Showing papers by "Hong Kong University of Science and Technology published in 2014"
TL;DR: The uncovered aggregation and design rules yield three high-efficiency (>10%) donor polymers and will allow further synthetic advances and matching of both the polymer and fullerene materials, potentially leading to significantly improved performance and increased design flexibility.
Abstract: Although the field of polymer solar cell has seen much progress in device performance in the past few years, several limitations are holding back its further development For instance, current high-efficiency (>90%) cells are restricted to material combinations that are based on limited donor polymers and only one specific fullerene acceptor Here we report the achievement of high-performance (efficiencies up to 108%, fill factors up to 77%) thick-film polymer solar cells for multiple polymer:fullerene combinations via the formation of a near-ideal polymer:fullerene morphology that contains highly crystalline yet reasonably small polymer domains This morphology is controlled by the temperature-dependent aggregation behaviour of the donor polymers and is insensitive to the choice of fullerenes The uncovered aggregation and design rules yield three high-efficiency (>10%) donor polymers and will allow further synthetic advances and matching of both the polymer and fullerene materials, potentially leading to significantly improved performance and increased design flexibility
2,839 citations
TL;DR: “United the authors stand, United they fall”–Aesop.
Abstract: "United we stand, divided we fall."--Aesop. Aggregation-induced emission (AIE) refers to a photophysical phenomenon shown by a group of luminogenic materials that are non-emissive when they are dissolved in good solvents as molecules but become highly luminescent when they are clustered in poor solvents or solid state as aggregates. In this Review we summarize the recent progresses made in the area of AIE research. We conduct mechanistic analyses of the AIE processes, unify the restriction of intramolecular motions (RIM) as the main cause for the AIE effects, and derive RIM-based molecular engineering strategies for the design of new AIE luminogens (AIEgens). Typical examples of the newly developed AIEgens and their high-tech applications as optoelectronic materials, chemical sensors and biomedical probes are presented and discussed.
2,322 citations
TL;DR: A comprehensive assessment of soil heavy metal pollution derived from mines in China is provided, while identifying policy recommendations for pollution mitigation and environmental management of these mines.
2,061 citations
Johns Hopkins University1, Johns Hopkins University School of Medicine2, University of Toronto3, University of La Frontera4, Imperial College London5, Post Graduate Institute of Medical Education and Research6, Armed Forces Medical College7, National Institute of Mental Health and Neurosciences8, Hong Kong University of Science and Technology9, University of Maryland, Baltimore10
TL;DR: A draft map of the human proteome is presented using high-resolution Fourier-transform mass spectrometry to discover a number of novel protein-coding regions, which includes translated pseudogenes, non-c coding RNAs and upstream open reading frames.
Abstract: The availability of human genome sequence has transformed biomedical research over the past decade. However, an equivalent map for the human proteome with direct measurements of proteins and peptides does not exist yet. Here we present a draft map of the human proteome using high-resolution Fourier-transform mass spectrometry. In-depth proteomic profiling of 30 histologically normal human samples, including 17 adult tissues, 7 fetal tissues and 6 purified primary haematopoietic cells, resulted in identification of proteins encoded by 17,294 genes accounting for approximately 84% of the total annotated protein-coding genes in humans. A unique and comprehensive strategy for proteogenomic analysis enabled us to discover a number of novel protein-coding regions, which includes translated pseudogenes, non-coding RNAs and upstream open reading frames. This large human proteome catalogue (available as an interactive web-based resource at http://www.humanproteomemap.org) will complement available human genome and transcriptome data to accelerate biomedical research in health and disease.
1,965 citations
TL;DR: The concept of urban computing is introduced, discussing its general framework and key challenges from the perspective of computer sciences, and the typical technologies that are needed in urban computing are summarized into four folds.
