cross sections of the 4He+238U and 6He+ 238U systems have been measured, at Louvain-la-Neuve, for energies around and below the Coulomb barrier, using an array of Si detectors surrounding a UF4 target.
Abstract: The fusion-fission cross sections of the He-4 + U-238 and He-6 + U-238 systems have been measured, at Louvain-la-Neuve, for energies around and below the Coulomb barrier, using an array of Si detectors surrounding a UF4 target. The data taken with 4He are in good agreement with previous data and with the coupled channel fusion calculation performed with ECIS. The He-6 data show a regular trend with a large enhancement below the barrier which is attributed to the halo structure of the He-6 nucleus.

Journal ArticleDOI
TL;DR: In this paper, a methodology for spatially resolved spectroscopy of extended sources, adapted to XMM background and vignetting characteristics, was proposed to correct for particle induced background.
Abstract: Using the PV observation of A1795, we illustrate the capability of XMM-EPIC to measure cluster temperature profiles, a key ingredient for the determination of cluster mass profiles through the equation of hydrostatic equilibrium. We develop a methodology for spatially resolved spectroscopy of extended sources, adapted to XMM background and vignetting characteristics. The effect of the particle induced background is discussed. A simple unbiased method is proposed to correct for vignetting effects, in which every photon is weighted according to its energy and location on the detector. We were able to derive the temperature profile of A1795 up to 0.4 times the virial radius. A significant and spatially resolved drop in temperature towards the center (r<200 kpc) is observed, which corresponds to the cooling flow region of the cluster. Beyond that region, the temperature is constant with no indication of a fall-off at large radii out to 1.2 Mpc.

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TL;DR: In this article, the synthesis of macrocyclic and acyclic cleft-like anion receptors in which four hydrogen bond donating urea moieties are present in a preorganized fashion is described.

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C. Afonso1, C. Alard, J. N. Albert2, Johannes Andersen3, R. Ansari2, Éric Aubourg1, P. Bareyre4, P. Bareyre1, F. Bauer1, J. P. Beaulieu, A. Bouquet4, S. Char5, X. Charlot1, F. Couchot2, Ch. Coutures1, F. Derue2, Roger Ferlet6, J. F. Glicenstein1, Bertrand Goldman, Andrew Gould, David S. Graff1, David S. Graff7, M. Gros1, J. Haissinski2, Jean-Christophe Hamilton4, D. Hardin1, J. de Kat1, A. Kim4, T. Lasserre1, É. Lesquoy1, C. Loup6, Christophe Magneville1, J. B. Marquette6, E. Maurice, A. Milsztajn1, M. Moniez2, Nathalie Palanque-Delabrouille1, O. Perdereau2, L. Prevot, N. Regnault2, J. Rich1, Michel Spiro1, Alfred Vidal-Madjar6, L. Vigroux1, S. Zylberajch1, Charles Alcock8, Charles Alcock9, R. A. Allsman10, David R. Alves, Tim Axelrod10, A. C. Becker, K. H. Cook9, Andrew J. Drake10, Kenneth C. Freeman10, Kim Griest8, Kim Griest11, L. J. King, Matthew J. Lehner12, S. L. Marshall9, Dante Minniti9, Bruce A. Peterson13, M. R. Pratt14, Peter J. Quinn15, A. W. Rodgers10, Peter B. Stetson16, Christopher W. Stubbs8, Christopher W. Stubbs17, William J. Sutherland18, A. B. Tomaney17, T. Vandehei11, T. Vandehei8, S. H. Rhie19, David P. Bennett, P. C. Fragile19, Bradley R. Johnson20, J. Quinn19, Andrzej Udalski21, M. Kubiak21, Michał K. Szymański21, Grzegorz Pietrzyński21, P. R. Woźniak22, K. Zebrun21, Michael D. Albrow23, J. A. R. Caldwell, Darren L. DePoy7, Martin Dominik24, B. S. Gaudi7, J. G. Greenhill25, K. Hill25, Stephen R. Kane13, R. M. Martin, J. W. Menzies23, R. M. Naber24, Richard W. Pogge7, K. R. Pollard23, Penny D. Sackett24, Kailash C. Sahu13, P. Vermaak, R. D. Watson25, Andrew Williams 
TL;DR: In this article, the authors fit the data for the binary lens microlensing event MACHO 98-SMC-1 from five different micro-lensing collaborations and find two distinct solutions characterized by binary separation d and mass ratio q: (d,q) = (0.54,0.50) and q = (3.65, 0.36), where d is in units of the Einstein radius.
Abstract: We fit the data for the binary lens microlensing event MACHO 98-SMC-1 from five different microlensing collaborations and find two distinct solutions characterized by binary separation d and mass ratio q: (d,q) = (0.54,0.50) and (d,q) = (3.65,0.36), where d is in units of the Einstein radius. However, the relative proper motion of the lens is very similar in the two solutions, 1.30 km s-1 kpc-1 and 1.48 km s-1 kpc-1, thus confirming that the lens is in the Small Magellanic Cloud. The close binary can be either rotating or approximately static but the wide binary must be rotating at close to its maximum allowed rate to be consistent with all the data. We measure limb-darkening coefficients for five bands ranging from I to V. As expected, these progressively decrease with rising wavelength. This is the first measurement of limb darkening for a metal-poor A star.

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Rolf A. T. M. van Benthem1
TL;DR: In this paper, DSM developed a new type of hyperbranched polyesteramides derived from cyclic carboxylic anhydrides and dialkanolamines.