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Showing papers by "Florida State University published in 2006"


Journal ArticleDOI
15 Sep 2006-Science
TL;DR: This work introduced a method for optically imaging intracellular proteins at nanometer spatial resolution and used this method to image specific target proteins in thin sections of lysosomes and mitochondria and in fixed whole cells to image retroviral protein Gag at the plasma membrane.
Abstract: We introduce a method for optically imaging intracellular proteins at nanometer spatial resolution. Numerous sparse subsets of photoactivatable fluorescent protein molecules were activated, localized (to approximately 2 to 25 nanometers), and then bleached. The aggregate position information from all subsets was then assembled into a superresolution image. We used this method--termed photoactivated localization microscopy--to image specific target proteins in thin sections of lysosomes and mitochondria; in fixed whole cells, we imaged vinculin at focal adhesions, actin within a lamellipodium, and the distribution of the retroviral protein Gag at the plasma membrane.

7,924 citations


Journal ArticleDOI
TL;DR: A survey of the top three political science journals from 1998 to 2002 suggests that the execution of these models is often flawed and inferential errors are common as discussed by the authors, and that scholars follow the simple checklist of dos and don'ts for using multiplicative interaction models presented in this article.
Abstract: Multiplicative interaction models are common in the quantitative political science literature. This is so for good reason. Institutional arguments frequently imply that the relationship between political inputs and outcomes varies depending on the institutional context. Models of strategic interaction typically produce conditional hypotheses as well. Although conditional hypotheses are ubiquitous in political science and multiplicative interaction models have been found to capture their intuition quite well, a survey of the top three political science journals from 1998 to 2002 suggests that the execution of these models is often flawed and inferential errors are common. We believe that considerable progress in our understanding of the political world can occur if scholars follow the simple checklist of dos and don'ts for using multiplicative interaction models presented in this article. Only 10% of the articles in our survey followed the checklist.

5,235 citations


Journal ArticleDOI
TL;DR: The results showed that social support incrementally predicted satisfaction beyond motivational work characteristics but was not related to increased training and compensation requirements, which provides new insight into how to avoid the trade-offs commonly observed in work design research.
Abstract: Although there are thousands of studies investigating work and job design, existing measures are incomplete. In an effort to address this gap, the authors reviewed the work design literature, identified and integrated previously described work characteristics, and developed a measure to tap those work characteristics. The resultant Work Design Questionnaire (WDQ) was validated with 540 incumbents holding 243 distinct jobs and demonstrated excellent reliability and convergent and discriminant validity. In addition, the authors found that, although both task and knowledge work characteristics predicted satisfaction, only knowledge characteristics were related to training and compensation requirements. Finally, the results showed that social support incrementally predicted satisfaction beyond motivational work characteristics but was not related to increased training and compensation requirements. These results provide new insight into how to avoid the trade-offs commonly observed in work design research. Taken together, the WDQ appears to hold promise as a general measure of work characteristics that can be used by scholars and practitioners to conduct basic research on the nature of work or to design and redesign jobs in organizations.

2,105 citations


Journal ArticleDOI
TL;DR: In this paper, the authors use meta-analysis to estimate the effect size and test whether effects are larger for high performance work practices (HPWPs) versus individual practices, operational versus financial performance measures, and manufacturing versus service organizations.
Abstract: Although there is growing evidence that high performance work practices (HPWPs) affect organizational performance, varying sample characteristics, research designs, practices examined, and organizational performance measures used has led extant findings to vary dramatically, making the size of the overall effect difficult to estimate. We use meta-analysis to estimate the effect size and test whether effects are larger for (a) HPWP systems versus individual practices, (b) operational versus financial performance measures, and (c) manufacturing versus service organizations. Statistical aggregation of 92 studies reveals an overall correlation that we estimate at .20. Also, the relationship is stronger when researchers examine systems of HPWPs and among manufacturers, but it appears invariant across performance measures. We use our findings as a basis to offer 4 suggestions intended to shape research practices such that future meta-analyses might answer today's emerging questions.

