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Showing papers by "Eindhoven University of Technology published in 1978"


Journal ArticleDOI
TL;DR: In this article, the Wigner distribution function of an optical signal appears to be in close resemblance to the ray concept in geometrical optics, and this resemblance reaches even farther: although derived from Fourier optics, the WIGNer distribution functions of some elementary optical systems can directly be interpreted in terms of geometry.

375 citations


Journal ArticleDOI
TL;DR: In this paper, a carbenium ion-based mechanism was proposed for the conversion of methanol and ethanol to branched aliphatics on a synthetic zeolite of the type H-ZSM-5.

285 citations


Journal ArticleDOI
TL;DR: In this paper, the authors measured 1/f noise in samples with lattice and impurity scattering, and showed that lattice scattering gives 1/ε noise, while impurity scatter gives 1 ε noise.

232 citations


Journal ArticleDOI
TL;DR: In this article, the structure of molybdenum and cobalt species present in CoMo γ-Al 2 O 3 (Co Mo atomic ratio, 0.64) catalyst systems was analyzed using laser Raman spectroscopy.

164 citations


Journal ArticleDOI
TL;DR: In this paper, it is shown that all these models are special cases of a new model which is a straightforward generalization of the 1-D case, and under certain conditions the existence of a stabilizing feedback is shown.
Abstract: During recent years several state-space models concerning discrete 2-D systems (systems with two time parameters) have appeared in the literature. These are used, for example, in image processing. To these models are attached the names of Attasi [1], Fornasini-Marchesini [2], Givone-Roesser [3]. In this paper it is shown that all these models are special cases of a new model which is a straightforward generalization of the 1-D case. Under certain conditions the existence of a stabilizing feedback is shown. In the last part connections with [4] are made.

163 citations


Journal ArticleDOI
TL;DR: In this article, the retention behavior of carboxylic acids in reversed-phase and reversed phase ion-pair choromatography on hydrophobic alkyl-modified silica gel was investigated.

127 citations


Journal ArticleDOI
TL;DR: In this article, the authors compared three types of liquid chromatographic detectors: tubular, packed bed and gas-segmented liquid flow systems, and gave some specific instrumental problems (mixing, noise level) for optimal design.

103 citations


Journal ArticleDOI
TL;DR: In this paper, the isothermal cross sections through the ternary phase diagram were investigated by means of the diffusion couple technique and the results were corroborated on essential points by the investigation of equilibrated alloys.
Abstract: We have investigated the isothermal cross sections through the ternary phase diagram Tiz.sbnd;Niz.sbnd;Cu at 800 and 870 °C by means of the diffusion couple technique. The results have been corroborated on essential points by the investigation of equilibrated alloys. Use has been made of optical, microprobe a nd X-ray analyses. The results differ from those mentioned in the literature. For two hitherto undescribed ternary intermetallic compounds X-ray diffraction data are given and crystallographic cell parameters are proposed.

98 citations


Journal ArticleDOI
TL;DR: In this article, it is shown that an explicit form for the dynamical equation of state may be obtained if in the neighbourhood of some state of thermodynamic equilibrium it is permissible to consider the equilibrium pressure and the thermodynamic affinities (conjugate to the internal degrees of freedom) as linear functions of ν, T and the internal variables and if, moreover, the phenomenological coefficients which occur in the equations for the irreversible processes, may be considered as constants.
Abstract: In this paper we investigate the relation (dynamical equation of state) among the (mechanical hydrostatic) pressure P , the volume ν and the temperature T of an isotropic medium with an arbitrary number, say n , of scalar internal degrees of freedom. It is assumed that the irreversible processes in the medium are due to volume viscosity and to changes in the internal variables and that these processes can be described with the aid of non-equilibrium thermodynamics. It is shown that an explicit form for the dynamical equation of state may be obtained if in the neighbourhood of some state of thermodynamic equilibrium it is permissible to consider the equilibrium pressure and the thermodynamic affinities (conjugate to the internal degrees of freedom) as linear functions of ν, T and the internal variables and if, moreover, the phenomenological coefficients, which occur in the equations for the irreversible processes, may be considered as constants. This dynamical equation of state has the form of a linear relation among P , ν, T , the first n derivatives with respect to time of P and of T and the first n +1 derivatives with respect to time of ν.

