Institution
Helsinki University of Technology
About: Helsinki University of Technology is a based out in . It is known for research contribution in the topics: Thin film & Vortex. The organization has 8962 authors who have published 20136 publications receiving 723787 citations. The organization is also known as: TKK & Teknillinen korkeakoulu.
Papers published on a yearly basis
Papers
More filters
••
24 Mar 2014TL;DR: ToDIGRA publications are licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 2.5 Generic License (http://creativecommons.org/licenses/by-nc-nd/2.5/).
Abstract: ToDIGRA publications are licensed under a Creative Commons Attribution-NonCommercial-NoDerivs 2.5 Generic License (http://creativecommons.org/licenses/by-nc-nd/2.5/).
248 citations
••
TL;DR: In this article, the effect of the comonomer ratio on the thermal and mechanical properties of the copolymers was investigated by size-exclusion chromatography (SEC), differential scanning calorimetry (DSC), nuclear magnetic resonance (NMR) spectrometry, and tensile testing.
Abstract: Copolymers of e-caprolactone and L-lactide (e-CL/L-LA) and e-caprolactone and DL-lactide (e-CL/DL-LA) were synthesized with compositions 80/20, 60/40, and 40/60 (wt % in feed). The polymerization temperature was 140°C and Sn(II)octoate was used as a catalyst. The effect of the comonomer ratio on the thermal and mechanical properties of the copolymers was investigated by size-exclusion chromatography (SEC), differential scanning calorimetry (DSC), nuclear magnetic resonance (NMR) spectrometry, and tensile testing. The copolymers differed widely in their physical characteristics, ranging from weak elastomers to tougher thermoplastics according to the ratio of e-CL and LA in the copolymerization. Poly(L-lactide) (PLLA), poly(DL-lactide) (PDLLA), and poly(e-caprolactone) (PCL) homopolymers were studied as references. The tensile modulus and tensile strength were much higher for PLLA, PDLLA, and PCL homopolymers than for the copolymers. The maximum strain was very low for PLLA and PDLLA, whereas the copolymers and PCL exhibited large elongation. © 1996 John Wiley & Sons, Inc.
247 citations
••
247 citations
••
TL;DR: Data indicate that unilateral touch of fingers is associated, in addition to the well known activation of the contralateral SI cortex, with deactivation of the ipsilateral SI cortex and of the MI cortex of both hemispheres.
Abstract: The whole human primary somatosensory (SI) cortex is activated by contralateral tactile stimuli, whereas its subarea 2 displays neuronal responses also to ipsilateral stimuli. Here we report on a transient deactivation of area 3b of the ipsilateral SI during long-lasting tactile stimulation. We collected functional magnetic resonance imaging data with a 3 T scanner from 10 healthy adult subjects while tactile pulses were delivered at 1, 4, or 10 Hz in 25 s blocks to three right-hand fingers. In the contralateral SI cortex, activation [positive blood oxygenation level-dependent (BOLD) response] outlasted the stimulus blocks by 20 s, with an average duration of 45 s. In contrast, a transient deactivation (negative BOLD response) occurred in the ipsilateral rolandic cortex with an average duration of 18 s. Additional recordings on 10 subjects confirmed that the deactivation was not limited to the right SI but occurred in the SI cortex ipsilateral to the stimulated hand. Moreover, the primary motor cortex (MI) contained voxels that were phasically deactivated in response to both ipsilateral and contralateral touch. These data indicate that unilateral touch of fingers is associated, in addition to the well known activation of the contralateral SI cortex, with deactivation of the ipsilateral SI cortex and of the MI cortex of both hemispheres. The ipsilateral SI deactivation could result from transcallosal inhibition, whereas intracortical SI-MI connections could be responsible for the MI deactivation. The shorter time course of deactivation than activation would agree with stronger decay of inhibitory than EPSP at the applied stimulus repetition rates.
246 citations
••
TL;DR: An ambient ionization technique for mass spectrometry, desorption atmospheric pressure photoionization (DAPPI), is presented, and its application to the rapid analysis of compounds of various polarities on surfaces is demonstrated.
Abstract: An ambient ionization technique for mass spectrometry, desorption atmospheric pressure photoionization (DAPPI), is presented, and its application to the rapid analysis of compounds of various polarities on surfaces is demonstrated. The DAPPI technique relies on a heated nebulizer microchip delivering a heated jet of vaporized solvent, e.g., toluene, and a photoionization lamp emitting 10-eV photons. The solvent jet is directed toward sample spots on a surface, causing the desorption of analytes from the surface. The photons emitted by the lamp ionize the analytes, which are then directed into the mass spectrometer. The limits of detection obtained with DAPPI were in the range of 56-670 fmol. Also, the direct analysis of pharmaceuticals from a tablet surface was successfully demonstrated. A comparison of the performance of DAPPI with that of the popular desorption electrospray ionization method was done with four standard compounds. DAPPI was shown to be equally or more sensitive especially in the case of less polar analytes.
245 citations
Authors
Showing all 8962 results
Name | H-index | Papers | Citations |
---|---|---|---|
Ashok Kumar | 151 | 5654 | 164086 |
Hannu Kurki-Suonio | 138 | 433 | 99607 |
Nicolas Gisin | 125 | 827 | 64298 |
Anne Lähteenmäki | 116 | 485 | 81977 |
Riitta Hari | 111 | 491 | 43873 |
Andreas Richter | 110 | 769 | 48262 |
Mika Sillanpää | 96 | 1019 | 44260 |
Markku Leskelä | 94 | 876 | 36881 |
Ullrich Scherf | 92 | 735 | 36972 |
Mikko Ritala | 91 | 584 | 29934 |
Axel H. E. Müller | 89 | 564 | 30283 |
Karl Henrik Johansson | 88 | 1089 | 33751 |
T. Poutanen | 86 | 120 | 33158 |
Elina Lindfors | 86 | 420 | 23846 |
Günter Breithardt | 85 | 554 | 33165 |