1,903 citations


Journal ArticleDOI
10 Feb 2006-Science
TL;DR: It is shown that viral-mediated, mesolimbic dopamine pathway–specific knockdown of brain-derived neurotrophic factor is required for the development of experience-dependent social aversion in mice experiencing repeated aggression.
Abstract: Mice experiencing repeated aggression develop a long-lasting aversion to social contact, which can be normalized by chronic, but not acute, administration of antidepressant. Using viral-mediated, mesolimbic dopamine pathway-specific knockdown of brain-derived neurotrophic factor (BDNF), we showed that BDNF is required for the development of this experience-dependent social aversion. Gene profiling in the nucleus accumbens indicates that local knockdown of BDNF obliterates most of the effects of repeated aggression on gene expression within this circuit, with similar effects being produced by chronic treatment with antidepressant. These results establish an essential role for BDNF in mediating long-term neural and behavioral plasticity in response to aversive social experiences.

1,873 citations


Book ChapterDOI
01 Jun 2006
TL;DR: There are several factors that influence the level of professional achievement as discussed by the authors, such as extensive experience of activities in a domain is necessary to reach very high levels of performance, however, extensive experience does not always lead to expert levels of achievement.
Abstract: There are several factors that influence the level of professional achievement. First and foremost, extensive experience of activities in a domain is necessary to reach very high levels of performance. Extensive experience in a domain does not, however, invariably lead to expert levels of achievement. When individuals are first introduced to a professional domain after completing their basic training and formal education, they often work as apprentices and are supervised by more-experienced professionals as they accomplish their work-related responsibilities. After months of experience, they typically attain an acceptable level of proficiency, and with longer experience, often years, they are able to work as independent professionals. At that time most professionals reach a stable, average level of performance, and then they maintain this pedestrian level for the rest of their careers. In contrast, some continue to improve and eventually reach the highest levels of professional mastery. Traditionally, individual differences in the performance of professionals have been explained by an account given by Galton (1869/1979, see Ericsson, 2003a, for a description). According to this view, every healthy person will improve initially through experience, but these improvements are eventually limited by innate factors that cannot be changed through training; hence attainable performance is constrained by one's basic endowments, such as abilities, mental capacities, and innate talents. This general view also explains age-related declines in professional achievement, owing to the inevitable degradation of general capacities and processes with age (see also Krampe & Charness, Chapter 40).

1,482 citations


Journal ArticleDOI
TL;DR: This article found that older adults were less likely than younger adults to use technology in general, computers, and the World Wide Web, and that computer anxiety, fluid intelligence, and crystallized intelligence were important predictors of the use of technology.
Abstract: The successful adoption of technology is becoming increasingly important to functional independence. The present article reports findings from the Center for Research and Education on Aging and Technology Enhancement (CREATE) on the use of technology among communitydwelling adults. The sample included 1,204 individuals ranging in age from 18–91 years. All participants completed a battery that included measures of demographic characteristics, self-rated health, experience with technology, attitudes toward computers, and component cognitive abilities. Findings indicate that the older adults were less likely than younger adults to use technology in general, computers, and the World Wide Web. The results also indicate that computer anxiety, fluid intelligence, and crystallized intelligence were important predictors of the use of technology. The relationship between age and adoption of technology was mediated by cognitive abilities, computer self-efficacy, and computer anxiety. These findings are discussed in terms of training strategies to promote technology adoption.

1,447 citations


Journal ArticleDOI
TL;DR: The findings demonstrate the diagnostic heterogeneity of adolescents engaging in NSSI, highlight the significant overlap between N SSI and suicide attempts, and provide a point of departure for future research aimed at elucidating the relations between non-suicidal and suicidal self-injury.
Abstract: Non-suicidal self-injury (NSSI) is a prevalent behavioral problem, yet many fundamental aspects of NSSI remain unknown. This case series study reports on the diagnostic correlates of adolescents with a recent history of NSSI and examines the relation between NSSI and suicide attempts. Data are from clinical interviews with 89 adolescents admitted to an adolescent psychiatric inpatient unit who engaged in NSSI in the previous 12 months. Results revealed that 87.6% of adolescents engaging in NSSI met criteria for a DSM-IVAxis I diagnosis (M=3.0, S.D.=2.2, range=0 to 8 diagnoses), including externalizing (62.9%), internalizing (51.7%), and substance use (59.6%) disorders. Most adolescents assessed also met criteria for an Axis II personality disorder (67.3%). Overall, 70% of adolescents engaging in NSSI reported a lifetime suicide attempt and 55% reported multiple attempts. Characteristics of NSSI associated with making suicide attempts included a longer history of NSSI, use of a greater number of methods, and absence of physical pain during NSSI. These findings demonstrate the diagnostic heterogeneity of adolescents engaging in NSSI, highlight the significant overlap between NSSI and suicide attempts, and provide a point of departure for future research aimed at elucidating the relations between non-suicidal and suicidal self-injury. © 2006 Elsevier Ireland Ltd. All rights reserved.