72 citations


Journal ArticleDOI
TL;DR: In this paper, the thickness of the diffusion layer was determined as a function of the volume rate of the gas evolution for both hydrogen and oxygen evolving electrodes in alkaline solution, and it was concluded from the experimental results that the mass transfer can be explained on the basis of the hydrodynamic model when no coalescence of gas bubbles occurs and on that of the penetration model when coalescence occurs frequently.

71 citations


Journal ArticleDOI
TL;DR: A simple definition of generalized quadratic residue codes, that is, quadratics residue codes of block length p^{m} , is given and an account of many of their properties is presented.
Abstract: A simple definition of generalized quadratic residue codes, that is, quadratic residue codes of block length p^{m} , is given, and an account of many of their properties is presented.

Journal ArticleDOI
TL;DR: In this paper, an algorithm for counting exactly internal molecular energy levels is described and the influence of anharmonicity is discussed and it is shown that reliable densities can only be obtained for low energies if anharmony constants are used.

Journal ArticleDOI
TL;DR: In this paper, five different signals have been analyzed in ESR spectra obtained from sulfided molybdenum- or tungsten-containing catalyst samples, and they have been attributed to paramagnetic surface species in the MoS2 and WS2 phases.

Journal ArticleDOI
TL;DR: In this article, a new deactivation method for glass capillary columns is described, where vapours of PEG 20M are bled from a short pre-column on to the capillary column and act as the deactivating agent.

Journal ArticleDOI
TL;DR: In this article, the amount of adsorbed sodium ions in the compact part of the electrical double layer of the vitreous silica electrolyte interface has been estimated at pH 10 with the aid of a sodium-24 and bromide-82 tracer.

Journal ArticleDOI
TL;DR: A survey of applications of system and parameter identification methods to biological systems, including cardiovascular, respiratory, neural, renal, metabolic, skeletal and other systems, is presented.

Journal ArticleDOI
TL;DR: In this paper, the authors reviewed the existing methods of calculating monomer reactivity ratios in copolymerization and classified them according to their mathematical and computational similarities, and showed that the actual error structure of the variables corresponds to the assumed error structure.
Abstract: Existing methods of calculating monomer reactivity ratios in copolymerization are reviewed briefly, evaluated, and classified according to their mathematical and computational similarities. More attention is paid to procedures based on the integrated copolymer equation with which calculation of r values is performed most often by electronic computer. Unfortunately, until now all procedures have shown shortcomings because the real-error structure of the observations has not been taken into account. A new algorithm that does account correctly for measurement errors in both variables is described. A computational method is illustrated for copolymerization data obtained from quantitative gas chromatographic analysis of the monomer feed throughout the reaction. It is shown that the actual error structure of the variables corresponds to the assumed error structure. Reliability of the estimates is substantially increased, compared with the existing methods. Standard deviations of the monomer reactivity ratios are given and appear to be in good agreement with reality.

Journal ArticleDOI
TL;DR: In this paper, a theory for Van der Pauw structures with contacts of non-zero lengths which are invariant for rotations of 90° was given. And a general theorem has been derived.
Abstract: A theory is given for Van der Pauw structures with contacts of non-zero lengths which are invariant for rotations of 90°. A general theorem has been derived. For a certain class of structures an analytical solution of the Laplace equation is obtained instead of using finite difference equations. The method leans heavily on Schwarz-Christoffel transformation techniques.

Journal ArticleDOI
TL;DR: In this paper, a short-cut calculation method is developed for Biot numbers larger than 10, initial homogeneous product temperatures equal to or larger than the temperature of the cooling medium and for the main container geometries including spheres, cylinders and rectangular bodies.
Abstract: Based on analytical equations for the temperature distribution history in a container, the relation between the reductions of the concentrations of heat labile food components, including microorganisms. nutrients and sensory factors, and the kinetic parameters of the reactions causing these reductions, has been calculated numerically. For a constant temperature of the heating medium with time it is concluded that the loss of quality is almost minimal at one Fourier value of the heating time. This optimal Fourier value is a function of only the Biot number and the relationship between initial product temperature, cooling water temperature and retort temperature. At an infinite value of Biot and a cooling water temperature equal to the initial product temperature the optimum Fourier value amounts to 0.5. On the basis of this conclusion a short-cut calculation method is developed. The method is valid for Biot numbers larger than 10, initial homogeneous product temperatures equal to or larger than the temperature of the cooling medium and for the main container geometries including spheres, cylinders and rectangular bodies. The method does not require tedious interpolations of tables. The calculation of the optimum process conditions to obtain the desired sterility and the calculation of the retention of the quality factor of interest require only a few minutes on a pocket calculator. For routine calculations the procedure can conveniently be programmed.