Abstract: Urbanization's rapid progress has modernized many people's lives but also engendered big issues, such as traffic congestion, energy consumption, and pollution. Urban computing aims to tackle these issues by using the data that has been generated in cities (e.g., traffic flow, human mobility, and geographical data). Urban computing connects urban sensing, data management, data analytics, and service providing into a recurrent process for an unobtrusive and continuous improvement of people's lives, city operation systems, and the environment. Urban computing is an interdisciplinary field where computer sciences meet conventional city-related fields, like transportation, civil engineering, environment, economy, ecology, and sociology in the context of urban spaces. This article first introduces the concept of urban computing, discussing its general framework and key challenges from the perspective of computer sciences. Second, we classify the applications of urban computing into seven categories, consisting of urban planning, transportation, the environment, energy, social, economy, and public safety and security, presenting representative scenarios in each category. Third, we summarize the typical technologies that are needed in urban computing into four folds, which are about urban sensing, urban data management, knowledge fusion across heterogeneous data, and urban data visualization. Finally, we give an outlook on the future of urban computing, suggesting a few research topics that are somehow missing in the community.
1,290 citations
TL;DR: It is expected that the mechanistic insights into the AIE phenomena, based on the restriction of intramolecular motions and structure rigidification, can guide the future design of AIE materials with fascinating structures and functionalities.
Abstract: Macromolecules with aggregation-induced emission (AIE) attributes are a class of luminescent materials that display enhanced emission when they are aggregated. They have attracted much attention because of their good solubility, processability, high emission efficiency in the aggregated states, etc. A large variety of AIE macromolecules have been developed, showing exponential growth of research interest in this field. This review summarizes the design principles and recent synthetic advancements, topological structures, as well as the frontiers of functionalities and potential applications of AIE macromolecules, especially fluorescence sensing, biological applications and optoelectronic applications, with an emphasis on the recent progress. New luminogenic systems without conventional chromophores displaying aggregated state emission are discussed. The highly dense clusters of heteroatoms with lone pair electrons in these systems may serve as the chromophore and are cited as “heterodox clusters”. It is expected that the mechanistic insights into the AIE phenomena, based on the restriction of intramolecular motions and structure rigidification, can guide the future design of AIE materials with fascinating structures and functionalities.
1,128 citations
TL;DR: A comprehensive review of recent synthetic methods along with associated synthesis mechanisms, characterization, fundamental properties, and promising applications of Cupric oxide (CuO) nanostructures is presented in this article.
1,030 citations
TL;DR: Self-aligned in situ reduced graphene oxide (rGO)/polymer nanocomposites with the engineered structure and properties present high performance electromagnetic interference shielding with a remarkable shilding efficiency of 38 dB.
Abstract: Nanocomposites that contain reinforcements with preferred orientation have attracted significant attention because of their promising applications in a wide range of multifunctional fields. Many efforts have recently been focused on developing facile methods for preparing aligned graphene sheets in solvents and polymers because of their fascinating properties including liquid crystallinity and highly anisotropic characteristics. Self-aligned in situ reduced graphene oxide (rGO)/polymer nanocomposites are prepared using an all aqueous casting method. A remarkably low percolation threshold of 0.12 vol% is achieved in the rGO/epoxy system owing to the uniformly dispersed, monolayer graphene sheets with extremely high aspect ratios (>30000). The self-alignment into a layered structure at above a critical filler content induces a unique anisotropy in electrical and mechanical properties due to the preferential formation of conductive and reinforcing networks along the alignment direction. Accompanied by the anisotropic electrical conductivities are exceptionally high dielectric constants of over 14000 with 3 wt% of rGO at 1 kHz due to the charge accumulation at the highly-aligned conductive filler/insulating polymer interface according to the Maxwell-Wagner-Sillars polarization principle. The highly dielectric rGO/epoxy nanocomposites with the engineered structure and properties present high performance electromagnetic interference shielding with a remarkable shilding efficiency of 38 dB.
1,011 citations
TL;DR: The development of highly conductive NiCo2S4 single crystalline nanotube arrays grown on a flexible carbon fiber paper (CFP), which can serve not only as a good pseudocapacitive material but also as a three-dimensional conductive scaffold for loading additional electroactive materials.