1,291 citations


Journal ArticleDOI
17 Nov 2006-Science
TL;DR: The results of nine experiments suggest that money brings about a self-sufficient orientation in which people prefer to be free of dependency and dependents.
Abstract: Money has been said to change people's motivation (mainly for the better) and their behavior toward others (mainly for the worse) The results of nine experiments suggest that money brings about a self-sufficient orientation in which people prefer to be free of dependency and dependents Reminders of money, relative to nonmoney reminders, led to reduced requests for help and reduced helpfulness toward others Relative to participants primed with neutral concepts, participants primed with money preferred to play alone, work alone, and put more physical distance between themselves and a new acquaintance

1,129 citations


Journal ArticleDOI
TL;DR: In this article, a general aromaticity index (AI) and two threshold values are proposed as unequivocal criteria for the existence of either aromatic (AI > 0.5) or condensed aromatic structures (AI >= 0.67) in NOM.
Abstract: Recent progress in Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS) provided extensive molecular mass data for complex natural organic matter (NOM). Structural information can be deduced solely from the molecular masses for ions with extreme molecular element ratios, in particular low H/C ratios, which are abundant in thermally altered NOM (e.g. black carbon). In this communication we propose a general aromaticity index (AI) and two threshold values as unequivocal criteria for the existence of either aromatic (AI > 0.5) or condensed aromatic structures (AI >= 0.67) in NOM. AI can be calculated from molecular formulae which are derived from exact molecular masses of naturally occurring compounds containing C, H, O, N, S and P and is especially applicable for substances with aromatic cores and few alkylations. In order to test the validity of our model index, AI is applied to FTICRMS data of a NOM deep-water sample from the Weddell Sea (Antarctica), a fulvic acid standard and an artificial dataset of all theoretically possible molecular formulae. For graphical evaluation a ternary plot is suggested for four-dimensional data representation. The proposed aromaticity index is a step towards structural identification of NOM and the molecular identification of black carbon in the environment.

1,057 citations


Journal ArticleDOI
07 Sep 2006-Nature
TL;DR: It is found that thawing permafrost along lake margins accounts for most of the methane released from the lakes, and it is estimated that an expansion of thaw lakes between 1974 and 2000, which was concurrent with regional warming, increased methane emissions in the study region by 58 per cent.
Abstract: Large uncertainties in the budget of atmospheric methane, an important greenhouse gas, limit the accuracy of climate change projections Thaw lakes in North Siberia are known to emit methane, but the magnitude of these emissions remains uncertain because most methane is released through ebullition (bubbling), which is spatially and temporally variable Here we report a new method of measuring ebullition and use it to quantify methane emissions from two thaw lakes in North Siberia We show that ebullition accounts for 95 per cent of methane emissions from these lakes, and that methane flux from thaw lakes in our study region may be five times higher than previously estimated Extrapolation of these fluxes indicates that thaw lakes in North Siberia emit 38 teragrams of methane per year, which increases present estimates of methane emissions from northern wetlands (< 6-40 teragrams per year; refs 1, 2, 4-6) by between 10 and 63 per cent We find that thawing permafrost along lake margins accounts for most of the methane released from the lakes, and estimate that an expansion of thaw lakes between 1974 and 2000, which was concurrent with regional warming, increased methane emissions in our study region by 58 per cent Furthermore, the Pleistocene age (35,260-42,900 years) of methane emitted from hotspots along thawing lake margins indicates that this positive feedback to climate warming has led to the release of old carbon stocks previously stored in permafrost

Journal ArticleDOI
TL;DR: While the process is essentially ubiquitous in coastal areas, the assessment of its magnitude at any one location is subject to enough variability that measurements should be made by a variety of techniques and over large enough spatial and temporal scales to capture the majority of these changing conditions.

Journal ArticleDOI
TL;DR: It is shown that ego depletion moderates the effects of many traits on behavior, particularly such that wide differences in socially disapproved motivations produce greater differences in behavior when ego depletion weakens the customary inner restraints.
Abstract: Self-regulation is a highly adaptive, distinctively human trait that enables people to override and alter their responses, including changing themselves so as to live up to social and other standards. Recent evidence indicates that self-regulation often consumes a limited resource, akin to energy or strength, thereby creating a temporary state of ego depletion. This article summarizes recent evidence indicating that regular exercises in self-regulation can produce broad improvements in self-regulation (like strengthening a muscle), making people less vulnerable to ego depletion. Furthermore, it shows that ego depletion moderates the effects of many traits on behavior, particularly such that wide differences in socially disapproved motivations produce greater differences in behavior when ego depletion weakens the customary inner restraints.

