Institution
Harbin Engineering University
Education•Harbin, Heilongjiang, China•
About: Harbin Engineering University is a education organization based out in Harbin, Heilongjiang, China. It is known for research contribution in the topics: Control theory & Microstructure. The organization has 31149 authors who have published 27940 publications receiving 276787 citations. The organization is also known as: HEU.
Papers published on a yearly basis
Papers
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TL;DR: In this paper, a high-voltage asymmetric supercapacitor is successfully fabricated using Ni(OH)2/graphene and porous graphene as the positive and negative electrodes, respectively.
Abstract: Hierarchical flowerlike nickel hydroxide decorated on graphene sheets has been prepared by a facile and cost-effective microwave-assisted method. In order to achieve high energy and power densities, a high-voltage asymmetric supercapacitor is successfully fabricated using Ni(OH)2/graphene and porous graphene as the positive and negative electrodes, respectively. Because of their unique structure, both of these materials exhibit excellent electrochemical performances. The optimized asymmetric supercapacitor could be cycled reversibly in the high-voltage region of 0–1.6 V and displays intriguing performances with a maximum specific capacitance of 218.4 F g−1 and high energy density of 77.8 Wh kg−1. Furthermore, the Ni(OH)2/graphene//porous graphene supercapacitor device exhibits an excellent long cycle life along with 94.3% specific capacitance retained after 3000 cycles. These fascinating performances can be attributed to the high capacitance and the positive synergistic effects of the two electrodes. The impressive results presented here may pave the way for promising applications in high energy density storage systems.
1,808 citations
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TL;DR: An asymmetric supercapacitor with high energy density has been developed successfully using graphene/MnO2 composite as positive electrode and activated carbon nanofibers (ACN) as negative electrode in a neutral aqueous Na2SO4 electrolyte as mentioned in this paper.
Abstract: Asymmetric supercapacitor with high energy density has been developed successfully using graphene/MnO2 composite as positive electrode and activated carbon nanofibers (ACN) as negative electrode in a neutral aqueous Na2SO4 electrolyte. Due to the high capacitances and excellent rate performances of graphene/MnO2 and ACN, as well as the synergistic effects of the two electrodes, such asymmetric cell exhibits superior electrochemical performances. An optimized asymmetric supercapacitor can be cycled reversibly in the voltage range of 0–1.8 V, and exhibits maximum energy density of 51.1 Wh kg−1, which is much higher than that of MnO2//DWNT cell (29.1 Wh kg−1). Additionally, graphene/MnO2//ACN asymmetric supercapacitor exhibits excellent cycling durability, with 97% specific capacitance retained even after 1000 cycles. These encouraging results show great potential in developing energy storage devices with high energy and power densities for practical applications.
1,768 citations
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TL;DR: In this paper, the authors reviewed several key issues for improving the energy densities of supercapacitors and some mutual relationships among various effecting parameters, and challenges and perspectives in this exciting field are discussed.
Abstract: In recent years, tremendous research effort has been aimed at increasing the energy density of supercapacitors without sacrificing high power capability so that they reach the levels achieved in batteries and at lowering fabrication costs For this purpose, two important problems have to be solved: first, it is critical to develop ways to design high performance electrode materials for supercapacitors; second, it is necessary to achieve controllably assembled supercapacitor types (such as symmetric capacitors including double-layer and pseudo-capacitors, asymmetric capacitors, and Li-ion capacitors) The explosive growth of research in this field makes this review timely Recent progress in the research and development of high performance electrode materials and high-energy supercapacitors is summarized Several key issues for improving the energy densities of supercapacitors and some mutual relationships among various effecting parameters are reviewed, and challenges and perspectives in this exciting field are also discussed This provides fundamental insight into supercapacitors and offers an important guideline for future design of advanced next-generation supercapacitors for industrial and consumer applications
1,761 citations
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TL;DR: In this paper, a self-limiting deposition of nanoscale MnO2 on the surface of graphene under microwave irradiation was proposed to synthesize graphene-MnO2 composites.
1,263 citations
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TL;DR: In this article, a strategy to prepare flexible and conductive MXene/graphene (reduced graphene oxide, rGO) supercapacitor electrodes by using electrostatic self-assembly between positively charged rGO modified with poly(diallyldimethylammonium chloride) and negatively charged titanium carbide MXene nanosheets is presented.
Abstract: A strategy to prepare flexible and conductive MXene/graphene (reduced graphene oxide, rGO) supercapacitor electrodes by using electrostatic self-assembly between positively charged rGO modified with poly(diallyldimethylammonium chloride) and negatively charged titanium carbide MXene nanosheets is presented. After electrostatic assembly, rGO nanosheets are inserted in-between MXene layers. As a result, the self-restacking of MXene nanosheets is effectively prevented, leading to a considerably increased interlayer spacing. Accelerated diffusion of electrolyte ions enables more electroactive sites to become accessible. The freestanding MXene/rGO-5 wt% electrode displays a volumetric capacitance of 1040 F cm−3 at a scan rate of 2 mV s−1 , an impressive rate capability with 61% capacitance retention at 1 V s−1 and long cycle life. Moreover, the fabricated binder-free symmetric supercapacitor shows an ultrahigh volumetric energy density of 32.6 Wh L−1, which is among the highest values reported for carbon and MXene based materials in aqueous electrolytes. This work provides fundamental insight into the effect of interlayer spacing on the electrochemical performance of 2D hybrid materials and sheds light on the design of next-generation flexible, portable and highly integrated supercapacitors with high volumetric and rate performances.
1,260 citations
Authors
Showing all 31363 results
Name | H-index | Papers | Citations |
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Zhongzheng Li | 1 | 1 | 1 |
Duan-song Wang | 1 | 1 | 5 |
Shanshan Jin | 1 | 1 | 18 |
Fengming Li | 1 | 1 | 10 |
Hongjian Jia | 1 | 1 | 1 |
Baoyu Ni | 1 | 1 | 3 |
Liguo Zhang | 1 | 1 | 32 |
Qiao Tian | 1 | 2 | 12 |
Yu Wen | 1 | 1 | 10 |
Haoyun Tang | 1 | 1 | 20 |
Wen-xu Zhang | 1 | 2 | 1 |
Fanping Shi | 1 | 1 | 3 |
Shanshan Jin | 1 | 1 | 12 |
Jianneng Zhang | 1 | 2 | 1 |
Haili Jiang | 1 | 1 | 4 |