ExxonMobil

About: ExxonMobil is a company organization based out in Irving, Texas, United States. It is known for research contribution in the topics: Catalysis & Polymerization. The organization has 16969 authors who have published 23758 publications receiving 535713 citations. The organization is also known as: Exxon Mobil Corporation & Exxon Mobil Corp..

Lake-type controls on petroleum source rock potential in nonmarine basins

Abstract: Based on numerous empirical observations of lacustrine basin strata, we propose a three-fold classification of lacustrine facies associations that accounts for the most important features of lacustrine petroleum source rocks and provides a predictive framework for exploration in nonmarine basins where lacustrine facies are incompletely delineated. (1) The fluvial-lacustrine facies association is characterized by freshwater lacustrine mudstones interbedded with fluvial-deltaic deposits, commonly including coal. Shoreline progradation dominates basin fill, resulting in the stacking of indistinctly expressed cycles up to 10 m thick. In map view, the deposits may be regionally widespread but laterally discontinuous and contain strong facies contrasts. Transported terrestrial organic matter contributes to mixed type I-III kerogens that generate waxy oil (type I kerogen is hydrogen rich and oil prone; type III kerogen is hydrogen poor and mainly gas prone). The Luman Tongue of the Green River Formation (Wyoming) and the Honyanchi Formation (Junggar basin, China) provide examples of this facies association, which is also present in the Songliao basin of northeastern China, the Central Sumatra basin, and the Cretaceous Doba/Doseo basins in west-central Africa. (2) The fluctuating profundal facies association represents a combination of progradational and aggradational basin fill and includes some of the world's richest source rocks. Deposits are regionally extensive in map view, having relatively homogenous source facies containing oil-prone, type I kerogen. Examples include the Laney Member of the Green River Formation (Wyoming), the Lucaogou Formation (Junggar basin, China), the Bucomazi Formation (offshore west Africa), and the Lagoa Feia Formation (Campos basin, Brazil). (3) The evaporative facies association represents dominantly aggradational fill related to desiccation cycles in saline to hypersaline lakes and may include evaporite and eolianite deposits. Sublittoral organic-rich mudstone facies are relatively thin but may be (Begin page 1034) quite rich and widespread. The highest organic enrichment coincides with the deepest lake stages. Low input of land plant organic matter results in minimal lateral contrasts in organic content. In some cases a distinctive type I-S (sulfur-rich) kerogen may generate oil at thermal maturities as low as 0.45% vitrinite reflectance equivalent. Examples include the Wilkins Peak Member of the Green River Formation (Wyoming), the Jingjingzigou Formation (Junggar basin, China), the Jianghan and Qaidam basins (China), and the Blanca Lila Formation (Argentina).

Transport in sandstone: A study based on three dimensional microtomography

Abstract: High resolution imaging of the microstructure of Fontainebleau sandstone allows a direct comparison between theoretical calculations and laboratory measurements. While porosity, pore-volume-to-surface ratio, permeability, and end point relative permeability are well predicted by our calculations, we find that electrical resistivity and wetting phase residual saturation are both overestimated.

Geometry of frictionless and frictional sphere packings

Abstract: We study static packings of frictionless and frictional spheres in three dimensions, obtained via molecular dynamics simulations, in which we vary particle hardness, friction coefficient, and coefficient of restitution. Although frictionless packings of hard spheres are always isostatic (with six contacts) regardless of construction history and restitution coefficient, frictional packings achieve a multitude of hyperstatic packings that depend on system parameters and construction history. Instead of immediately dropping to four, the coordination number reduces smoothly from $z=6$ as the friction coefficient $\ensuremath{\mu}$ between two particles is increased.

Ordered and curved meso-structures in membranes and amphiphilic films

Abstract: Curvature-induced instabilities in membranes and amphiphilic films are investigated by introducing a general coupling between a shape variable (such as curvature) and «internal» degrees of freedom (such as area per molecule, tilt angle, or local composition). A mean-field treatment of the Ginzburg-Landau free energy expansion shows the existence of various undulated phases (on a mesoscopic scale) that can appear between condensed (solid-like) and dilute (fluid-like) homogeneous phases of the membrane. These undulated phases are characterized by undulations in their local composition as well as in their local curvature. We find two types of undulated phases - stripe and hexagonal — and calculate the phase diagram for the system.

Development of a Detailed Gasoline Composition-Based Octane Model

Abstract: We present a model that predicts the research and motor octane numbers of a wide variety of gasoline process streams and their blends including oxygenates based on detailed composition. The octane number is correlated to a total of 57 hydrocarbon lumps measured by gas chromatography. The model is applicable to any gasoline fuel regardless of the refining process it originates from. It is based on the analysis of 1471 gasoline fuels from different naphtha process streams such as reformates, cat-naphthas, alkylates, isomerates, straight runs, and various hydroprocessed naphthas. Blends of these individual process streams are also considered in this work. The model predicts the octane number within a standard error of 1 number for both the research and motor octane numbers.