Journal ArticleDOI
TL;DR: Using simulated datasets, the Bayesian method generally fares better than the ML approach in accuracy and coverage, although for some values the two approaches are equal in performance.
Abstract: Comparison of the performance and accuracy of different inference methods, such as maximum likelihood (ML) and Bayesian inference, is difficult because the inference methods are implemented in different programs, often written by different authors. Both methods were implemented in the program MIGRATE, that estimates population genetic parameters, such as population sizes and migration rates, using coalescence theory. Both inference methods use the same Markov chain Monte Carlo algorithm and differ from each other in only two aspects: parameter proposal distribution and maximization of the likelihood function. Using simulated datasets, the Bayesian method generally fares better than the ML approach in accuracy and coverage, although for some values the two approaches are equal in performance. Motivation: The Markov chain Monte Carlo-based ML framework can fail on sparse data and can deliver non-conservative support intervals. A Bayesian framework with appropriate prior distribution is able to remedy some of these problems. Results: The program MIGRATE was extended to allow not only for ML(-) maximum likelihood estimation of population genetics parameters but also for using a Bayesian framework. Comparisons between the Bayesian approach and the ML approach are facilitated because both modes estimate the same parameters under the same population model and assumptions. Availability: The program is available from http://popgen.csit.fsu.edu/ Contact: beerli@csit.fsu.edu

Journal ArticleDOI
TL;DR: In this paper, the authors proposed that IT-enabled supply chain capabilities are firm-specific, and hard-to-copy across organizations, and provided a new perspective in evaluating IT investment in the supply chain process.

Journal ArticleDOI
07 Apr 2006-Science
TL;DR: Divergence time estimates calibrated by minimum age constraints from 43 fossils indicate that most of the subfamilies representing extant ants arose much earlier than previously proposed but only began to diversify during the Late Cretaceous to Early Eocene, which also witnessed the rise of angiosperms and most herbivorous insects.
Abstract: We present a large-scale molecular phylogeny of the ants (Hymenoptera: Formicidae), based on 4.5 kilobases of sequence data from six gene regions extracted from 139 of the 288 described extant genera, representing 19 of the 20 subfamilies. All but two subfamilies are recovered as monophyletic. Divergence time estimates calibrated by minimum age constraints from 43 fossils indicate that most of the subfamilies representing extant ants arose much earlier than previously proposed but only began to diversify during the Late Cretaceous to Early Eocene. This period also witnessed the rise of angiosperms and most herbivorous insects.

Journal ArticleDOI
15 Jun 2006-Nature
TL;DR: Reconciling available atomic structures with the three-dimensional whole spike density map yields insights into the orientation of Env spike structural elements and possible structural bases of their functions.
Abstract: Envelope glycoprotein (Env) spikes on AIDS retroviruses initiate infection of host cells and are therefore targets for vaccine development. Though crystal structures for partial Env subunits are known, the structure and distribution of native Env spikes on virions is obscure. We applied cryoelectron microscopy tomography to define ultrastructural details of spikes. Virions of wild-type human immunodeficiency virus 1 (HIV-1) and a mutant simian immunodeficiency virus (SIV) had approximately 14 and approximately 73 spikes per particle, respectively, with some clustering of HIV-1 spikes. Three-dimensional averaging showed that the surface glycoprotein (gp120) 'head' of each subunit of the trimeric SIV spike contains a primary mass, with two secondary lobes. The transmembrane glycoprotein 'stalk' of each trimer is composed of three independent legs that project obliquely from the trimer head, tripod-like. Reconciling available atomic structures with the three-dimensional whole spike density map yields insights into the orientation of Env spike structural elements and possible structural bases of their functions.