Abstract: We report on the development of highly conductive NiCo2S4 single crystalline nanotube arrays grown on a flexible carbon fiber paper (CFP), which can serve not only as a good pseudocapacitive material but also as a three-dimensional (3D) conductive scaffold for loading additional electroactive materials. The resulting pseudocapacitive electrode is found to be superior to that based on the sibling NiCo2O4 nanorod arrays, which are currently used in supercapacitor research due to the much higher electrical conductivity of NiCo2S4. A series of electroactive metal oxide materials, including CoxNi1–x(OH)2, MnO2, and FeOOH, were deposited on the NiCo2S4 nanotube arrays by facile electrodeposition and their pseudocapacitive properties were explored. Remarkably, the as-formed CoxNi1–x(OH)2/NiCo2S4 nanotube array electrodes showed the highest discharge areal capacitance (2.86 F cm–2 at 4 mA cm–2), good rate capability (still 2.41 F cm–2 at 20 mA cm–2), and excellent cycling stability (∼4% loss after the repetitive ...
1,008 citations
TL;DR: It is demonstrated that by using a simple construction, an acoustically reflecting surface can acquire hybrid resonances and becomes impedance-matched to airborne sound at tunable frequencies, such that no reflection is generated.
Abstract: Acoustic impedance-matched surfaces do not reflect incident waves. Traditional means of acoustic absorption have so far resulted in imperfect impedance matching and bulky structures, or require costly and sophisticated electrical design. Inspired by electromagnetic metamaterials, a subwavelength acoustically reflecting surface with hybrid resonances and impedance-matched to airborne sound at tunable frequencies is now demonstrated.
757 citations
TL;DR: A novel strategy is used to synthesize a non-noble-metal-based electrocatalyst of the OER by finely combining layered FeNi double hydroxide that is catalytically active and electric conducting graphene sheets, taking advantage of the electrostatic attraction between the two positively charged nanosheets.
Abstract: Cost-effective electrocatalysts for the oxygen evolu- tion reaction (OER) are critical to energy conversion and storage processes. A novel strategy is used to synthesize a non- noble-metal-based electrocatalyst of the OER by finely com- bining layered FeNi double hydroxide that is catalytically active and electric conducting graphene sheets, taking advant- age of the electrostatic attraction between the two positively charged nanosheets. The synergy between the catalytic activity of the double hydroxide and the enhanced electron transport arising from the graphene resulted in superior electrocatalytic properties of the FeNi-GO hybrids for the OER with over- potentials as low as 0.21 V, which was further reduced to 0.195 V after the reduction treatment. Moreover, the turnover frequency at the overpotential of 0.3 V has reached 1 s 1 , which is much higher than those previously reported for non-noble- metal-based electrocatalysts. The growing demand for energy and the increasing concerns about environment pollution from fossil fuels are stimulating intense research interest in energy conversion and storage from alternative sustainable energy sources. As one of the most important process to produce and store renewable energy in chemical form, the oxygen evolution reaction (OER) has led to many studies in recent years. However, the kinetics of OER is sluggish. Therefore, an effective electro- catalyst is needed to accelerate the reaction and reduce the large overpotential and thus improve the energy conversion efficiency. Metal oxides are the most active and durable electrocatalysts for OER, among which IrO2 and RuO2 are thought to be best OER catalysts in both acidic and alkaline solutions. (1) However, the high cost and element scarcity greatly hindered the widespread use of these noble-metal oxide catalysts. Therefore, it is desirable to develop efficient alternative catalysts based on inexpensive and earth-abun- dant elements without compromising good catalytic activity and durability for OER. Recently, extensive efforts have been made to use perovskites (2) and first-row transition-metal- based materials (3) as low-cost catalysts or electrode materials
TL;DR: This study is the first to demonstrate the contributions of different reactive species to the micropollutant degradation in the UV/chlorine system under environmentally relevant conditions.
