Hong Kong Polytechnic University

About: Hong Kong Polytechnic University is a education organization based out in Hong Kong, China. It is known for research contribution in the topics: Computer science & Tourism. The organization has 29633 authors who have published 72136 publications receiving 1956312 citations. The organization is also known as: HKPU & PolyU.

Review on life cycle assessment of energy payback and greenhouse gas emission of solar photovoltaic systems

Abstract: This paper aims to examine the sustainability and environmental performance of PV-based electricity generation systems by conducting a thorough review of the life cycle assessment (LCA) studies of five common photovoltaic (PV) systems, i.e., mono-crystalline (mono-Si), multi-crystalline (multi-Si), amorphous silicon (a-Si), CdTe thin film (CdTe) and CIS thin film (CIS), and some advanced PV systems. The results show that, among the five common PV systems, the CdTe PV system presents the best environmental performance in terms of energy payback time (EPBT) and greenhouse gases (GHG) emission rate due to its low life-cycle energy requirement and relatively high conversion efficiency. Meanwhile, the mono-Si PV system demonstrates the worst because of its high energy intensity during the solar cells’ production process. The EPBT and GHG emission rate of thin film PV systems are within the range of 0.75–3.5 years and 10.5–50 g CO 2 -eq./kW h, respectively. In general, the EPBT of mono-Si PV systems range from 1.7 to 2.7 years with GHG emission rate from 29 to 45 g CO 2 -eq./kW h, which is an order of magnitude smaller than that of fossil-based electricity. This paper also reviews the EPBT and GHG emission rates of some advanced PV systems, such as high-concentration, heterojunction and dye-sensitized technologies. The EBPT of high-concentration PV system is lower, ranging from 0.7 to 2.0 years, but the CO 2 emission rate of dye-sensitized PV system is higher than the ones of other PV systems at the moment. The LCA results show that PV technologies are already proved to be very sustainable and environmental-friendly in the state of the art. With the emerging of new manufacturing technologies, the environmental performance of PV technologies is expected to be further improved in the near future. In addition, considering the existing limitations in the previous LCA studies, a few suggestions are recommended.

Robust intrinsic ferromagnetism and half semiconductivity in stable two-dimensional single-layer chromium trihalides

Abstract: Two-dimensional (2D) intrinsic ferromagnetic (FM) semiconductors are crucial to develop low-dimensional spintronic devices. Using density functional theory, we show that single-layer chromium trihalides (SLCTs) (CrX3, X = F, Cl, Br and I) constitute a series of stable 2D intrinsic FM semiconductors. A free-standing SLCT can be easily exfoliated from the bulk crystal, due to a low cleavage energy and a high in-plane stiffness. Electronic structure calculations using the HSE06 functional indicate that both bulk and single-layer CrX3 are half semiconductors with indirect gaps and their valence and conduction bands are fully spin-polarized in the same spin direction. The energy gaps and absorption edges of CrBr3 and CrI3 are found to be in the visible frequency range, which implies possible opto-electronic applications. Furthermore, SLCTs are found to possess a large magnetic moment of 3 μB per formula unit and a sizable magnetic anisotropy energy. The magnetic exchange constants of SLCTs are then extracted using the Heisenberg spin Hamiltonian and the microscopic origins of the various exchange interactions are analyzed. A competition between a near 90° FM superexchange and a direct antiferromagnetic (AFM) exchange results in a FM nearest-neighbour exchange interaction. The next and third nearest-neighbour exchange interactions are found to be FM and AFM, respectively, and this can be understood by the angle-dependent extended Cr–X–X–Cr superexchange interaction. Moreover, the Curie temperatures of SLCTs are also predicted using Monte Carlo simulations and the values can be further increased by applying a biaxial tensile strain. The unique combination of robust intrinsic ferromagnetism, half semiconductivity and large magnetic anisotropy energies renders the SLCTs as promising candidates for next-generation semiconductor spintronic applications.

Wearable energy-dense and power-dense supercapacitor yarns enabled by scalable graphene–metallic textile composite electrodes

Abstract: One-dimensional flexible supercapacitor yarns are of considerable interest for future wearable electronics. The bottleneck in this field is how to develop devices of high energy and power density, by using economically viable materials and scalable fabrication technologies. Here we report a hierarchical graphene-metallic textile composite electrode concept to address this challenge. The hierarchical composite electrodes consist of low-cost graphene sheets immobilized on the surface of Ni-coated cotton yarns, which are fabricated by highly scalable electroless deposition of Ni and electrochemical deposition of graphene on commercial cotton yarns. Remarkably, the volumetric energy density and power density of the all solid-state supercapacitor yarn made of one pair of these composite electrodes are 6.1 mWh cm(-3) and 1,400 mW cm(-3), respectively. In addition, this SC yarn is lightweight, highly flexible, strong, durable in life cycle and bending fatigue tests, and integratable into various wearable electronic devices.