Journal ArticleDOI
TL;DR: Assessment of the psychometric properties of a CF scale using data from a survey of social workers living in New York City following the September 11, 2001, terrorist attacks indicated that the CF scale measured multiple dimensions.
Abstract: Few studies have focused on caring professionals and their emotional exhaustion from working with traumatized clients, referred to as compassion fatigue (CF). The present study had 2 goals: (a) to assess the psychometric properties of a CF scale, and (b) to examine the scale's predictive validity in a multivariate model. The data came from a survey of social workers living in New York City following the September 11, 2001, terrorist attacks on the World Trade Center. Factor analyses indicated that the CF scale measured multiple dimensions. After overlapping items were eliminated, the scale measured 2 key underlying dimensions—secondary trauma and job burnout. In a multivariate model, these dimensions were related to psychological distress, even after other risk factors were controlled. The authors discuss the results in light of increasing the ability of professional caregivers to meet the emotional needs of their clients within a stressful environment without experiencing CF.

Journal ArticleDOI
TL;DR: In this paper, the authors used data from a survey of 309 consumers to develop a 32-item self-report scale measuring consumer motivations for online opinion seeking and found that consumers seek the opinions of others online to reduce their risk, because others do it, to secure lower prices, to get information easily, by accident (unplanned), because it is cool, because they are stimulated by off-line inputs such as TV, and to get pre-purchase information.
Abstract: Online interpersonal influence or electronic word-of-mouth (“eWOM”) is an important aspect of ecommerce. Consumers give and seek opinions online in much the same way as they do offline, thereby affecting the sales of many goods and services. To further the understanding of eWOM, the present study used data from a survey of 309 consumers to develop a 32-item self-report scale measuring consumer motivations for online opinion seeking. This study revealed eight distinct factors. Consumers seek the opinions of others online to reduce their risk, because others do it, to secure lower prices, to get information easily, by accident (unplanned), because it is cool, because they are stimulated by off-line inputs such as TV, and to get pre-purchase information. A second study using data from 109 consumers showed that: (1) the scales measuring these motivations are free from social desirability response bias and acquiescence, (2) other consumers’ information is more important than advertising, and (3) consum...

Journal ArticleDOI
TL;DR: In 5 experiments, the authors addressed 2 novel questions regarding language-based motor resonance regarding visual motion that is associated with an action and whether motor resonance is modulated during sentence comprehension.
Abstract: Observing actions and understanding sentences about actions activates corresponding motor processes in the observer-comprehender. In 5 experiments, the authors addressed 2 novel questions regarding language-based motor resonance. The 1st question asks whether visual motion that is associated with an action produces motor resonance in sentence comprehension. The 2nd question asks whether motor resonance is modulated during sentence comprehension. The authors' experiments provide an affirmative response to both questions. A rotating visual stimulus affects both actual manual rotation and the comprehension of manual rotation sentences. Motor resonance is modulated by the linguistic input and is a rather immediate and localized phenomenon. The results are discussed in the context of theories of action observation and mental simulation.

Journal ArticleDOI
TL;DR: Lysine (Brazil nut, cashew nut, hazelnut, pine nut, and walnut), sulfur amino acids methionine and cysteine (almond), tryptophan (macadamia, pecan), and threonine (peanut) to be the first limiting amino acid as compared to human (2-5 year old) amino acid requirements.
Abstract: Commercially important edible nut seeds were analyzed for chemical composition and moisture sorption. Moisture (1.47-9.51%), protein (7.50-21.56%), lipid (42.88-66.71%), ash (1.16-3.28%), total soluble sugars (0.55-3.96%), tannins (0.01-0.88%), and phytate (0.15-0.35%) contents varied considerably. Regardless of the seed type, lipids were mainly composed of mono- and polyunsaturated fatty acids (>75% of the total lipids). Fatty acid composition analysis indicated that oleic acid (C18:1) was the main constituent of monounsaturated lipids in all seed samples. With the exception of macadamia, linoleic acid (C18:2) was the major polyunsaturated fatty acid. In the case of walnuts, in addition to linoleic acid (59.79%) linolenic acid (C18:3) also significantly contributed toward the total polyunsaturated lipids. Amino acid composition analyses indicated lysine (Brazil nut, cashew nut, hazelnut, pine nut, and walnut), sulfur amino acids methionine and cysteine (almond), tryptophan (macadamia, pecan), and threonine (peanut) to be the first limiting amino acid as compared to human (2-5 year old) amino acid requirements. The amino acid composition of the seeds was characterized by the dominance of hydrophobic (range = 37.16-44.54%) and acidic (27.95-33.17%) amino acids followed by basic (16.16-21.17%) and hydrophilic (8.48-11.74%) amino acids. Trypsin inhibitory activity, hemagglutinating activity, and proteolytic activity were not detected in the nut seed samples analyzed. Sorption isotherms (Aw range = 0.08-0.97) indicated a narrow range for monolayer water content (11-29 mg/g of dry matter). No visible mold growth was evident on any of the samples stored at Aw < 0.53 and 25 degrees C for 6 months.