Abstract: The UV/free chlorine process forms reactive species such as hydroxyl radicals (HO•), chlorine atoms (Cl•), Cl2•–, and O•–. The specific roles of these reactive species in aqueous micropollutant degradation in the UV/chlorine process under different conditions were investigated using a steady-state kinetic model. Benzoic acid (BA) was chosen as the model micropollutant. The steady-state kinetic model developed fitted the experimental data well. The results showed that HO• and Cl• contributed substantially to BA degradation, while the roles of the other reactive species such as Cl2•– and O•– were negligible. The overall degradation rate of BA decreased as the pH increased from 6 to 9. In particular, the relative contributions of HO• and Cl• to the degradation changed from 34.7% and 65.3% respectively at pH 6 to 37.9% and 62% respectively at pH 9 under the conditions evaluated. Their relative contributions also changed slightly with variations in chlorine dosage, BA concentration and chloride concentration. ...
TL;DR: In this paper, the authors conducted a meta-analysis of the link between entrepreneurs' personal networks and small firm performance and identified new moderators affecting this relationship and developed recommendations for future research on the contingent value of social capital for small firms.
TL;DR: By designing surfaces with tapered micro/nanotextures which behave as harmonic springs, the timescales become independent of the impact velocity, allowing the occurrence of pancake bouncing and rapid drop detachment over a wide range of impact velocities.
Abstract: When a water drop bounces back from a hydrophobic surface, its initial, spherical shape is usually restored. Now, experiments with a specially engineered superhydrophobic surface made from micrometre-sized tapered pillars covered with copper oxide ‘nanoflowers’ show that droplets can bounce back with a flat, pancake-like shape. Engineering surfaces that promote rapid drop detachment1,2 is of importance to a wide range of applications including anti-icing3,4,5, dropwise condensation6 and self-cleaning7,8,9. Here we show how superhydrophobic surfaces patterned with lattices of submillimetre-scale posts decorated with nanotextures can generate a counter-intuitive bouncing regime: drops spread on impact and then leave the surface in a flattened, pancake shape without retracting. This allows a fourfold reduction in contact time compared with conventional complete rebound 1,10,11,12,13. We demonstrate that the pancake bouncing results from the rectification of capillary energy stored in the penetrated liquid into upward motion adequate to lift the drop. Moreover, the timescales for lateral drop spreading over the surface and for vertical motion must be comparable. In particular, by designing surfaces with tapered micro/nanotextures that behave as harmonic springs, the timescales become independent of the impact velocity, allowing the occurrence of pancake bouncing and rapid drop detachment over a wide range of impact velocities.
TL;DR: In this article, the authors proposed a new network architecture that overlays an uplink cellular network with randomly deployed power beacons (PBs) for powering mobiles, called a hybrid network.
Abstract: Microwave power transfer (MPT) delivers energy wirelessly from stations called power beacons (PBs) to mobile devices by microwave radiation. This provides mobiles practically infinite battery lives and eliminates the need of power cords and chargers. To enable MPT for mobile recharging, this paper proposes a new network architecture that overlays an uplink cellular network with randomly deployed PBs for powering mobiles, called a hybrid network. The deployment of the hybrid network under an outage constraint on data links is investigated based on a stochastic-geometry model where single-antenna base stations (BSs) and PBs form independent homogeneous Poisson point processes (PPPs) with densities λb and λp, respectively, and single-antenna mobiles are uniformly distributed in Voronoi cells generated by BSs. In this model, mobiles and PBs fix their transmission power at p and q, respectively; a PB either radiates isotropically, called isotropic MPT, or directs energy towards target mobiles by beamforming, called directed MPT. The model is used to derive the tradeoffs between the network parameters (p, λb, q, λp) under the outage constraint. First, consider the deployment of the cellular network. It is proved that the outage constraint is satisfied so long as the product pλbα/2 is above a given threshold where α is the path-loss exponent. Next, consider the deployment of the hybrid network assuming infinite energy storage at mobiles. It is shown that for isotropic MPT, the product qλpλbα/2 has to be above a given threshold so that PBs are sufficiently dense; for directed MPT, zmqλpλbα/2 with zm denoting the array gain should exceed a different threshold to ensure short distances between PBs and their target mobiles. Furthermore, similar results are derived for the case of mobiles having small energy storage.
