ExxonMobil

About: ExxonMobil is a company organization based out in Irving, Texas, United States. It is known for research contribution in the topics: Catalysis & Polymerization. The organization has 16969 authors who have published 23758 publications receiving 535713 citations. The organization is also known as: Exxon Mobil Corporation & Exxon Mobil Corp..

Method of cleaving semiconductor diode laser wafers

Abstract: Thick double heterostructure (Al,Ga)As wafers comprising layers of gallium arsenide and gallium aluminum arsenide on a metallized n-GaAs substrate are separated into individual devices for use as diode lasers. In contrast to prior art techniques employed with thinner wafers of mechanically cleaving the wafer in mutually orthogonal directions, the wafer is first separated into bars of diodes by a process which comprises (a) forming channels of substantially parallel sidewalls about 1 to 4 mils deep into the surface of the n-GaAs substrate (b) etching into the n-GaAs substrate with an anisotropic etchant to a depth sufficient to form V-grooves in the bottom of the channels and (c) mechanically cleaving into bars of diodes. The cleaving may be done by prior art techniques using a knife, razor blade or tweezer edge or by attaching the side of the wafer opposite to the V-grooves to a flexible adhesive tape and rolling the assembly in a manner such as over a tool of small radius. The diode bars may then, following passivation, be further cleaved into individual diodes by the prior art technique of mechanically scribing and cleaving. Processing in accordance with the invention results in good length definition and uniformity, high device yields and low density of striations on laser facets. The inventive process permits handling of thicker wafers on the order of 6 to 10 mils or so, which are cleaved only with great difficulty by prior art techniques. Such thicker wafers are less susceptible to breaking during handling and permit fabrication of shorter diode (cavity) length, which in turn is related to lower threshold current for device operation.

Genesis and characterization of dolomite, Arab-D Reservoir, Ghawar field, Saudi Arabia

Abstract: This study reports the results of an investigation into the nature, origin and significance of linear dolomite trends across the Arab-D reservoir in Ghawar field. In the course of this study, three distinct types of dolomite were identified based on petrographic and geochemical criteria: fabric-preserving (FP), non-fabric-preserving (NFP) and baroque dolomite. Fabric-preserving (FP) dolomite is very finely crystalline dolomite in which details of the original limestone fabric are usually well preserved. Beds of FP dolomite typically occur as thin, sheet-like or stratigraphic layers that are always intimately associated with the overlying anhydrite. This dolomite is interpreted to have formed very early in the diagenetic history of the sediment, by dense, highly evaporated magnesium-rich brines associated with the overlying anhydrite. In contrast, NFP dolomite is a medium crystalline, non-baroque dolomite in which all traces of the original limestone fabric have been obliterated. This dolomite also typically occurs as stratigraphic beds, although it is not restricted to the uppermost part of the Arab-D but occurs throughout the reservoir. The NFP dolomite is the most common type present in the reservoir, and is interpreted on the basis of its general geochemical similarity to the FP dolomites to have mostly formed from hypersaline fluids, although some NFP dolomite is thought to represent a transitional form with the third dolomite type, baroque dolomite. Strontium isotopic ratios suggest that both the FP and most of the NFP dolomite formed very early, at or shortly after deposition of the original sediment. The third type of dolomite, baroque, is a coarsely crystalline dolomite with “saddle-shaped” crystals displaying undulose extinction in thin section. It is rare in the reservoir and appears to be limited to wells that contain abnormally thick sections of dolomite; in extreme cases, baroque dolomite is vertically pervasive. Geochemically, baroque dolomite is distinctive with high iron and very low oxygen isotopic compositions, and is interpreted to have formed from high temperature fluids during burial diagenesis. These fluids are suggested to have ascended up into the reservoir from depth along a fault/facture system, relatively late in the diagenetic history of the rock.

Coated oil and gas well production devices

Abstract: Provided are coated oil and gas well production devices and methods of making and using such coated devices. In one form, the coated device includes one or more cylindrical bodies, hardbanding on at least a portion of the exposed outer surface, exposed inner surface, or a combination of both exposed outer or inner surface of the one or more cylindrical bodies, and a coating on at least a portion of the inner surface, the outer surface, or a combination thereof of the one or more cylindrical bodies. The coating includes one or more ultra-low friction layers, and one or more buttering layers interposed between the hardbanding and the ultra-low friction coating. The coated oil and gas well production devices may provide for reduced friction, wear, erosion, corrosion, and deposits for well construction, completion and production of oil and gas.

Hydrocarbon recovery from impermeable oil shales

Abstract: An economic method for in situ maturing and production of oil shale or other deep-lying, impermeable resources containing immobile hydrocarbons. Vertical fractures are created using horizontal or vertical wells. The same or other wells are used to inject pressurized fluids heated to less than approximately 370~ C, and to return the cooled fluid for reheating and recycling. The heat transferred to the oil shale gradually matures the kerogen to oil and gas as the temperature in the shale is brought up, and also promotes permeability within the shale in the form of small fractures sufficient to allow the shale to flow into the well fractures where the product is collected commingled with the heating fluid and separated out before the heating fluid is recycled.

NMR of platinum catalysts. I. Line shapes

Abstract: The authors report spin-echo NMR studies of $^{195}\mathrm{Pt}$ in small particles of Pt supported on alumina. For the samples studied, the fraction of Pt atoms on the surface (called the dispersion) ranged from 4% to 58%. The studies were at fields ${H}_{0}$ of 80 to 85 kG, frequency ${\ensuremath{ u}}_{0}=74$ MHz, and at a temperature of 77 K. The lines are broad (3-5 kG), requiring special methods which permit substantial signal averaging (\ensuremath{\sim} 50 000 echoes). In the low-dispersion (large-particle) samples, there is a strong absorption at the position of the $^{195}\mathrm{Pt}$ NMR in bulk Pt metal ($\frac{{H}_{0}}{{\ensuremath{ u}}_{0}}=1.138$ kG/MHz) which becomes progressively weaker as the particle size decreases. A peak which is near the $^{195}\mathrm{Pt}$ resonance in typical diamagnetic compounds ($\frac{{H}_{0}}{{\ensuremath{ u}}_{0}}\ensuremath{\sim}1.09$ kG/MHz) is found in samples which are coated with adsorbed molecules. It disappears when the surface is cleaned. The authors show that this peak arises from the surface layer of Pt atoms, and that its position ($\frac{{H}_{0}}{{\ensuremath{ u}}_{0}}$) shows that coating the Pt atoms on the surface largely ties up the electron spins of the surface Pt atoms in bonds. The exact position of this peak depends on the chemical species which is adsorbed. The authors show that when Pt is cleaned, then exposed to air for long times, the surface peak reveals that the surface has reconstructed to form Pt${(\mathrm{OH})}_{6}$.