Journal ArticleDOI
TL;DR: A new, monophyletic taxonomy for dendrobatids is proposed, recognizing the inclusive clade as a superfamily (Dendrobatoidea) composed of two families (one of which is new), six subfamilies (three new), and 16 genera (four new).
Abstract: The known diversity of dart-poison frog species has grown from 70 in the 1960s to 247 at present, with no sign that the discovery of new species will wane in the foreseeable future. Although this growth in knowledge of the diversity of this group has been accompanied by detailed investigations of many aspects of the biology of dendrobatids, their phylogenetic relationships remain poorly understood. This study was designed to test hypotheses of dendrobatid diversification by combining new and prior genotypic and phenotypic evidence in a total evidence analysis. DNA sequences were sampled for five mitochondrial and six nuclear loci (approximately 6,100 base pairs [bp]; x¯ = 3,740 bp per terminal; total dataset composed of approximately 1.55 million bp), and 174 phenotypic characters were scored from adult and larval morphology, alkaloid profiles, and behavior. These data were combined with relevant published DNA sequences. Ingroup sampling targeted several previously unsampled species, including Ar...

Journal ArticleDOI
TL;DR: This paper examined the cognitive correlates of 3rd-grade skill in arithmetic, algorithmic computation, and arithmetic word problems and found that inattentive behavior independently predicted all three aspects of mathematics performance.
Abstract: The purpose of this study was to examine the cognitive correlates of 3rd-grade skill in arithmetic, algorithmic computation, and arithmetic word problems. Third graders (N = 312) were measured on language, nonverbal problem solving, concept formation, processing speed, long-term memory, working memory, phonological decoding, and sight word efficiency as well as on arithmetic, algorithmic computation, and arithmetic word problems. Teacher ratings of inattentive behavior also were collected. Path analysis indicated that arithmetic was linked to algorithmic computation and to arithmetic word problems and that inattentive behavior independently predicted all 3 aspects of mathematics performance. Other independent predictors of arithmetic were phonological decoding and processing speed. Other independent predictors of arithmetic word problems were nonverbal problem solving, concept formation, sight word efficiency, and language.

Journal ArticleDOI
TL;DR: Experiments 1-4 showed that receiving an ostensibly diagnostic forecast of a lonesome future life reduced sensitivity to physical pain, as indicated by both (higher) thresholds and tolerance, and also caused emotional insensitivity.
Abstract: Prior findings of emotional numbness (rather than distress) among socially excluded persons led the authors to investigate whether exclusion causes a far-reaching insensitivity to both physical and emotional pain. Experiments 1-4 showed that receiving an ostensibly diagnostic forecast of a lonesome future life reduced sensitivity to physical pain, as indicated by both (higher) thresholds and tolerance. Exclusion also caused emotional insensitivity, as indicated by reductions in affective forecasting of joy or woe over a future football outcome (Experiment 3), as well as lesser empathizing with another person's suffering from either romantic breakup (Experiment 4) or a broken leg (Experiment 5). The insensitivities to pain and emotion were highly intercorrelated.

Journal ArticleDOI
TL;DR: In agreement with the model of Persson and Lang, all experimental data show that energy transfer to the metal surface is the dominant quenching mechanism, and the radiative rate is unchanged throughout the experiment.
Abstract: The fluorescence behavior of molecular dyes at discrete distances from 15 nm diameter gold nanoparticles as a function of distance and energy is investigated Photoluminescence and luminescence lifetime measurements both demonstrate quenching behavior consistent with 1/d(4) separation distance from dye to the surface of the nanoparticle In agreement with the model of Persson and Lang, all experimental data show that energy transfer to the metal surface is the dominant quenching mechanism, and the radiative rate is unchanged throughout the experiment