TL;DR: This work highlights that GQDs can act as a superfast electron tunnel for optoelectronic devices and improve perovskite solar cells' power conversion efficiency.
Abstract: We report on a significant power conversion efficiency improvement of perovskite solar cells from 8.81% to 10.15% due to insertion of an ultrathin graphene quantum dots (GQDs) layer between perovskite and TiO2. A strong quenching of perovskite photoluminescence was observed at ∼760 nm upon the addition of the GQDs, which is pronouncedly correlated with the increase of the IPCE and the APCE of the respective cells. From the transient absorption measurements, the improved cell efficiency can be attributed to the much faster electron extraction with the presence of GQDs (90–106 ps) than without their presence (260–307 ps). This work highlights that GQDs can act as a superfast electron tunnel for optoelectronic devices.
TL;DR: The results indicate that the S@NG nanocomposite based Li/S cells have a great potential to replace the current Li-ion batteries.
Abstract: Nitrogen-doped graphene (NG) is a promising conductive matrix material for fabricating high-performance Li/S batteries. Here we report a simple, low-cost, and scalable method to prepare an additive-free nanocomposite cathode in which sulfur nanoparticles are wrapped inside the NG sheets (S@NG). We show that the Li/S@NG can deliver high specific discharge capacities at high rates, that is, ∼1167 mAh g–1 at 0.2 C, ∼1058 mAh g–1 at 0.5 C, ∼971 mAh g–1 at 1 C, ∼802 mAh g–1 at 2 C, and ∼606 mAh g–1 at 5 C. The cells also demonstrate an ultralong cycle life exceeding 2000 cycles and an extremely low capacity-decay rate (0.028% per cycle), which is among the best performance demonstrated so far for Li/S cells. Furthermore, the S@NG cathode can be cycled with an excellent Coulombic efficiency of above 97% after 2000 cycles. With a high active S content (60%) in the total electrode weight, the S@NG cathode could provide a specific energy that is competitive to the state-of-the-art Li-ion cells even after 2000 cycl...
TL;DR: This paper considers multi-user massive MIMO systems and proposes a distributed compressive CSIT estimation scheme so that the compressed measurements are observed at the users locally, while the CSIT recovery is performed at the base station jointly.
Abstract: To fully utilize the spatial multiplexing gains or array gains of massive MIMO, the channel state information must be obtained at the transmitter side (CSIT). However, conventional CSIT estimation approaches are not suitable for FDD massive MIMO systems because of the overwhelming training and feedback overhead. In this paper, we consider multi-user massive MIMO systems and deploy the compressive sensing (CS) technique to reduce the training as well as the feedback overhead in the CSIT estimation. The multi-user massive MIMO systems exhibits a hidden joint sparsity structure in the user channel matrices due to the shared local scatterers in the physical propagation environment. As such, instead of naively applying the conventional CS to the CSIT estimation, we propose a distributed compressive CSIT estimation scheme so that the compressed measurements are observed at the users locally, while the CSIT recovery is performed at the base station jointly. A joint orthogonal matching pursuit recovery algorithm is proposed to perform the CSIT recovery, with the capability of exploiting the hidden joint sparsity in the user channel matrices. We analyze the obtained CSIT quality in terms of the normalized mean absolute error, and through the closed-form expressions, we obtain simple insights into how the joint channel sparsity can be exploited to improve the CSIT recovery performance.
TL;DR: In this article, a solvent-evaporation-assisted intercalation method was introduced to fabricate the hybrid of alternating molybdenum disulfide (MoS2) sheets and reduced graphene oxide layers, in which the nanosize of the MoS2 nanosheets can be effectively controlled by leveraging the confinement effect within the two-dimensional graphene layers.
