Henan University of Technology

About: Henan University of Technology is a education organization based out in Zhengzhou, China. It is known for research contribution in the topics: Catalysis & Starch. The organization has 7648 authors who have published 6503 publications receiving 73067 citations. The organization is also known as: Hénán Gōngyè Dàxué.

Multidimensional Evolution of Carbon Structures Underpinned by Temperature-Induced Intermediate of Chloride for Sodium-Ion Batteries.

Abstract: Different dimensions of carbon materials with various features have captured numerous interests due to their applications on the tremendous fields. Restricted by the raw materials and devices, the controlling of their morphology is a major challenge. Utilizing the catalytic features of the intermediates from the low-cost salts and polymerization of 0D carbon quantum dots (CQDs), 0D CQDs are expected to self-assemble into 1/2/3D carbon structures with the assistance of temperature-induced intermediates (e.g., ZnO, Ni, and Cu) from the salts (ZnCl2, NiCl2, and CuCl). The formation mechanisms are illustrated as follows: 1) the "orient induction" to evoke "vine style" growth mechanism of ZnO; 2) the "dissolution-precipitation" of Ni; and 3) the "surface adsorption self-limited" of Cu. Subsequently, the degree of graphitization, interlayer distance, and special surface area are investigated in detail. 1D structure from 700 °C as anode displays a high Na-storage capacity of 301.2 mAh g-1 at 0.1 A g-1 after 200 cycles and 107 mAh g-1 at 5.0 A g-1 after 5000 cycles. Quantitative kinetics analysis confirms the fundamentals of the enhanced rate capacity and the potential region of Na-insertion/extraction. This elaborate work opens up an avenue toward the design of carbon with multidimensions and in-depth understanding of their sodium-storage features.