Book ChapterDOI
01 Jun 2006
TL;DR: This chapter focuses on the influential developments within cognitive science and cognitive psychology that have occurred over the last three decades and attempts to characterize some of the emerging insights about mechanisms and aspects of expertise that generalize across domains.
Abstract: Introduction The study of expertise has a very long history that has been discussed in several other chapters in this handbook (Ericsson, Chapter 1; Amirault & Branson, Chapter 5). This chapter focuses on the influential developments within cognitive science and cognitive psychology that have occurred over the last three decades. Our chapter consists of two parts. In the first part we briefly review what we consider the major developments in cognitive science and cognitive psychology that led to the new field of expertise studies. In the second part we attempt to characterize some of the emerging insights about mechanisms and aspects of expertise that generalize across domains, and we explore the original theoretical accounts, along with more recent ones. The Development of Expertise Studies In this handbook there are several pioneering research traditions represented that were brought together to allow laboratory studies of expertise, along with the development of formal models that can reproduce the performance of the experts. One early stream was the study of thinking using protocol analysis, where participants were instructed to “think aloud” while solving everyday life problems (Duncker, 1945), and experts were asked to think aloud while selecting moves for chess positions (de Groot, 1946/1965; Ericsson, Chapter 13). Another stream developed out of the research on judgment and decision making, where researchers compared the judgments of experts to those of statistical models (Meehl, 1954; Yates & Tschirhart, Chapter 24).

Journal ArticleDOI
TL;DR: The authors examined individuals' party identifications and their attitudes on abortion, government spending and provision of services, and government help for African Americans using the 1992-94-96 National Election Study panel study, finding strong support for their argument.
Abstract: Scholars have long debated the individual-level relationship between partisanship and policy preferences. We argue that partisanship and issue attitudes cause changes in each other, but the pattern of influence varies systematically. Issue-based change in party identification should occur among individuals who are aware of party differences on an issue and find that issue to be salient. Individuals who are aware of party differences, but do not attach importance to the issue, should evidence party-based issue change. Those lacking awareness of party differences on an issue should show neither effect. We test our account by examining individuals' party identifications and their attitudes on abortion, government spending and provision of services, and government help for African Americans using the 1992-94-96 National Election Study panel study, finding strong support for our argument. We discuss the implications of our findings both for the microlevel study of party identification and the macrolevel analysis of partisan change.

Journal ArticleDOI
TL;DR: A consensus set of warning signs identified by the American Association of Suicidology working group are presented, along with a discussion of relevant clinical and research applications.
Abstract: The current article addresses the issue of warning signs for suicide, attempting to differentiate the construct from risk factors. In accordance with the characteristic features discussed, a consensus set of warning signs identified by the American Association of Suicidology working group are presented, along with a discussion of relevant clinical and research applications.

Posted Content
TL;DR: The authors found that those who returned to disadvantaged neighborhoods recidivate at a greater rate while those who return to resource rich or affluent communities recide at a lesser rate, controlling for individual-level factors.
Abstract: Prior studies of recidivism have focused almost exclusively on individual-level characteristics of offenders and their offenses to explore the correlates of reoffending. Notably absent from these studies are measures reflecting the neighborhood contexts in which individuals live. The current research addresses this shortcoming. Using data on a sample of ex-offenders in Multnomah County, Oregon (Portland and surrounding area) in conjunction with 2000 census data, we answer two questions. First, which individual-level factors influence rates of recidivism? Second, to what extent does neighborhood socioeconomic status account for variation in the reoffending behavior of ex-prisoners that is not explained by their individual-level characteristics? We find that those who return to disadvantaged neighborhoods recidivate at a greater rate while those who return to resource rich or affluent communities recidivate at a lesser rate, controlling for individual-level factors.

Journal ArticleDOI
TL;DR: In this article, the authors investigated the impact of mangroves, the dominant intertidal vegetation of the tropics, on marine DOC inventories and found that mangrove is the main source of terrigenous DOC in the open ocean off northern Brazil.
Abstract: [1] Organic matter, which is dissolved in low concentrations in the vast waters of the oceans, contains a total amount of carbon similar to atmospheric carbon dioxide To understand global biogeochemical cycles, it is crucial to quantify the sources of marine dissolved organic carbon (DOC) We investigated the impact of mangroves, the dominant intertidal vegetation of the tropics, on marine DOC inventories Stable carbon isotopes and proton nuclear magnetic resonance spectroscopy showed that mangroves are the main source of terrigenous DOC in the open ocean off northern Brazil Sunlight efficiently destroyed aromatic molecules during transport offshore, removing about one third of mangrove-derived DOC The remainder was refractory and may thus be distributed over the oceans On a global scale, we estimate that mangroves account for >10% of the terrestrially derived, refractory DOC transported to the ocean, while they cover only <01% of the continents' surface