Abstract: Since the electrocatalytic activity of layered molybdenum disulfide (MoS2) for hydrogen evolution reaction (HER) closely depends on its exposed edges, the morphology and size of the material are critically important. Herein, we introduce a novel solvent-evaporation-assisted intercalation method to fabricate the hybrid of alternating MoS2 sheets and reduced graphene oxide layers, in which the nanosize of the MoS2 nanosheets can be effectively controlled by leveraging the confinement effect within the two-dimensional graphene layers. Significantly, the resulting MoS2/reduced graphene oxide (RGO) composite shows excellent catalytic activity for HER characterized by higher current densities and lower onset potentials than the conventional pre-exfoliated RGO supported MoS2 nanosheets. Further experiments on the effect of oxidation degree of graphene, the crystallinity of MoS2, and the exposed active site density on the HER performance of the MoS2/RGO composites show that there is an optimum condition for the c...
TL;DR: The approach using angular ligand containing partially fixed TPE units paves a way toward highly porous MOFs with fluorescence turn-on response that will find wide applications in chemical sensing.
Abstract: We report a 2D layered metal–organic framework (MOF) with wide channels named NUS-1 and its activated analogue NUS-1a composed of Zn4O-like secondary building units and tetraphenylethene (TPE)-based ligand 4,4′-(2,2-diphenylethene-1,1-diyl)dibenzoic acid. Due to its special structure, NUS-1a exhibits unprecedented gas sorption behavior, glass-transition-like phase transition under cryogenic conditions, and responsive turn-on fluorescence to various volatile organic compounds. Our approach using angular ligand containing partially fixed TPE units paves a way toward highly porous MOFs with fluorescence turn-on response that will find wide applications in chemical sensing.
TL;DR: In this paper, the authors show that the Gibbs free energy for atomic hydrogen adsorption (ΔG0H) on MoSe2 edges is closer to thermoneutral than that on MoS2, with an H coverage of about 75% on the edge under operating conditions.
Abstract: MoSe2 nanosheets and MoSe2/graphene hybrids have been prepared by a facile hydrothermal method. The number of layers of the MoSe2 nanosheets is typically <10 as confirmed directly by transmission electron microscopy and indirectly by a red shift of the characteristic A1g Raman peak. The hydrogen evolution reaction (HER) studies show that the onset potentials of MoSe2 and MoSe2/RGO hybrids are only ∼0.15 V vs. RHE and ∼0.05 V vs. RHE, respectively, about 20–30 mV lower than those of MoS2 and its graphene hybrids reported previously. Density functional theory calculations reveal that the Gibbs free energy for atomic hydrogen adsorption (ΔG0H) on MoSe2 edges is closer to thermoneutral than that on MoS2, with an H coverage of about 75% on the edge under operating conditions, which is also higher than that of MoS2 reported in the literature. The consistency between the experimental and computational results indicates that MoSe2 nanosheets have potential to be a better HER catalyst than their MoS2 counterpart.
TL;DR: The all-printable fabrication of polycrystalline nanowire-based high-performance photodetectors on flexible substrates is demonstrated, showing their ultra-high photoconductive gain, responsivity and detectivity up to 3.3 × 1017 Jones.
Abstract: High-performance photodetectors are critical for high-speed optical communication and environmental sensing, and flexible photodetectors can be used for a wide range of portable or wearable applications. Here we demonstrate the all-printable fabrication of polycrystalline nanowire-based high-performance photodetectors on flexible substrates. Systematic investigations have shown their ultra-high photoconductive gain, responsivity and detectivity up to 3.3 × 10(17) Jones. Further analysis shows that their high performance originates from the unique band-edge modulation along the nanowire axial direction, where the existence of Schottky barriers in series leads to highly suppressed dark current of the device and also gives rise to fast photoelectric response to low-intensity optical signal owing to barrier height modulation. The discovered rationale in this work can be utilized as guideline to design high-performance photodetectors with other nanomaterial systems. The developed fabrication scheme opens up possibility for future flexible and high-performance integrated optoelectronic sensor circuitry.
TL;DR: Analyses of the computational QM/MM model reveal that the novel mechanism behind the AIE of THBDBA and BDBA is the restriction of intramolecular vibration (RIV).