Journal ArticleDOI
TL;DR: The influence of pressure on water flow towards an ice front, located above a glass filter, was investigated experimentally at temperatures in the range from 0 to −0.05°C.


Journal ArticleDOI
TL;DR: In this article, the anomalous field dependence of the N ¼ eel temperature for a system of loosely coupled classical Heisenberg chains with orthorhombic anisotropy for different directions of the applied magnetic field was analyzed.
Abstract: We present the first theoretical results on the anomalous field dependence of the N\'eel temperature for a system of loosely coupled classical Heisenberg chains with orthorhombic anisotropy for different directions of the applied magnetic field. The results compare favorably with the experimental phase diagrams of a series of selected $S=\frac{5}{2}$ compounds with varying degrees of one dimensionality and anisotropy.

Journal ArticleDOI
TL;DR: In this paper, the reliability of qualitative and quantitative head-space gas analysis of parts per billion * amounts of hydrocarbons in aqueous samples was studied on model systems by capillary-column gas chromatography.

Journal ArticleDOI
TL;DR: Application of the method to urine samples of patients with various endocrine disorders is included and preliminary results are given on the reproducibility of the derivatization procedure (formation of methoxime-trimethylsilyl (MO-TMS) ethers), the gas chromatographic analysis and the whole method.

Journal ArticleDOI
TL;DR: In this paper, the 1/ε voltage noise was shown to be proportional to the square of the bias voltage for both planar and hemispherical geometry, respectively, in the SCLC regime, where the current is proportional to V2 and V 3 2, respectively.
Abstract: 1/ƒ noise calculations and experiments are presented for solid state single injection diodes operating in the ohmic and space-charge-limited current (SCLC) regime. Investigations are performed on diodes both with a planar and with a hemispherical geometry. In the ohmic regime the 1/ƒ voltage noise is proportional to the square of the bias voltage V for both geometrics. In the space-charge regime the 1/ƒ voltage noise is theoretically found to be proportional to V and V 3 4 for planar and hemispherical geometry, respectively. Here the current is proportional to V2 and V 3 2 , respectively. The experiment al results of 1/ƒ voltage noise are found to be in agreement with the calculations for both kinds of geometry.

Journal ArticleDOI
TL;DR: In this paper, a model describing the low-frequency current noise in metal-insulator-metal diodes is presented, where the transmission coefficient is modulated by the Nyquist noise of the insulator.
Abstract: A model describing the low-frequency current noise in metal-insulator-metal diodes is presented. It is assumed that the transmission coefficient is modulated by the Nyquist noise of the insulator. This coefficient in turn modulates the current. The frequency dependence of the noise is calculated to be ƒ −α , where α depends on the impedance of the insulator and can have the values 0 or 1 or 2. The model is compared with experimental results, and the agreement is found to be satisfactory.

Journal ArticleDOI
TL;DR: In this paper, the influence of several model extensions such as recombination via excited states, the presence of a trap distribution, donor-acceptor pair recombination, presence of additional centres, temperature dependent rate parameters, thermal quenching of luminescence and scattering due to ionized defect centres on TSL and TSC curves was investigated.

01 Jan 1978
TL;DR: The final author version and the galley proof are versions of the publication after peer review and the final published version features the final layout of the paper including the volume, issue and page numbers.

Journal ArticleDOI
TL;DR: A summary is given of the issues and conclusions of the round-table discussions on ‘Economic evaluation of computer control’, ‘Ergonomic aspects’ and ‘Application of “Modern Control Theory” to Computer Control in the Process Industry’.