Ghulam Ishaq Khan Institute of Engineering Sciences and Technology

About: Ghulam Ishaq Khan Institute of Engineering Sciences and Technology is a education organization based out in Topi, Pakistan. It is known for research contribution in the topics: Quantum efficiency & Diode. The organization has 618 authors who have published 940 publications receiving 10674 citations.

Influence of substrate surface conditions on the plasma sprayed ceramic and metallic particles flattening

Abstract: The influence of the substrate surface temperature and oxidation state on the flattening of alumina and stainless steel particles and the morphology of resulting splats were studied in the current work. Particles were sprayed by a d.c. plasma gun on polished plain carbon steel and low alloy steel substrates preheated by plasma jet at different temperatures in air or in an oxidation limiting nitrogen shroud system added around substrates. Extensively fragmented splats of alumina and stainless steel were collected on substrates kept at room temperature. On substrates preheated to 573 (±20) K, the splat morphology of both materials transformed from splashed one to disk-shaped one. Optimal flattening degrees for stainless steel and alumina splats were measured for this substrate temperature, and the former particles exhibited flattening degree of the order of 1.2 times those of alumina. On plain carbon steel substrates, preheated in air at temperatures well above 573 K, the particle flattening degree decreased drastically and collected splats were extensively fragmented with bubbles like holes in them. The splashing and bubble formation in splats on preheated substrate were more dominating for low viscosity and higher Reynolds number stainless steel particles. The splat flattening–splashing and bubble formation were effectively limited by preheating substrates in the nitrogen shroud system. After a detailed characterization of substrate surface oxide layers, formed under different preheating conditions, it was concluded that splat morphology and flattening were only partially affected by the oxide chemical composition and thickness and were principally controlled by the surface roughness (more exactly its topography), induced by the oxidation.

Capacitive and diffusion-controlled mechanism of strontium oxide based symmetric and asymmetric devices

Abstract: A systematic approach has been employed to statistically analyze the Faradaic and non-Faradaic mechanism on electrodes. Two strategies have been adopted for device design, i.e. symmetric and asymmetric, by using the metal oxide synthesized via sonochemical method and activated carbon electrode. Structural and electrochemical characterization have been performed to investigate the morphological and electrochemical properties of electrode material. Both devices are electrochemically examined by using cyclic voltammetry (CV) and Galvanostatic charge discharge (GCD) measurements to evaluate the electrochemical performance. CV curves are further explored to study the capacitive and diffusive contribution in both devices. The diffusive-controlled contribution at low scan rate in asymmetric device is about 65% which is suitable for supercapattery applications while the symmetric device shows 91% diffusive contribution presenting better performance for battery applications. The strategy unveils the high capacitive and diffusive contribution in asymmetric and symmetric devices, respectively. Results reveal that same material can be exploited for supercapattery and battery applications by implementing different device architectures.