Abstract: Aggregation-induced emission (AIE) has been harnessed in many systems through the principle of restriction of intramolecular rotations (RIR) based on mechanistic understanding from archetypal AIE molecules such as tetraphenylethene (TPE). However, as the family of AIE-active molecules grows, the RIR model cannot fully explain some AIE phenomena. Here, we report a broadening of the AIE mechanism through analysis of 10,10',11,11'-tetrahydro-5,5'-bidibenzo[a,d][7]annulenylidene (THBDBA), and 5,5'-bidibenzo[a,d][7]annulenylidene (BDBA). Analyses of the computational QM/MM model reveal that the novel mechanism behind the AIE of THBDBA and BDBA is the restriction of intramolecular vibration (RIV). A more generalized mechanistic understanding of AIE results by combining RIR and RIV into the principle of restriction of intramolecular motions (RIM).
TL;DR: This paper proposes a new framework to design a green Cloud-RAN, which is formulated as a joint RRH selection and power minimization beamforming problem, and proposes a greedy selection algorithm, shown to provide near-optimal performance.
Abstract: A cloud radio access network (Cloud-RAN) is a network architecture that holds the promise of meeting the explosive growth of mobile data traffic. In this architecture, all the baseband signal processing is shifted to a single baseband unit (BBU) pool, which enables efficient resource allocation and interference management. Meanwhile, conventional powerful base stations can be replaced by low-cost low-power remote radio heads (RRHs), producing a green and low-cost infrastructure. However, as all the RRHs need to be connected to the BBU pool through optical transport links, the transport network power consumption becomes significant. In this paper, we propose a new framework to design a green Cloud-RAN, which is formulated as a joint RRH selection and power minimization beamforming problem. To efficiently solve this problem, we first propose a greedy selection algorithm, which is shown to provide near-optimal performance. To further reduce the complexity, a novel group sparse beamforming method is proposed by inducing the group-sparsity of beamformers using the weighted \ell_1/\ell_2-norm minimization, where the group sparsity pattern indicates those RRHs that can be switched off. Simulation results will show that the proposed algorithms significantly reduce the network power consumption and demonstrate the importance of considering the transport link power consumption.
TL;DR: The photonic analogue of topological insulator is experimentally realized by embedding non-bianisotropic and non-resonant metacrystal into a waveguide and the topologically non-trivial bandgap is confirmed by experimentally measured transmission spectra and calculated non-zero spin Chern numbers.
Abstract: Photonic analogue of topological insulator was recently predicted by arranging e/μ (permittivity/permeability)-matched bianisotropic metamaterials into two-dimensional superlattices. However, the experimental observation of such photonic topological insulator is challenging as bianisotropic metamaterial is usually highly dispersive, so that the e/μ-matching condition can only be satisfied in a narrow frequency range. Here we experimentally realize a photonic topological insulator by embedding non-bianisotropic and non-resonant metacrystal into a waveguide. The cross coupling between transverse electric and transverse magnetic modes exists in metacrystal waveguide. Using this approach, the e/μ-matching condition is satisfied in a broad frequency range which facilitates experimental observation. The topologically non-trivial bandgap is confirmed by experimentally measured transmission spectra and calculated non-zero spin Chern numbers. Gapless spin-filtered edge states are demonstrated experimentally by measuring the magnitude and phase of the fields. The transport robustness of the edge states is also observed when an obstacle was introduced near the edge.
TL;DR: The analyses show that even though firm-wide IT capability presents the characteristics of rarity, appropriability, non-reproducibility, and non-substitutability, its impact on organizational performance is fully mediated by business process agility, and the impact of the environment is multifaceted and nuanced.
Abstract: The business value of information technology (IT) has been one of the top concerns of both practitioners and scholars for decades. Numerous studies have documented the positive effects of IT capabi...
TL;DR: In this article, a cyclic arginine-glycine-aspartic acid (cRGD) tripeptide was used for targeting integrin αvβ3 overexpressed cancer cells and an apoptosis sensor which is composed of tetraphenylsilole (TPS) fluorophore with aggregation-induced emission (AIE) characteristics and a caspase-3 enzyme specific Asp-Glu-Val-Asp (DEVD) peptide.
