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Institution

ExxonMobil

CompanyIrving, Texas, United States
About: ExxonMobil is a company organization based out in Irving, Texas, United States. It is known for research contribution in the topics: Catalysis & Polymer. The organization has 16969 authors who have published 23758 publications receiving 535713 citations. The organization is also known as: Exxon Mobil Corporation & Exxon Mobil Corp..
Topics: Catalysis, Polymer, Polymerization, Hydrocarbon, Alkyl


Papers
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Book ChapterDOI
TL;DR: In this article, the authors present a review for the series of Graphite Intercalation Compounds (R1), which was one of the four definitive articles to come out in 1959 and 1960 (HI, C1, U1), a period of intense activity in graphite research.
Abstract: Publisher Summary Twenty years ago, Walter Rudorff wrote a review for the series entitled “Graphite Intercalation Compounds” (R1). It was one of the four definitive articles to come out in 1959 and 1960 (HI, C1, U1), a period of intense activity in graphite research. One have now again reached the “fever pitch,” with not only the appearance of several new articles (E l , H2, W1), but also the convening of the first international conference dedicated exclusively to graphite compounds (H3 ). In the following, one shall concentrate on the work performed between 1974 and the present. The interlayer voids are frequently attacked to yield a periodic sequence of filled and empty spaces. The stage of a compound is defined as the ratio of host layers to guest layers, so that a first-stage compound, in which every interlayer void is filled, is the most concentrated. Historically, compounds of graphite have been placed in three categories, depending on the strength of interaction between the reacting species and graphite.

103 citations

Patent
28 Jan 2002
TL;DR: In this article, a dual metallocene catalyst system was proposed for crystalline propylene polymers with a broad, bimodal molecular weight distribution for use in the production of biaxially oriented films or non-oriented films.
Abstract: This invention relates generally to crystalline propylene polymers, to methods for their production and to methods for their use in film applications. Specifically, this invention relates to crystalline propylene polymers comprising both propylene homopolymer and propylene copolymer. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymer and copolymer using propylene with a small amount of comonomer, preferably ethylene. The polymerization is catalyzed by a dual metallocene catalyst system. The resulting polymers have a broad, bimodal molecular weight distribution. The resulting polymers are excellent for use in the production of biaxially oriented films or non-oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional propylene polymer.

103 citations

Journal ArticleDOI
TL;DR: A succession of eight high-frequency sequences, traced along dip for 500 km, reveal that modest climate shifts from relatively dry seasonal to relatively wet seasonal with a duration of several sequences (~600,000 to 1 million years) had a dominant impact on facies, sediment dispersal patterns, and sequence architecture as mentioned in this paper.
Abstract: Pennsylvanian glacioeustatic cyclothems exposed in Kansas and adjacent areas provide a unique opportunity to test models of the impact of relative sea level and climate on stratal architecture. A succession of eight of these high-frequency sequences, traced along dip for 500 km, reveal that modest climate shifts from relatively dry-seasonal to relatively wet-seasonal with a duration of several sequences (~600,000 to 1 million years) had a dominant impact on facies, sediment dispersal patterns, and sequence architecture. The climate shifts documented herein are intermediate, both in magnitude and duration, between previously documented longer-term climate shifts throughout much of the Pennsylvanian and shorter-term shifts described within individual sequences. Climate indicators are best preserved at sequence boundaries and in incised-valley fills of the lowstand systems tracts (LST). Relatively drier climate indicators include high-chroma paleosols, typically with pedogenic carbonates, and plant assemblages that are dominated by gymnosperms, mostly xerophytic walchian conifers. The associated valleys are small ( 4 km wide and >20 m deep), and dominated by quartz sandstones derived from distant source areas, reflecting large drainage networks. Transgressive systems tracts (TST) in all eight sequences generally are characterized by thin, extensive limestones and thin marine shales, suggesting that the dominant control on TST facies distribution was the sequestration of siliciclastic sediment in updip positions. Highstand systems tracts (HST) were significantly impacted by the intermediate-scale climate cycle in that HSTs from relatively drier climates consist of thin marine shales overlain by extensive, thick regressive limestones, whereas HSTs from relatively wetter climates are dominated by thick marine shales. Previously documented relative sea-level changes do not track the climate cycles, indicating that climate played a role distinct from that of relative sea-level change. These intermediate-scale modest climate shifts had a dominant impact on sequence architecture. This independent measure of climate and relative sea level may allow the testing of models of climate and sediment supply based on modern systems.

103 citations

Journal ArticleDOI
TL;DR: Measurements on the corresponding methoxy- and acetoxyquinones indicate that internal hydrogen bonding in the alpha-hydroxyquinones makes a major contribution to stabilisation of the semiquinone, probably as a result of increased delocalisation due to exchange of the hydroxy hydrogen between the two neighbouring oxygen atoms.

103 citations

Journal ArticleDOI
01 Jun 1981-Fuel
TL;DR: In this paper, coal combustion experiments were carried out over the temperature range 25-900 °C using air at atmospheric pressure in a derivative thermogravimetric analysis system. But the results showed that combustion rates increased progressively with increasing temperature, passed through maxima and then declined.

103 citations


Authors

Showing all 16987 results

NameH-indexPapersCitations
David A. Weitz1781038114182
Avelino Corma134104989095
Peter Hall132164085019
James A. Dumesic11861558935
Robert H. Crabtree11367848634
Costas M. Soukoulis10864450208
Nicholas J. Turro104113153827
Edwin L. Thomas10460640819
Israel E. Wachs10342732029
Andrew I. Cooper9938934700
Michael J. Zaworotko9751944441
Enrique Iglesia9641631934
Yves J. Chabal9451933820
George E. Gehrels9245430560
Ping Sheng9059337141
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Performance
Metrics
No. of papers from the Institution in previous years
YearPapers
20234
202236
2021302
2020340
2019366
2018438