Institution
Environmental Molecular Sciences Laboratory
Facility•Richland, Washington, United States•
About: Environmental Molecular Sciences Laboratory is a facility organization based out in Richland, Washington, United States. It is known for research contribution in the topics: Mass spectrometry & X-ray photoelectron spectroscopy. The organization has 1471 authors who have published 3010 publications receiving 169961 citations.
Topics: Mass spectrometry, X-ray photoelectron spectroscopy, Fourier transform ion cyclotron resonance, Ab initio, Proteome
Papers published on a yearly basis
Papers
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TL;DR: In this paper, a review of small boron clusters as individual species in the gas phase is presented, and the planarity of the species has been further elucidated on the basis of multiple aromaticity, multiple antiaromaticity, and conflicting aromaticity.
552 citations
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TL;DR: In this article, a review of recent work on the growth of select, representative oxides that span the ranges of crystal structure, metal oxidation state, and stoichiometry is reviewed and used to illustrate the basic materials science.
551 citations
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TL;DR: In situ transmission electron microscopy is used to study the electrochemical lithiation of high-capacity crystalline Si nanoparticles for use in Li-ion battery anodes, and analysis suggests that this behavior is due to diffusion limitation but instead to the influence of mechanical stress on the driving force for reaction.
Abstract: In situ transmission electron microscopy (TEM) is used to study the electrochemical lithiation of high-capacity crystalline Si nanoparticles for use in Li-ion battery anodes. The lithiation reaction slows down as it progresses into the particle interior, and analysis suggests that this behavior is due not to diffusion limitation but instead to the influence of mechanical stress on the driving force for reaction.
540 citations
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TL;DR: In this article, a localized high-concentration electrolyte (LHCE) was proposed to solve the viscosity and wettability issues of sulfone-based electrolytes.
522 citations
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TL;DR: In this article, a fluorinated orthoformate-based electrolyte was used to prevent dendritic Li formation and minimise Li loss and volumetric expansion in Li-metal batteries.
Abstract: Lithium (Li) pulverization and associated large volume expansion during cycling is one of the most critical barriers for the safe operation of Li-metal batteries. Here, we report an approach to minimize the Li pulverization using an electrolyte based on a fluorinated orthoformate solvent. The solid–electrolyte interphase (SEI) formed in this electrolyte clearly exhibits a monolithic feature, which is in sharp contrast with the widely reported mosaic- or multilayer-type SEIs that are not homogeneous and could lead to uneven Li stripping/plating and fast Li and electrolyte depletion over cycling. The highly homogeneous and amorphous SEI not only prevents dendritic Li formation, but also minimizes Li loss and volumetric expansion. Furthermore, this new electrolyte strongly suppresses the phase transformation of the LiNi0.8Co0.1Mn0.1O2 cathode (from layered structure to rock salt) and stabilizes its structure. Tests of high-voltage Li||NMC811 cells show long-term cycling stability and high rate capability, as well as reduced safety concerns. Parasitic reactions between Li metal and electrolytes need to be mitigated in Li-metal batteries. Here, the authors report the use of a fluorinated orthoformate-based electrolyte, leading to a monolithic solid–electrolyte interphase and subsequently a high-performance Li-metal battery.
512 citations
Authors
Showing all 1477 results
Name | H-index | Papers | Citations |
---|---|---|---|
George M. Whitesides | 240 | 1739 | 269833 |
Yi Cui | 220 | 1015 | 199725 |
Donald G. Truhlar | 165 | 1518 | 157965 |
Ronald W. Davis | 155 | 644 | 151276 |
Richard D. Smith | 140 | 1180 | 79758 |
Yuehe Lin | 118 | 641 | 55399 |
Robert C. Haddon | 112 | 577 | 52712 |
Lai-Sheng Wang | 103 | 576 | 36212 |
Mark H. Engelhard | 103 | 545 | 39864 |
Alex Guenther | 100 | 447 | 45476 |
Gordon E. Brown | 100 | 454 | 32152 |
X. Sunney Xie | 98 | 225 | 44104 |
Jun Li | 98 | 631 | 40958 |
Richard A. Friesner | 97 | 367 | 52729 |
Chongmin Wang | 95 | 451 | 33983 |