Abstract: Targeted drug delivery to tumor cells with minimized side effects and real-time in situ monitoring of drug efficacy is highly desirable for personalized medicine. In this work, we report the synthesis and biological evaluation of a chemotherapeutic Pt(IV) prodrug whose two axial positions are functionalized with a cyclic arginine-glycine-aspartic acid (cRGD) tripeptide for targeting integrin αvβ3 overexpressed cancer cells and an apoptosis sensor which is composed of tetraphenylsilole (TPS) fluorophore with aggregation-induced emission (AIE) characteristics and a caspase-3 enzyme specific Asp-Glu-Val-Asp (DEVD) peptide. The targeted Pt(IV) prodrug can selectively bind to αvβ3 integrin overexpressed cancer cells to facilitate cellular uptake. In addition, the Pt(IV) prodrug can be reduced to active Pt(II) drug in cells and release the apoptosis sensor TPS-DEVD simultaneously. The reduced Pt(II) drug can induce the cell apoptosis and activate caspase-3 enzyme to cleave the DEVD peptide sequence. Due to free rotation of the phenylene rings, TPS-DEVD is nonemissive in aqueous media. The specific cleavage of DEVD by caspase-3 generates the hydrophobic TPS residue, which tends to aggregate, resulting in restriction of intramolecular rotations of the phenyl rings and ultimately leading to fluorescence enhancement. Such noninvasive and real-time imaging of drug-induced apoptosis in situ can be used as an indicator for early evaluation of the therapeutic responses of a specific anticancer drug.
TL;DR: A simple sol-gel-processed NiO nanocrystal (NC) layer is used as the hole-transport layer in an inverted perovskite solar cell based on an inorganic hole-extracting layer, which observed a cell efficiency of 9.11 %, which is by far the highest reported for planar perovSKite solar cells based on a inorganic holes-extraction layer.
Abstract: Hybrid organic/inorganic perovskite solar cells have been rapidly evolving with spectacular successes in both nanostructured and thin-film versions. Herein, we report the use of a simple sol-gel-processed NiO nanocrystal (NC) layer as the hole-transport layer in an inverted perovskite solar cell. The thin NiO NC film with a faceted and corrugated surface enabled the formation of a continuous and compact layer of well-crystallized CH3 NH3 PbI3 in a two-step solution process. The hole-extraction and -transport capabilities of this film interfaced with the CH3 NH3 PbI3 film were higher than those of organic PEDOT:PSS layers. The cell with a NiO NC film with a thickness of 30-40 nm exhibited the best performance, as a thinner layer led to a higher leakage current, whereas a thicker layer resulted in a higher series resistance. With the NiO film, we observed a cell efficiency of 9.11 %, which is by far the highest reported for planar perovskite solar cells based on an inorganic hole-extracting layer.
TL;DR: The authors used hierarchical and relationalism to analyze the mediating role of affective trust in the relationship between paternalistic leadership and employee in-role and extra-role performance in Chinese organizational context.
TL;DR: A planar perovskite solar cell that incorporates a nanocarbon hole-extraction layer is demonstrated for the first time by an inkjet printing technique with a precisely controlled pattern and interface.
Abstract: A planar perovskite solar cell that incorporates a nanocarbon hole-extraction layer is demonstrated for the first time by an inkjet printing technique with a precisely controlled pattern and interface. By designing the carbon plus CH3NH3I ink to transform PbI2 in situ to CH3NH3PbI3, an interpenetrating seamless interface between the CH3NH3PbI3 active layer and the carbon hole-extraction electrode was instantly constructed, with a markedly reduced charge recombination compared to that with the carbon ink alone. As a result, a considerably higher power conversion efficiency up to 11.60 % was delivered by the corresponding solar cell. This method provides a major step towards the fabrication of low-cost, large-scale, metal-electrode-free but still highly efficient perovskite solar cells.